• Title/Summary/Keyword: chemical reinforcement

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Effect of The Addition of Various Cellulose Nanofibers on The Properties of Sheet of Paper Mulberry Bast Fiber (각종 셀룰로오스 나노섬유의 첨가가 닥나무 인피섬유 시트의 특성에 미치는 영향)

  • Han, Song-Yi;Park, Chan-Woo;Kim, Bo-Yeon;Lee, Seung-Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.6
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    • pp.730-739
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    • 2015
  • Various cellulose nanofibers (CNF) with different morphology and chemical properties were prepared for the reinforcement of sheet of paper mulberry bast fiber. Lignocellulose nanofiber (LCNF), Holocellulose nanofiber (HCNF), alkali-treated HCNF (AT-HCNF), TEMPO-oxidated nanofiber (TEMPO-NF) and cellulose nanocrystal (CNF) were prepared and their addition effect on the properties of sheet of paper mulberry bast fiber were investigated. Air permeability, surface smoothness, and tensile properties were improved by increasing CNF addition. Its improvement may be due to the CNF deposited between and on paper mulberry bast fibers, which was confirmed by SEM observation.

Experimental Investigations of Combination Effects of Installation Damage and Creep Deformation on Long-Term Design Strength of Geogrids (지오그리드의 장기설계인장강도에 미치는 시공시 손상 및 크리프 변형 복합효과에 대한 실험적 평가)

  • Cho, Sam-Deok;Lee, Kwang-Wu;Oh, Se-Yong;Lee, Do-Hee
    • Journal of the Korean Geosynthetics Society
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    • v.4 no.4
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    • pp.23-37
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    • 2005
  • The factors affecting the long-term design strength of geogrid can be classified into factors on creep deformation, installation damage, temperature, chemical degradation and biological degradation. Especially, creep deformation and installation damage are considered as main factors to determine the long-term design strength of geogrid. Current practice in the design of a reinforced soil structures is to calculate the long-term design strength of a geosynthetic reinforcement damaged during installation by multiplying the two partial safety factors, $RF_{ID}$ and $RF_{CR}$. This method assumes that there is no evaluation of synergy effect between installation damage and creep deformation of geogrids. This paper describes the results of a series of experimental study, which are carried out to assess the combined effect of the installation damage and the creep deformation for the long-term design strength of geogrid reinforcements. A series of field tests was carried out to assess installation damage of various geogrids with respect to different fill materials, and then creep tests are conducted to evaluate the creep deformation of both undamaged and damaged geogrids. The results indicated that the tensile strength reduction factors, RF, considering the combined effect between the installation damage and the creep deformation is less than that calculated by the current design method.

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The Effects of Cure System on Vulcanization Reaction Constant and Physical Properties of Rubber Compounds (가황시스템 변화가 배합고무의 가황반응속도 및 물리적 특성에 미치는 영향)

  • Lee, Seag;Park, Nam Cook
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.419-426
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    • 1999
  • In this study, the reaction rate constant, activation energy, total crosslinking density, elastic constant, cure properties ($t_5,\;t_{90}$), modulus, and abrasion resistance of rubber compounds were investigated as a function of cure temperatures, cure systems and reinforcing filler loadings. Reaction rate constants showed strong dependence on thc carbon black loading, cure temperature and cure system, and increased sharply with increasing the reaction temperatures. The lowest activation energy was obtained in the efficient cure (EC) system which corresponds to the high level of sulfur to accelerator ratio, and the activation energy was decreased with decreasing the carbon black loadings. The change of carbon black loadings directly affects the modulus and abrasion resistance, but the change of cure system showed various effects on the rubber compounds. Increased carbon black loadings showed the high modulus, improved abrasion resistance and short scorch time but decrease in crosslinking density and elastic constant. Higher crosslinking density and elastic constant were shown in the EC cure system regardless of carbon black loadings, but scorch timc ($t_5$) was not affected by the change of the ratio of sulfur to accelerator. Rapid optimum cure time ($t_{90}$) were showen in the EC cure system. Also, the equivalent cure curve coefficient of rubber compound was 0.96 for conventional cure (CC) system, and 0.94 for semi-efficient cure (SEC) and EC system regardless carbon black loadings. As regarding the abrasion resistance, wear volume showed the logarithmic increase for the loaded weight.

