• Title/Summary/Keyword: chemical reinforcement

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Conservation and Scientific Analysis of Human Bone Excavated in Sabi Period of Baekje from Eungpyeong-ri, Buyeo (부여 응평리 출토 백제 사비기 인골 보존처리 및 과학적 분석)

  • KIM, Mijeong;LEE, Yunseop;CHO, Eunmin;PARK, Sujin;MOON, Minseong
    • Korean Journal of Heritage: History & Science
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    • v.55 no.1
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    • pp.305-321
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    • 2022
  • The stone chamber tomb in Eungpyeong-ri, Buyeo, is a joint tomb that contains the bodies of two individuals. This paper investigates the relationship between the buried persons and the characteristics of the stone chamber tomb. Based on the geographical location, relics, and the excavated human bones, it was determined that the tomb was built during the Sabi Period of the Baekje Dynasty and that the buried individuals were most probably residents of high stature or government officials. To study the excavated bones, the remains were carefully collected and conservation was carried out. Before collecting samples from the human bones for the analytical research, the results of near-infrared analysis were used to collect the samples for the isotope analysis and DNA analysis. The most important issue when handling the excavation site was the reinforcing agent and the concentration of the agent used. In situations like this, Paraloid B-72 is the most suitable agent. When the shape of human bones was difficult to distinguish from the soil, conservation was performed using X-ray and CT imaging data. The same chemical used for the reinforcement of the site was used to complete a minimum level of conservation to the surface areas where the conservation treatment of removing foreign substances, the reinforcement areas, and bonded areas were carried out. The collagen yield from the sample obtained at selected position was 3.8% to 6.1%. The results of analyzing the stable isotopes of carbon and nitrogen found in the extracted collagen showed that the stable isotope ratios came out to δ13C -18.3‰±0.1‰, -19.0‰±0.1‰ for EBW and δ15N 10.7‰±0.5‰, 10.6‰±0.1‰ for EBE. It is believed the two individuals consumed small amounts of minor cereals, mainly from C3 plants, and protein was obtained from eating terrestrial animals. What's more, the deviations in data obtained from the two individuals were so small that it could be inferred that the individuals ate similar foods. Considering the preservation state of the sample, amplifying DNA for the DNA analysis would have been very difficult since the amount of surviving DNA was so deficient. For DNA analysis, it is anticipated that the results could be derived by applying improved extraction methods that will be developed in the future. In this research, any association between scientific analysis(DNA and stable isotope ratio) and near-infrared spectroscopy was difficult to establish. Further research is needed on the utilization of near-infrared analysis for gathering samples from human bones.

Characteristics Strength of Silicasol-cement Grout Material for Ground Reinforcement (지반보강용 실리카졸 약액의 강도특성에 대한 연구)

  • Kim, Hyunki;Kim, Younghun;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.9
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    • pp.47-53
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    • 2010
  • This study was made on the fact that the compressive strength characteristic of the recently developed alkali silica-sol chemical grout material was examined, whose grout material used for this study was designed to understand its strength property through the uniaxial compressive strength test(homo-gel, sand-gel), permeability test, deflection strength test, etc. In order to compare with the engineering characteristics regarding alkali silica-sol grout material and sodium silicate grout material. The uniaxial compressive strength of silica-sol grout material was identified to be increased more than 3~5 times than sodium silicate grout material at the early stage(within 72 hours). When comparing with the uniaxial compressive strengths of Sand-gel and Homo-gel at the material age of 28 days in case of silica-sol grouting material the strength of Sand-gel was measured to be about 1.3 times higher than Homo-gel. In case of silica-sol, it is assumed to have the property to exert high strength when it is actually grouted into the ground. As a result of permeability test it is judged that it is possible to apply the silica-sol to the site in the place requiring the water cut-off as the silica-sol. As a result of testing the strength at the material age of 28 days of grouting-use silica-sol showed more than 3 times' difference than the sodium silicate grouting material.

