• Title/Summary/Keyword: chemical reinforcement

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Progresses on the Optimal Processing and Properties of Highly Porous Rare Earth Silicate Thermal Insulators

  • Wu, Zhen;Sun, Luchao;Wang, Jingyang
    • Journal of the Korean Ceramic Society
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    • v.55 no.6
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    • pp.527-555
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    • 2018
  • High-temperature thermal insulation materials challenge extensive oxide candidates such as porus $SiO_2$, $Al_2O_3$, yttria-stabilized zirconia, and mullite, due to the needs of good mechanical, thermal, and chemical reliabilities at high temperatures simultaneously. Recently, porous rare earth (RE) silicates have been revealed to be excellent thermal insulators in harsh environments. These materials display attractive properties, including high porosity, moderately high compressive strength, low processing shrinkage (near-net-shaping), and very low thermal conductivity. The current critical challenge is to balance the excellent thermal insulation property (extremely high porosity) with their good mechanical properties, especially at high temperatures. Herein, we review the recent developments in processing techniques to achieve extremely high porosity and multiscale strengthening strategy, including solid solution strengthening and fiber reinforcement methods, for enhancing the mechanical properties of porous RE silicate ceramics. Highly porous RE silicates are highlighted as emerging high-temperature thermal insulators for extreme environments.

Yield enhancement of matrix precursor in short carbon fiber reinforced randomly oriented carbon/carbon composite

  • Raunija, Thakur Sudesh Kumar;Sharma, Sharad Chandra;Verma, Anil
    • Carbon letters
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    • v.19
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    • pp.57-65
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    • 2016
  • Isroaniso matrix precursor synthesized from commercially available petroleum pitch was stabilized in air. The influence of oxygen mass gain during stabilization on the yield of matrix precursor was studied. Additionally, the influence of pressure on the yield of the stabilized matrix precursor in a real system was studied. The fourier transform infrared spectrometry (FTIR), thermogravimetric analysis (TGA), yield, yield rate, and yield impact were used to check the effect of stabilization and pressure on the yield of the matrix precursor and the end properties of the composite thereafter. The results showed that the yield increased with stabilization duration up to 20 h whereas it decreased for stabilization duration beyond 20 h. Further results showed that the stabilized matrix precursor for a duration of 5 h could withstand almost two-fold greater hot-pressing pressure without resulting in exudation as compared to that of a 1 h stabilized matrix precursor. The enhanced hot-pressing pressure significantly improved the yield of the matrix precursor. As a consequence, the densification and mechanical properties were increased significantly. Further, the matrix precursor stabilized for a duration of 20 h or more failed to provide proper and uniform binding of the reinforcement.

Effect of Washing Treatment of Aged Paper Materials for Better Conservation (열화된 종이자료의 보존성 개선을 위한 세척처리 특성)

  • Lee, Kwi-Bok;Seo, Yung-Bum;Park, So-Yeon;Jeon, Yang;Shin, Jong-Soon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.4 s.117
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    • pp.53-60
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    • 2006
  • Paper materials for long term conservation suffer slowly mechanical and chemical deterioration, the extent of which may depend upon their conservation environment. Those deterioration includes discoloring, low moisture content, acidification, and brittleness. To slow deterioration, washing treatment, deacidification, and polymer reinforcement on paper materials are usually used. One easy and simple method of fixing low moisture content and acidification was an washing method, and we used both distilled and alkali water in washing method in this study. Alkali water is electrolyzed cathode water of high pH, and has no alkali metal ions in it. Experiment showed that washing treatment with both distilled and alkali water gave improvement in raising moisture content, pH, and mechanical strength of paper materials even after severe accelerated aging test. Advantageous effect of alkali water over distilled water on preventing deterioation was also shown clearly.

