• New & Renewable Energy
• /
• v.17 no.4
• /
• pp.36-45
• /
• 2021

To remove the Cu secondary phase remaining on the surface of a CIGSSe absorber layer manufactured by the two-step process, KCN etching was applied before depositing the CdS buffer layer. In addition, it was possible to increase the conversion efficiency by air annealing after forming the CdS buffer layer. In this study, various pre-treatment/post-treatment conditions wereapplied to the S-containing CIGSSe absorber layerbefore and after formation of the CdS buffer layer to experimentally confirm whether similareffects as those of Se-terminated CIGSe were exhibited. Contrary to expectations, it was noted that CdS air annealing had negative effects.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.7
• /
• pp.1967-1971
• /
• 2013

Aim of our study is finding adsorbents suitable for pre-concentration of chemical warfare agents (CWAs). We considered Tenax, bare silica and polydimethylsiloxane (PDMS)-coated silica as adsorbents for dimethyl methylphosphonate (DMMP) and dipropylene glycol methyl ether (DPGME). Tenax showed lower thermal stability, and therefore, desorption of CWA simulants and decomposition of Tenax took place simultaneously. Silica-based adsorbents showed higher thermal stabilities than Tenax. A drawback of silica was that adsorption of CWA simulant (DMMP) was significantly reduced by pre-treatment of the adsorbents with humid air. In the case of PDMS-coated silica, influence of humidity for CWA simulant adsorption was less pronounced due to the hydrophobic nature of PDMS-coating. We propose that PDMS-coated silica can be of potential importance as adsorbent of CWAs for their pre-concentration, which can facilitate detection of these CWAs.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.30 no.4
• /
• pp.27-40
• /
• 2022

In this study, the anaerobic digestion potential and thermo-chemical pre-treatment were evaluated for efficient anaerobic co-digestion of dewatered sludge(DS) and food waste(FW). As a result, the degradable organic matter concentration and methane yield of FW were evaluated to 2.2 and 1.3 times higher than that of DS, respectively. In order to increase the amount of biogas production, it was determined that it is desirable to increase the mixing ratio of FW. The efficiency of thermo-chemical pre-treatment was evaluated for the reaction temperature, NaOH concentration, reaction time and mixture ratio. As a result of evaluation through pre-treatment efficiency and dehydration capacity, the optimum pre-treatment conditions were evaluated as follows: reaction temperature 140℃, NaOH concentration 60 meq/L, reaction time 60 min, mixture ratio 1:5(DS:FW). The gas production rate and methane yield increased 1.6 and 1.5 times, respectively, compared to before and after applying the optimum pre-treatment. Therefore, it is necessary to increase the mixing ratio of food waste for efficient anaerobic co-digestion of DS and FW. and it is necessary to increase the solubilization efficiency of waste by application of pre-treatment.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.32 no.2
• /
• pp.1-7
• /
• 2000

In the previous experiment, it was found that OCC pre-treatment with Hobart mixer at 20-25％ consistency for 3 hrs or more followed by the application of the equal refining time, caused the increase of tensile strength, burst strength, compressive strength and tear resistance, compared to the no pre-treated. Four completely different fibers, which were Hw-BKP, Sw-BKP, White ledger, and OCC were selected for this experiment to investigate the effect of mechanical pre-treatment process on different fibers. From the experiment, it was found that the mechanical pre-treatment did not decrease fiber length at all, but decreased freeness, com-pared to the no pre-treated, when the same refining time was applied. WRVs of the pre-treated fibers were higher than the no pre-treated at the same freeness level. It was speculated that the mechanical pre-treatment induced only hydrophilic nature of fibers without damaging fiber length by delaminating fiber walls. The fiber surface area and the physical strength differences of handsheets will be discussed in the next publication.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.23 no.1
• /
• pp.18-23
• /
• 2010

We demonstrated that the solution processed organic light-emitting diodes (OLEDs) have the high efficiency with pre-treated indium-tin-oxide (ITO). ITO surface was pre-treated with four methods and compared each other. The pre-treatment of ITO surface improves the chemical and physical characteristics of ITO such as the surface roughness, adhesion property, and the hole injection ability. These properties were analyzed by the contact angle, atomic force microscope (AFM) image, and the current flow character in device. As a results, the device with ITO pre-treated by $O_2$ plasma shows the current efficiency of 5.93 cd/A, which is 1.5 times the device without pre-treatment.

