• Title/Summary/Keyword: chemical pretreatment

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Synthesis of the Carbon Nano/micro Coils Applicable to the Catalyst Support to Hold the Tiny Catalyst Grain (매우 작은 크기의 촉매 알갱이를 지지하기 위한 촉매 지지대용 탄소 나노/마이크로 코일의 합성)

  • Park, Chan-Ho;Kim, Sung-Hoon
    • Journal of the Korean Vacuum Society
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    • v.22 no.6
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    • pp.277-284
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    • 2013
  • Carbon coils could be synthesized using $C_2H_2/H_2$ as source gases and $SF_6$ as an incorporated additive gas under thermal chemical vapor deposition system. The Ni layer on the $SiO_2$ substrate was used as a catalyst for the formation of the carbon coils. The characteristics (formation densities, morphologies, and geometries) of the as-grown carbon coils on the substrate with or without the $H_2$ plasma pretreatment process were investigated. By the relatively short time (1 minute) $H_2$ plasma pretreatment on the Ni catalyst layered-substrate prior to the carbon coils synthesis reaction, the dominant formation of the carbon microcoils on the substrate could be achieved. After the relatively long time (30 minutes) $H_2$ plasma pretreatment process, on the other hand, we could obtain the noble-shaped geometrical nanostructures, namely the formation of the numerous carbon nanocoils along the growth of the carbon microcoils. This noble-shaped geometrical nanostructure seemed to play a promising role as the good catalyst support for holding the very tiny Ni catalyst grains.

The Evaluation of Fouling Mechanism on Cross Flow Precoagulation-UF Process (십자형 응집-UF 막분리 공정 적용시 전처리 응집조건에 따른 막오염 메카니즘 규명)

  • Jung, Chul-Woo;Son, Hee-Jong
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.639-645
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    • 2008
  • The objectives of this research are to (1) observe changes in particle size distribution due to formation of microflocs during coagulation process (2) identify the membrane fouling potential on cross flow system (3) investigate the mechanism of membrane fouling. The rate of flux decline for the hydrophobic membrane was significantly greater than for the hydrophilic membrane, regardless of pretreatment conditions. The pretreatment of the raw water significantly reduced the fouling of the UF membrane. Also, the rate of flux decline for the hydrophobic membrane was considerably greater than for the hydrophilic membrane. Applying coagulation process before membrane filtration showed not only reducing membrane fouling, but also improving the removal of dissolved organic materials that might otherwise not be removed by the membrane. That is, during the mixing period, substantial changes in particle size distribution occurred under rapid and slow mixing condition due to the simultaneous formation of microflocs and NOM precipitates. Therefore, combined pretreatment using coagulation not only improved dissolved organics removal efficiency but also flux recovery efficiency.

Development of humic acid extraction method in soil and sediment using ultrasonic for 14C dating (초음파를 이용한 14C 연대측정 토양시료의 부식산 추출법 개발)

  • Park, Jiyoun;Hong, Wan;Park, Junghun
    • Analytical Science and Technology
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    • v.22 no.2
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    • pp.136-140
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    • 2009
  • To improve the carbon recovery yield of chemical pretreatment in soil and sediment for $^{14}C$ age dating using AMS (Accelerator Mass Spectrometry), we have developed ultrasonic method in chemical pretreatment to replace with stirring method which has been generally used in each step of humic acid extraction for soil and sediment samples. Extraction conditions such as ultrasonic power, temperature and reaction time have been optimized. Six times higher carbon recovery yield could be obtained from low carbon content samples using ultrasonic method. We also compared the dating results by AMS obtained using ultrasonic method with the ages of samples treated by the stirring method. It was found that this new method could be applied to the pretreatment process of low carbon content samples for AMS age dating without effects on the dated ages, and with highly improved carbon recovery yields.

An Improved Selective Isolation of Rare Actinomycetes from Forest Soil

  • Seong, Chi-Nam;Park, Ji-Heok;Baik, Keun-Shik
    • Journal of Microbiology
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    • v.39 no.1
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    • pp.17-23
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    • 2001
  • Various pretreatment procedures and selective media were applied to assess the optimal conditions for the isolation of rare actinomycetes from soil. Pretreatment of wet-heating for 15 min at 70$^{\circ}C$ and phenol treatment of soil suspension were the most effective methods for the isolation of these microorganisms. Hair hydrolysate vitamin agar (HHVA) was the most suitable medium for the recovery of rare actinomycetes. Thirty-five rare actinomycete strains were chosen using selective isolation approaches, then morphological and chemical properties of the isolates were determined. The isolates belonged to one of the following genus, Micromonospora, Microbispora, Actinoplanes and Streptosporangium.

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Evaluation of Oil Pollutants Removal in Seawater as Pretreatment Process for Reverse Osmosis Desalination Process (역삼투식 해수담수화의 전처리공정으로서 유분 제거의 평가)

  • ;Okada Mitsumasa
    • Proceedings of KOSOMES biannual meeting
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    • 2003.05a
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    • pp.205-209
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    • 2003
  • The various pretreatment processes were evaluated for removal of oil pollutants with weathered oil contaminated seawater in a reverse osmosis desalination process. Weathered oil contaminated seawater was made by biodegradation and photooxidation with oil containing seawater. Coagulation, ultrafiltration, advanced oxidation processes and granular activated carbon filtration was used with pretreatment for dissolved organic carbon. Crude oil was removed but. weathered oil contaminated seawater was not removed by biodegradation and coagulation. DOC and E260 was removed with about 20 % and 40 % by membrane filter of cut off molecular weight 500. So, the most of dissolved organic carbon in weathered oil contaminated seawater was revealed that molecular weight was lower than 500. It is difficult to remove DOC in weathered oil contaminated seawater by advanced oxidation processes treatment, but, E260 was removed more high. However, DOC in weathered oil contaminated seawater was easily adsorbed to GAC. It is revealed that DOC was removed by adsorption.