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The Application of Nanoliposome Composed of Ceramide as an Anti-irritant in Cosmetics (세라마이드를 구성성분으로 하는 나노리포좀의 응용 - 화장품에서의 자극완화제)

  • Jo Byoung Kee;Ahn Gi Woong;Shin Bong Soo;Jeong Ji Hean;Park Hae-Ryong;Hwang Yong-Il
    • Journal of Life Science
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    • v.15 no.2 s.69
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    • pp.267-272
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    • 2005
  • The objective of this study is to suggest the potentialities of nanoliposome composed of ceramide as an anti-irritant against various irritants used in cosmetics. Ceramides are major structural components of the epidermal permeability barrier, which is known to play an essential part in human physiology by not only preventing the loss of water from the body but also protecting the body from external physical, chemical, and microbial insults. According to the results, better effects on reinforcement of skin barrier function and anti-irritation were obtained with nanoliposome composed of ceramide than with dispersed ceramide. And, we performed in vitro skin penetration test using horizontal Franz diffusion cells with skin membrane prepared from hairless mouse to evaluate the influence of nanoliposome composed of ceramide on the skin penetration of lactic acid in formulations. From the results, we found that the anti-irritation effects of nanoliposome containing ceramide were due to reduced penetration rate of irritants. Conclusively, we could develop a new anti-irritation system and apply this nanoliposome composed of ceramide to the final cosmetic products successfully.

A Change of Surface Properties of Carbon Black by Surface Treatment (표면처리에 의한 Carbon Black의 표면물성변화)

  • Lee, Chang-Woo;Lee, Chang-Il;Hong, Young-Ho;Hong, In-Kwon;Jang, Yun-Ho;Hahm, Yeong-Min
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.768-776
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    • 1996
  • Carbon Black has various advantageous properties such as reinforcement, tinting, weathering, chemical resistance, electrical resistance, etc., but it has poor affinity in the solution. The purpose of this study is to enhance dispersion in the aqueous solution by altering the surface characteristics. Two different treatments were applied for both channel black and furnace black respectively. Channel black was treated in alkaline solution to replace hydrogen of the carboxyl group with alkaline metal, Li, Na, K. Furnace black has few functional groups, and it was treated with $HNO_3$ to increase the number of functional group on carbon black. It was seen that the substitution of alkaline metal on the surface of channel black enhances the degree of dispersion. Also the higher the acid concentration and reaction temperature, the more the number of some functional groups on the furnace black. Reaction time was not seen to be effective.

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Computer Simulation of Izod Impact Test for Impact Modifier Reinforced Nylon6 (충격보강제가 포함된 나일론 6에서 Izod 충격시험의 컴퓨터 모사)

  • Park, Yohan;Lyu, Min-Young;Paul, D.R.
    • Elastomers and Composites
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    • v.48 no.2
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    • pp.172-179
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    • 2013
  • Impact modifier reinforced polymers are frequently used. In this study, Izod impact test has been simulated to analyze the mechanism of impact reinforcement of Nylon6 which contains impact modifier. The modeling of rubber particles added to Nylon6 as an impact modifier has been attempted. Based on the modeling, simulation of Izod impact test has been performed to observe the distribution and direction of stress at the cross-section of impact specimen. Three computer simulation models for Nylon6 were investigated. Those were without impact modifier, containing impact modifier without surface treatment, and containing impact modifier with surface treatment in the Nylon6. Simulation results showed that the stress which originated at the notch surface propergated to the inside of specimen round a impact modifier. In addition to that, impact modifier reinforced Nylon6 specimen showed low stress ditribution in the cross-section specially at notch surface. Principal stress in perpendicular direction to crack was also lowered in impact modifier reinforced Nylon6. These enhanced impact resistance reduced and crack propergations. Through this study it was realized that the computer simulation can be utilized to investigate the property enhacement of composite materials.

A Study on the Eco-Friendly Durable Pre-Painting for Concrete Structure (콘크리트 구조물의 친환경 내구성 도장에 관한 기초 연구)

  • Jo, Byung Wan;Choi, Ji Sun;Lee, Seong Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.2
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    • pp.110-116
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    • 2013
  • A concrete structure has become bigger and higher because of development of construction technology and a change in construction environment. Also it tends to focus on repairing, reinforcement and exterior in harmony with environment for structure maintenance and performance improvement. The research is about eco friendly durable painting applicable to concrete structure using civil and architecture. it purpose to improve external beauties and durable problems due to flexibility by variation of temperature, adhesion of exterior wall, crack and delamination in existing organic and mineral painting. For those problems, we made a eco friendly pre-paint that is made with preliminary treatment mixture as a highly enriched waterproof agent and adhesive increasing agent in preprocessing mixture. Then we performed an experiment on durability of prevention neutralization of concrete, durability abrasion, hiding power, adhesion, temperature resistance and resistance to chemical attack. The result of an experiment shows that hiding power is over 0.96 in standard test, durability abrasion test got higher value 1mg than water paint 75mg and tensile strength is 6 times higher than standard waterproof specification.