Durability and Crack Control of Concrete Using Fluosilicates Based Composite (규불화염계 복합 조성물을 혼입한 콘크리트의 균열제어 및 내구성)

  • Yun, Hyun-Do;Yang, Il-Seung;Kim, Do-Su;Khil, Bae-Su;Han, Seung-Gu
    • Journal of the Korea Concrete Institute
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    • v.18 no.1 s.91
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    • pp.57-64
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    • 2006
  • The crack presented in concrete structures causes a structural defect, the durability decrease, and external damages etc. Therefore, it is necessary to improve durability through the effort to control the crack. Fluosilicic acid($H_2SiF_6$) is recovered as aqueous solution which absorbs $SiF_4$ produced from the manufacturing of industrial-graded $H_3PO_4$ or HF. Generally, fluosilicates prepared by the reaction between $H_2SiF_6$ and metal salts. Addition of fluosilicates to cement endows odd properties through unique chemical reaction with the fresh and hardened cement. Mix proportions for experiment were modulated at 0.45 of water to cement ratio and $0.0{\sim}2.0%$ of adding ratio of fluosilicate salt based inorganic compound. To evaluate correlation of concrete strength and adding ratio of fluosilicate salt based inorganic compound, the tests were performed about design strength(21, 24, 27 MPa) with 0.5% of adding ratio of fluosilicate salt based inorganic compound. Applications of fluosilicate salt based inorganic compound to reduce cracks resulted from plastic and drying shrinkage, to improve durability are presented in this paper. Durability was evaluated as neutralization, chloride ion penetration depth, freezing thawing resistant tests and weight loss according reinforcement corrosion. It is ascertained that the concrete added fluosilicate salt based inorganic compound showed m ability to reduce the total area and maximum crack width significantly as compared non-added concrete. In addition, the durability of concrete improved because of resistance to crack and watertightness by packing role of fluosilicate salt based inorganic compound obtained and pozzolanic reaction of soluble $SiO_2$ than non-added concrete.

Modeling of Chloride Ingress in Reinforced Concrete Structures (철근 콘크리트 구조물의 염소이온 침투 모델)

  • Koo, Hyun-Bon;Kim, Eui-Tae;Lee, Kwang-Myong
    • Journal of the Korea Concrete Institute
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    • v.15 no.1
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    • pp.25-34
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    • 2003
  • The degradation of reinforced concrete (RC) structures due to physical and chemical attacks has been a major issue in construction engineering. Deterioration of RC structures by chloride attack followed by reinforcement corrosion is one of the serious problems. An objective of this study is to develop a form of mathematical model of chloride ingress into concrete. In order to overcome some limits of the previous approaches, a chloride ingress model, consisting of chloride solution intrusion through the capillary pore and chloride ion diffusion through the pore water, was proposed. Moreover, the variability of chloride ion diffusivity due to the degree of hydration of cement, relative humidity in pore, exposure condition, and variation of chloride binding, was considered in the model. In order to verify the proposed model, the results predicted by the proposed model were compared with analysis results of Life-365, a computer program for predicting the service life of reinforced concrete structures exposed to chlorides. In conclusion, the proposed model would be promising to predict the chloride ion profile and to estimate the service life of RC structures.

Weathering Properties and Slope Stability Evaluations of Bedrock under the Chokseongnu Pavilion, Jinjuseong Fortress, Korea (진주성 촉석루 성곽지반의 풍화특성과 사면안정성 평가)

  • Jo, Young-Hoon;Lee, Myeong-Seong;Lee, Sun-Myung;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.20
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    • pp.89-103
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    • 2007
  • The bedrock beneath the Chokseongnu pavilion consists of sandstone with alternate dark-gray to light-brown siltstone and dark-gray shale of the Jinju Formation, where bedding is well developed toward the Chokseongmun gate. Large to small joints and overbreak from the erosion weathering have been developed in the bedrock. Besides, water leakage from development of discontinuity planes, fragmentation of shale, crack and joint by tree roots are observed on the bedrock. While shale and siltstone showed high sensitivity in physical and chemical weathering, respectively, sandstone indicated the highest weathering sensitivity in both. As the results of structural stability analysis, the whole bedrock has high instability in wedge failures, and especially section No. II slope is more instable than section No. I. Therefore, it is necessary for the bedrock to be strengthened by improvement method for soft foundations and the surface reinforcement. The trees causing mechanical collapse of the bedrock should be also removed and a water flow prevention measure or a water exhaust are required.