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Enhancing Enzymatic Digestibility of Miscanthus sinensis using Steam Explosion Coupled with Chemicals

  • Jung, Ji Young;Yang, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.2
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    • pp.218-230
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    • 2016
  • The effect of steam explosion coupled with alkali (1% sodium hydroxide, 1% potassium hydroxide and 15% sodium carbonate) or organosolv solvent (85% methanol, 70% ethanol and dioxane) on the production of sugar, changes in the chemical composition of M. sinensis were evaluated. The steam explosion coupled with 1% potassium hydroxide and dioxane were better as compared with other treatments based on the removals of acid insoluble lignin, and about 89.0% and 85.4%. Enzymatic hydrolysis of steam explosion with 1% potassium hydroxide and dioxane treated M. sinensis, gave a 98.0% and 96.5% of glucose conversion, respectively. These results suggested that pretreatment of M. sinensis with either potassium hydroxide or dioxane could be a promising pretreatment method for glucose production.

A Study on the Treatment of Dyeing Wastewater Using TiO₂/H₂O₂/UV Processes (TiO₂/H₂O₂/UV 공정을 이용한 염색폐수처리에 관한 연구)

  • Jo, Il Hyeong;Jeong, Hyo Jun;Park, Gyeong Ryeol;Seong, Gi Seok;Lee, Yong Gyu;Lee, Hong Geun
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.27-27
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    • 2000
  • In order to treat the dyeing wastewater, the UV/TiO₂/H₂O₂ system was investigated, and proper pretreatment methods were examined to reduce the load on the system considering economical and technical efficiency. The results of this study were as follows: 1.UV/TiO₂/H₂O₂ system with pretreatment process was adopted, the result of Chemical coagulation and pH control units was pH 11→ coagulation → pH 4 and the optimum dosage of FeCl₃ was 600㎎/ℓ 2. Proper dosage of TiO₂in the UV/TiO₂/H₂O₂ system with pretreatment process was 2g/ℓ and H₂O₂ was 1000㎎/ℓ, UV contact time was 20min to get below 200㎎/ℓ of $COD_{Cr}$

A Study on the Treatment of Dyeing Wastewater Using $TiO_2/H_2O_2/UV$ Processes ($TiO_2/H_2O_2/UV$ 공정을 이용한 염색폐수처리에 관한 연구)

  • 조일형;정효준;박경렬;성기석;이용규;이홍근
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.26-34
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    • 2000
  • In order to treat the dyeing wastewater, the $UV/TiO_2/H_2O_2$ system was investigated, and proper pretreatment methods were examined to reduce the load on the system considering economical and technical efficiency. The results of this study were as follows: 1. $UV/TiO_2/H_2O_2$ system with pretreatment process was adopted, the result of Chemical coagulation and pH control units was $pH{\;}11{\;}{\rightarrow}{\;}coagulation{\;}{\rightarrow}{\;}pH{\;}4$ and the optimum dosage of $FeCl_3$ was $600mg/{\ell}$. 2. Proper dosage of $TiO_2$ in the $UV/TiO_2/H_2O_2$ system with pretreatment process was $2g/{\ell}$ and $H_2O_2$ was $1000mg/{\ell}$, UV contact time was 20min to get $200mg/{\ell}$ of $COD_{Cr}$.

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Evaluation of Pretreatment Processes for Dissolved Organic Carbon Removal in a Desalination Process (해수담수화에서 용존유기물을 제거하기 위한 전처리 공정의 평가)

  • Kim, Woo-Hang;Mitsumasa, Okada
    • Journal of Korean Society on Water Environment
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    • v.20 no.5
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    • pp.447-451
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    • 2004
  • The various pretreatment processes were evaluated to remove organic pollutants of weathered oil contaminated seawater(WOCS) for reverse osmosis desalination process, Biodegradation, coagulation, ultrafiltration, advanced oxidation processes and granular activated carbon filtration were used to evaluate the potential of organic pollutants removal in WOCS. Dissolved Organic Carbon(DOC) was almost not removed by biodegradation in WOCS. DOC was removed by 25% and 10% with the addition of $FeCl_3$ and PAC in WOCS, respectively. The removal efficiency using ultrafiltration(WOCS 500) was about 20% of DOC and 40% of $E_{260}$, respectively. In AOP application of WOCS, the removal of organic materials was improved up to 60% by the combination of $UV/O_3$ compared to UV process. However, 98% of DOC in woes could be removed by granular activated carbon filtration. It is revealed that activated carbon filtration is the best process for the pretratment of DOC removal.

Anaerobic Fermentation of Woody Biomass Treated by Various Methods

  • Nakamura, Yoshitoshi;Mtui, Godliving
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.3
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    • pp.179-182
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    • 2003
  • Anaerobic fermentation was attempted to produce methane from the wood chip (Eucalyptus globulus). By the pretreatment of the wood chip using hot water with high temperature, NaOH, and steam explosion, the production of methane gas was enhanced. The pretreatment using Steam explosion resulted in more amount of methane gas produced than the treatment using either hot water or 1% (w/w) NaOH with high temperature, and the steam explosion at a steam pressure of 25 atm and a steaming time of 3 min was the most effective for the methane production. The amount of methane gas produced depended on the ratio of weight of Klason lignin, a high molecular weight lignin, in the treated wood chip.