Strength Characteristics of Epoxy Cement Mortar without Hardening Agent (경화제를 사용하지 않은 에폭시 시멘트 모르타르의 압축강도 특성에 관한 연구)

  • Park, Young-Shik
    • Journal of the Korean Society of Industry Convergence
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    • v.10 no.4
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    • pp.207-211
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    • 2007
  • The durable lifetime of RC structures is shortened by various reasons, which are the generation of cracks in construction and service term, the exterior deterioration according to climatic condition, the surface damage due to chloride attack and the corrosion of reinforced bars. The durability of concrete structures is nevertheless able to be increased by the method and the material of reinforcement and repair. The epoxy resin is widely used for reinforment and repair of concrete because of the superiority in mechanical property, adhesive property, abrasion resistance, impact resistance and chemical resistance. The epoxy cement mortar with hardening agent has a lot of disadvantages that are troublesome mixing work, weakened weatherability and high cost for hardening agent. In this study, the mix proportion of mortar is presented just only with epoxy resin and some admixtures, and the test result of mortar without hardening agent shows the higher strength than the mortar with hardening agent. In the mix proportion, the weight of epoxy resin must be less than 15% of the unit weight of cement, and 10% of unit weight of cement is adequate for the weight of admixtures.

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(An) experimental study on the development of lightweight concrete using the PCM (PCM 혼입 경량기포콘크리트 패널 개발을 위한 기초적 연구)

  • Lim, Myung Kwan;Enkhbold, Odontuya;Kim, Young Ho;Choi, Dong Uk
    • KIEAE Journal
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    • v.14 no.4
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    • pp.133-138
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    • 2014
  • The present study was carried out to assess the basic material properties and thermal behavior of light-weight foamed concrete panel mixed with PCM (Phase Changing Material). To do so, this study fabricated light-weight foamed concrete (1.0kg/m3) in pre-foaming method and mixed it with PCM micro capsule of 1-dodecanol and melamine to examine its physical and thermal properties. The results confirmed strength reinforcement effect by proper replacement ratio of fly-ash, which is an industrial by-product, and PCM. In addition, it found out that PCM-mixed light-weight foamed concrete had time delay and temperature reduction effect within the range of PCM phase transition according to the rise of outdoor temperature. It was also observed that the insulation performance of PCM-mixed light-weight foamed concrete was more dependent upon thickness than PCM replacement ratio.

A Study on the Ground Reinforcement and Impermeable Effect by McG (McG(맥) 주입공법에 의한 지반보강 및 차수효과에 관한 연구)

  • Chun, Byung-Sik;Jung, Jong-Ju;Chung, Chang-Hee;Do, Kyung-Yang;Do, Jong-Nam
    • Proceedings of the Korean Geotechical Society Conference
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    • 2006.03a
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    • pp.352-361
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    • 2006
  • The grouting method is widely used in construction to reduce permeability and reinforce the ground. If the cement and grout material are not mixed well in the injection tip equipment, an opposite flow and Interception state of the chemical grouting can occur. McG method installs a special grouting device to allow better mixing of the grouting material and prevent backward flow. The block of nozzle also diversify powder rate of cement. YSS that lowers $Na_2O$ and thereby increases durability is developed by gel-forming reaction material. In this study, the seepage state and unconfined compressive strength of the injection material using the special injection tip equipment is tested. The results of laboratory and field tests clearly demonstrate that the strength increases and permeability decreases using the McG method.

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X-ray Photoelectron Spectroscopic Analysis of Modified MWCNT and Dynamic Mechanical Properties of E-beam Cured Epoxy Resins with the MWCNT

  • Lee, Young-Seak;Im, Ji-Sun;Yun, Seok-Min;Nho, Young-Chang;Kang, Phil-Hyun;Jin, Hang-Kyo
    • Carbon letters
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    • v.10 no.4
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    • pp.314-319
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    • 2009
  • The surface treatment effects of reinforcement filler were investigated based on the dynamic mechanical properties of mutiwalled carbon nanotubes (MWCNTs)/epoxy composites. The as-received MWCNTs(R-MWCNTs) were chemically modified by direct oxyfluorination method to improve the dispersibility and adhesiveness with epoxy resins in composite system. In order to investigate the induced functional groups on MWCNTs during oxyfluorination, X-ray photoelectron spectroscopy was used. The thermo-mechanical property of MWCNTs/epoxy composite was also measured based on effects of oxyfluorination treatment of MWCNTs. The storage modulus of MWCNTs/epoxy composite was enhanced about 1.27 times through oxyfluorination of MWCNTs fillers at $25^{\circ}C$. The storage modulus of oxyfluorinated MWCNTs (OF73-MWCNTs) reinforced epoxy composite was much higher than that of R-MWCNTs/epoxy composite. It revealed that oxygen content led to the efficient carbon-fluorine covalent bonding during oxyfluorination. These functional groups on surface modified MWCNTs induced by oxyfluorination strikingly made an important role for the reinforced epoxy composite.