• Journal of the Korea Fashion and Costume Design Association
• /
• v.5 no.3
• /
• pp.15-23
• /
• 2003

Chestnut trees have been used as a dyeing material, which are grow naturally, are cultivated all the area of Korea. So, there is abundant amount of the materials and they have better colorfastness than other natural dyeing materials. But chestnut husk extract is good at silk and wool fabrics, not cotton fabrics. That's why many methods using chestnut extraction for dyeing are being studied. But most of them depend on treatment method with chemical material which doesn't fit with the aim, using natural materials. Therefore in this research, we used protein pre-treatment method which is dyeing chestnut husk extract after treating at cotton fabrics with bean sap. And we studied the effect of dyeability of chestnut husk extract to cotton fabrics. As a result of pre-treatment of bean sap at cotton fabrics, dyeability was increased. Besides laundering fastness, dry cleaning fastness, perspiration fastness and light fastness were almost increased.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.21 no.3
• /
• pp.43-52
• /
• 2013

In this study, various influent sludge pre-treatment methods were adopted to investigate their effects on the sludge digestion and methane production in combined mesophilic anaerobic and thermophilic aerobic sludge digestion process. A lab-scale sewage sludge digestion process was operated during 4 phases using different feed sludge pre-treatment strategies. In phase 1, feed sludge was supplied without any pre-treatment. In contrast, in phases 2, 3 and 4, thermal, thermal-alkaline and long time alkaline treatment (7 days) were applied to influent sludge, respectively. With sludge pre-treatment, TCOD removal was drastically increased from 44% to 76% from phases 1 to 4, respectively. Also, pre-treatment of feed sludge significantly improved the methane production rate of MAD, showing an increment from 101 to 165-256mL/L/day. Meanwhile, TCOD removal and methane production at phase 4 were not increased, compared to those at phase 3. Based on the experimental results, it was concluded that pre-treatment of feed sludge significantly increases the efficiency of sludge digestion and thermal-alkaline method was the most effective method among the pre-treatment methods examined.

• Environmental Engineering Research
• /
• v.22 no.1
• /
• pp.1-11
• /
• 2017

One of the most threatening consequences of eutrophic freshwater reservoirs is algal blooming which typically occur after the long a mega drought or/and irregular rainfall under influence of climate change. The long-term experiences of chemical treatment are known as a most practical effort to reduce health concerns from human exposure of harmful cyanobacteria as well as to preserve ultimate freshwater resources. Even though these conventional chemical treatment methods do not completely solve the algal residue problem in water treatment plant or directly in the water bodies, they still have big advantages as fast and efficient removal process of cyanobacteria due to cheaper, easier to manage. This review summarizes their chemical treatment scenarios of the representative coagulants, pre-oxidants and algaecides composed to chemical compounds which immediately may help to manage severe cyanobacteria blooms in the summer seasons.

• Bulletin of the Korean Chemical Society
• /
• v.25 no.8
• /
• pp.1189-1194
• /
• 2004

The adsorption isotherms of N2 onto the metallic silver treated activated carbon fiber samples after acid treatment are Type I with a small amount of capillary condensation hysteresis. Increasing amount of acid treatment leads to a decrease in SBETs and external surface area. But, micropore volume and average pore diameter are presented in constant regular values with increasing amount of sulfuric acid treatment. SEM observes the surface morphology and crystal grown state of metal on the fiber surface. The results of EDX of Ag-activated carbon fiber pre-treated with acid show the spectra corresponding to almost all samples rich in silver with increasing the amount of acid treated. The FT-IR spectra of Ag-activated carbon fiber show that the acid pre-treatment is consequently associated with the homogeneous dispersion of metal with the increased surface acidity of the activated carbon fiber. The type and quality of oxygen groups are determined with Boehm titration method. From the those results, a positive influence of the acidic groups on the carbon fiber surface by acid treatment is also demonstrated by an increase in the contents of metallic silver with increasing of acidic groups.

• Journal of the Korean Applied Science and Technology
• /
• v.22 no.3
• /
• pp.250-256
• /
• 2005

This study was aimed to investigate treatment feasibility of leachate from D landfill that is located in gyr대ungbuk. From the analytical results of leachate, organic and nonbiodegradable matters were contained in high concentration. Thus chemical treatment was introduced to degrade nonbiodegradable matters in pre or post biological process. Two types of Fenton oxidation were adapted in this study. The first one is pre treatment process before biological treatment. The second one is post treatment process after biological treatment. The optimal conditions of both treatment methods were investigated as follows. In case of pre treatment process, the optimal conditions appeared in $Fe^{+2}/H_2O_2$(mmol/mmol): 0.1, $H_2O_2/CODcr$(mg/mg): 27.0, pH: 3 and reaction time: 2hrs. On the other hand, in case of post treatment process, the optimal conditions appeared in $Fe^{2+}$(mmol/mmol): 0.14, $H_2O_2/COD_{cr}$(mg/mg): 57.4, pH: 3 and reaction time: 1.25hrs. In the above optimal conditions, high COD removal was obtained in pre and post treatment process. Also it can expect that Fenton oxidation converted nonbiodegradable matters into biodegradable matters.