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Evaluation of incremental sheet forming characteristics for 3D-structured aluminum sheet - part 2 (3D 구조 알루미늄 판재의 점진판재성형 특성 평가 (제2보))

  • Kim, Young-Suk;Do, Van-Cuong;Ahn, Dae-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.3
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    • pp.1585-1593
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    • 2015
  • 3D-structured (embossed) aluminum sheets have been used in the heat insulation purpose for automative exhaust parts because of increasing their surface areas and stiffness reinforcement imposed in making the embossing pattern. However, there are many restrictions in press forming of the embossed sheet compared with the flat sheet (non-embossed one) because of its difference in the mechanical properties and the geometrical 3-dimensional shape. In this paper we investigated the deformation characteristic of embossed aluminum sheet in the incremental sheet forming process which has frequently used in the design verification and the trial manufacturing of sheet products. The single point incremental forming (SPIF) experiments for the rectangular cone forming using the CNC machine with a chemical wood-machined die and a circular tool shape showed that the formability of the embossed sheet are better than that of the flat sheet in view of the maximum angle of cone forming. This comes from the fact that the embossed sheet between the tool and the elastic die wall is plastically compressed and the flatted area contributes to increase the plastic deformation. Also the tool path along the outward movement from the center showed a better formability than that of the inward movement from the edge. However the surface quality for the tool path along the outward movement evaluated from the surface deflection is inferior than that of the tool path along the inward movement.

EFFECTS Of VARIOUS SILANE COUPLING AGENTS ON THE STRENGTH AND THE SURFACE ROUGHNESS OF GLASS FIBER-ADDED PMMA RESIN (수종의 실란처리 유리섬유를 첨가한 의치상용 레진의 강도변화 및 마모전.후 표면성상분석)

  • Lee, Sang-Il;Kim, Chang-Whe;Lim, Young-Jun;Kim, Myung-Joo;Yun, Suk-Dae
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.4
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    • pp.457-468
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    • 2007
  • Statements of problem: The fracture of acrylic resin dentures remains an unsolved problem. Therefore, many investigations have been performed and various approaches to strengthening acrylic resin, for example, the reinforcement of heat-cured acrylic resin using glass fibers, have been suggested over the years. Silane is important for bonding between glass fiber and resin. Purpose: The aim of the present study was to investigate the effect of various silane on the strength of PMMA resin and roughness of resin-glass fiber complex after abrasion test. Material and methods: 3mm glass fiber (Chopped strand, Hankuk fiber Co., Milyang, Korea) was treated with 3 kinds of silane (MPS, EPS, APS) (Sila-ace, Chisso chemical, Tokyo, Japan) and mixed with PMMA resin(Vertex RS, Vertex Dental B.V., Zeist, Netherlands). Transverse strength and Young's modulus was measured using Instron (Instron model 4466, Instron, Massachusetts, USA). After abrasion test (The 858 Mini Bionix II Test System, MTS System Co., Minnesota, USA) surface roughness was evaluated using tester (Form Talysurf plus, Taylor Hopson Ltd., Leicester England). Examination of scanning electron microscope was also performed. Results: Within this study, the following conclusions were drawn. 1. Surface treatment of glass fiber with MPS and APS increased transverse strength of PMMA resin complex, but surface treatment with EPS decreased transverse strength of PMMA resin complex (p<0.05). 2. Silane treated glass fiber increased Young's modulus of PMMA resin complex compared to desized glass fiber (p<0.05). 3. Roughness increased after abrasion test in case of PMMA resin reinforced with desized glass fiber (p<0.05). 4. Roughness change was not observed after abrasion test in case of PMMA resin reinforced with silane treated glass fiber (p>0.05).