Comparative Study on the Flexural Performance of Concrete Reinforced with Polypropylene and Steel Fibers (폴리프로필렌 및 강섬유 보강콘크리트의 휨 성능에 관한 비교 연구)

  • Cho, Baiksoon;Lee, Jong-Han;Back, Sung Yong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.6
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    • pp.1677-1685
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    • 2014
  • Short discrete fibers compounded with concrete can enhance the tensile resistance and ductility of concrete. Recently, the effectiveness of the reinforcement has increased according to the increasing length of steel fiber. However, the lengthening of steel fiber requires reducing the ratio of the fiber content to remain the workability and quality of concrete. Thus, the present study evaluated the flexural performance of fiber reinforced concrete with less than l.0% fiber volume ratios of steel fiber, 30mm and 60mm long, and polypropylene fiber, being evaluated as a good reinforcing material with chemical stability, long-term durability, and cost effectiveness. Concrete with more than 0.25% steel and 0.5% polypropylene fibers improved the brittle failure of concrete after reaching cracking strength. Concrete reinforced with polypropylene exhibited deflection-softening behavior, but that with more than 0.5% polypropylene delayed stress reduction and recovered flexural strength by 60 to 80% after cracking strength. In conclusion, concrete reinforced with more than 0.75% polypropylene could improve structural flexural performance. In particular, energy absorption capacity of reinforced concrete with 1.0% polypropylene fiber was similar to that with 0.5% and 0.7% steel fibers.

Interfacial Adhesion Properties of Oxygen Plasma Treated Polyketone Fiber with Natural Rubber (폴리케톤 섬유의 산소 플라즈마 처리에 따른 천연고무와의 계면접착 특성)

  • Won, Jong Sung;Choi, Hae Young;Yoo, Jae Jung;Choi, Han Na;Yong, Da Kyung;Lee, Seung Goo
    • Journal of Adhesion and Interface
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    • v.13 no.1
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    • pp.45-50
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    • 2012
  • Recently developed polyketone fiber has various applications in the mechanical rubber goods as reinforcement because of its good mechanical properties. However, its surface is not suitable for good adhesion with the rubber matrix. Thus, a surface modification is essential to obtain the good interfacial adhesion. Plasma treatment, in this study, has been conducted to modify the surface of the polyketone fiber. The morphological changes of the fibers by oxygen plasma treatment were observed by using SEM and AFM. The chemical composition changes of PK fiber surface treated with oxygen plasma were investigated using an XPS (X-ray photoelectron spectroscopy). Finally, the effect of these changes on the interfacial adhesion between fiber and rubber was analyzed by using a microdroplet debonding test. By the plasma treatment, oxygen moieties on the fiber surface increased with processing time and power. The surface RMS roughness increases until the proper processing condition, but a long plasma processing time resulted in a rather reduced roughness because of surface degradation. When the treatment time and power were 60 s and 80 W, respectively, the highest interfacial shear strength (IFSS) was obtained between the PK fiber and natural rubber. However, as the treatment time and power were higher than 60 s and 80 W, respectively, the IFSS decreased because of degradation of the PK fiber surface by severe plasma treatment.

Analysis on the Damage Status by Diagnostical Methodology for the Improvement Landscape on the Supyo-bridge at Chunggae-stream (청계천 수표교(水標橋)의 경관 향상을 위한 진단학적(診斷學的) 훼손상태 분석)

  • An, Jin-Sung;Choi, Ah-Hyun;Kim, Yu-Il
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.28 no.3
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    • pp.105-113
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    • 2010
  • This study is for the preservation plan of the tradition space which is performed by the damage status analysis through performing the value assessment. Especially, it is an experimental study for finding the process and methods by analyzing the major element for the value assessment of the selected object's damage status through the expert group who are systematized in their interest to conserve the traditional structure in traditional space. For that purpose, this study should be performed by the fundamental understanding of the physical property of the Supyo-bridge and the condition of the selected site's environment. Meanwhile, this study has been done that 'map of the damage status distribution' for making records of damage status of the Supyo-bridge on the property utilized field measurement adapted by photogrammetry and assessment guidelines, which are for investigation on damage status of objects that are standardized 'Raccomandazioni Normal' which could be said construction culture assets management guidelines of Italian government. As the result of investigation, damage status of each part in the Supyo-bridge was mostly composed of damage by sediment and corrosion and in case of 9 damage types including corrosion, in consideration of physical and chemical properties and distribution status of those elements, it is made an judgement that is not working as a threatened factor regarding security of the Supyo-bridge. On the contrary, for the improvement landscape, in case of 'Thermoclastism' phenomenon observed in 'upper floor', 'Myungae stone' and 'bridge pier' is that when taking it into consideration that is widely distributed concentrated on the bridge pier, surface reinforcement job along with elimination of damage part will be judged to be requested for earliest treatment.