Insulation Reinforcement of the Electrical Power Cable Degradated by the Water Tree Using Silicon (실리콘을 이용한 수트리 열화된 전력 케이블의 절연 보강)

  • Kang, Hyeong-Gon;Park, Jun-Chae;Ko, Seok-Cheol;Lim, Sung-Hun;Lee, C.H.;Hanh, Y.B.;Han, B.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.468-471
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    • 2003
  • Fault of under ground power cable occurs usually from the water tree such as the vented tree, the bow tree and the water-rich halo. The water tree penetrates to the polyethylene cable insulations. Sometimes, the water tree also diffuses to mother cable in the substation. In this paper, instead of replacement of the faulty cable, we tried to cure an electrical power cable degraded by the water trees with silicon injection method. And measured the results with the isothermal relaxation current analysis method. After cable cure, Chonil line was improved from 2.27 to 1.96 in a phase, from 2.148 to 2.020 in b phase, and from badness to 2.192 in c phase. And Keumam line was also improved from 2.419 to 1.920 in a phase, from 2.301 to 2.000 in b phase, and from badness to 1.957 in c phase.

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The Characteristic of Titanium Composites Including of Nano-sized TiNx for Stack Separator

  • Park, Sung-Bum;Ban, Tae-Ho;Woo, Heung-Sik;Kim, Sung-Jin
    • Journal of Powder Materials
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    • v.17 no.2
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    • pp.123-129
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    • 2010
  • The fabrication of interconnect from titanium powders and $TiN_x$ powders is investigated. Corrosion-resistant titanium and $TiN_x$ are used as reinforcement in order to reveal high heat and corrosion resistance at the elevated temperature. We fabricated the plates for interconnect reinforced with $TiN_x$ by mixing titanium powders with 10 wt.% of nano-sized $TiN_x$. Spark Plasma Sintering (SPS) was chosen for the sintering of these composites. The plate made of titanium powders and $TiN_x$ powders demonstrates higher corrosion resistance than that of the plate of titanium powders alone. The physical properties of specimens were analyzed by performing hardness test and biaxial strength test. The electrochemical properties, such as corrosion resistance and hydrogen permeability at high temperature, were also investigated. The microstructures of the specimens were investigated by FESEM and profiles of chemical compositions were analyzed by EDX.

Analysis of Pheasant Carcass and Sensory Characteristics of Pheasant meat Products (꿩의 도체분석 및 꿩고기 가공제품의 관능 특성)

  • 전홍남;최성희;오홍록
    • Food Science of Animal Resources
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    • v.18 no.4
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    • pp.307-315
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    • 1998
  • To develop processed meat products of pheasant, cut-up parts of pheasant carcass was analyzed, and eight different pheasant meat products were prepared and evaluated for sensory qualities. The average live weight of pheasant was 1,089.2g, and the ratio of carcass to live weight was 75.6%. The cut-up part ratios of breast, leg, neck, back and wings to carcass weight were 33.4%, 22.5%, 5.0%, 4% and 9.5%, respectively. The chemical compositions of breast and leg meat were shown to be moisture of 73.72% and 75.58%, protein of 25.31% and 22.69%, fat of 0.28% and 0.83%, and ash of 0.84% and 0.90%, respectively. Sensory evaluation of eight different meat products of pheasant revealed that all products of pheasant meat, except frankfurt sausage, received equal or better taste score compared with products of chicken or pork, and flavor score except pressed ham and salad. Color, binding ability and particle perception scores of pheasant meat products were equal or superior to those of respective meat products of chicken or pork. The present results suggest that pheasant meat has a potential to be utilized for various value-added products and that the meat bun is the most promising product of pheasant meat. A reinforcement of color, binding ability and particle perception of meat products of other species could also be expected by addition of pheasant meat to them.