A Case Studty on the Ground Reinforcement and Waterproofing Effect of Weathering and Fault Zone by Special Injection Tip Equipment Using Microcement Type (특수주입선단장치에 의한 마이크로시멘트계 약액주입의 풍화대, 단층파쇄대의 지반보강 및 차수효과 사례연구)

  • Do, Jongnam;Jung, Jongju;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.2
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    • pp.21-28
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    • 2009
  • A grouting method has been widely used in construction of large-scale structure to reduce permeability and reinforce the ground. If cement and grout material were not mixed well in the injection tip equipment, an opposite flow and interception state of the chemical grouting can occur. McG (Multi-mixing counterflow prevented Grouting, McG) method installed a special grouting device to allow better mixing of the grouting material(above fineness $6,000cm^2/g$) and prevent backward flow. The block of nozzle also diversify powder rate of cement. YSS (Youngil Special Silicate, YSS) that lowers $Na_2O$ and thereby increases durability was developed by gel-forming reaction material. The seepage state and unconfined compressive strength of the injection material using the special injection tip equipment was tested in this study. The results of this study showed that the uniaxial compressive strength, permeability, N-value, TCR and RQD were improved by this method. Engineering characteristics obtained by the special injection tip method will be compared with those by the other method through various field tests from now on.

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Temperature-Dependency Thermal Properties and Transient Thermal Analysis of Structural Frames Exposed to Fire (온도의존성 열특성 계수를 고려한 화재에 노출된 철근콘크리트 골조의 해석적 연구)

  • Han, Byung-Chan;Kwon, Young-Jin;Kim, Jae-Hwan;Shin, Yeong-Soo;Choi, Eun-Gyu
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.283-292
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    • 2007
  • A research projects is currently being conducted to develop a nonlinear finite element analysis methods for predicting the structural behavior of reinforced concrete frame structures, exposed to fire. As part of this, reinforced concrete frames subjected to fire loads were analyzed using the nonlinear finite-element program DIANA. Two numerical steps are incorporated in this program. The first step carries out the nonlinear transient heat flow analysis associated with fire and the second step predicts the structural behavior of reinforced concrete frames subjected to the thermal histories predicted by first step. The complex features of structural behavior in fire conditions, such as thermal expansion, plasticity, cracking or crushing, and material properties changing with temperature are considered. A concrete material model based on nonlinear fracture mechanics to take cracking into account and plasticity models for concrete in compression and reinforcement steel were used. The material and analytical models developed in this paper are verified against the experimental data on simple reinforced concrete beams. The changes in thermal parameters are discussed from the point of view of changes of structure and chemical composition due to the high temperature exposure. Although, this study considers codes standard fire for reinforced concrete frame, any other time-temperature relationship can be easily incorporated.

Comparison of Mechanical and Interfacial Properties on Chemical Structures of Acrylic and Epoxy Adhesives (아크릴 및 에폭시 접착제의 화학적 구조에 따른 유리섬유 복합재료의 기계적 및 계면 물성 변화 평가)

  • Shin, Pyeong-Su;Kim, Jong-Hyun;Choi, Jin-Yeong;Kwon, Dong-Jun;Lee, Sang-Il;Park, Joung-Man
    • Composites Research
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    • v.29 no.2
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    • pp.79-84
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    • 2016
  • An adhesive can be used to connect two different materials in structures. In comparing with other connecting methods, such as bolt, rivet, and hot melting, the adhesive does not need to use them. It leads to reduce the weight and decrease the stress concentration along the connecting line. This work studied the comparison of mechanical and interfacial properties of commonly-used two adhesives, acrylic type and bisphenol-A epoxy type. Tensile and flexural strength of neat adhesives were also compared. Lap shear test of two adhesives was deduced from the measurement of tensile and fatigue tests. After testing, the failure patterns of adhesive surfaces were observed by a microscope. Tensile strength and mechanical fatigue resistance at using bisphenol-A epoxy adhesive were better than acrylic adhesive. Also adding CNT reinforcement in epoxy adhesive can anticipate mechanical improvement.