• Title/Summary/Keyword: chemical measurement

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Quantitative Measurement of Ethane Using Mid-infrared Cavity Ring-down Spectroscopy

  • Yonghee Kim;Byung Jae Chun;Lim Lee;Kwang-Hoon Ko;Seung-Kyu Park;Taek-Soo Kim;Hyunmin Park
    • Current Optics and Photonics
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    • v.7 no.4
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    • pp.457-462
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    • 2023
  • Quantitative measurement of trace ethane is important in environmental science and biomedical applications. For these applications, we typically require a few tens of part-per-trillion level measurement sensitivity. To measure trace-level ethane, we constructed a cavity ring-down spectroscopy setup in the 3.37 ㎛ mid-infrared wavelength range, which is applicable to multi-species chemical analysis. We demonstrated that the detection limit of ethane is approximately 300 parts per trillion, and the measured concentration is in agreement with the amounts of the injected sample. We expect that these results can be applied to the chemical analysis of ethane and applications such as breath test equipment.

Measurement of Water Flow in Closed Conduits by Chemical Tracer Method (추적자를 이용한 유량 측정)

  • Lee, Sun-Ki;Chung, Bag-Soon;Kim, Chang-Ho
    • The KSFM Journal of Fluid Machinery
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    • v.2 no.2 s.3
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    • pp.19-26
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    • 1999
  • Thermal output in a nuclear power plant is verified with calorimetric heat balance on the secondary plant. The calorimetry involves the precise measurement of the feedwater flow rate. However, the correct indication of feedwater flow rate obtained by a pressure-difference measurement across a venturi can be affected by instrument errors, fouling or a poorly developed velocity profile. This can result in an inaccurate mass flow rate and consequently an inaccurate estimate of power. The purpose of this study is to develop verification methods with accuracy better than $0.5\%$ for high precision flow measurement to be used for measuring feedwater flow rate. This chemical tracer method is a testing process that uses tracers which can be applied to quantify losses in electrical output due to the incorrect measurements of feedwater flow rate. And this system has good response to the variation of the flow rate. Accuracy of better than 0.5 percent can be expected for feedwater flow measurement, providing that the system can be stabilized during the test. This methodology is applicable to other flow systems well.

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Determination of Isotopic Ratios for Ca in Inductively Coupled Plasma Mass Spectrometry (ICPMS) by Removing Water Related Molecules

  • 박용남;S. R. Koirtyohann
    • Bulletin of the Korean Chemical Society
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    • v.18 no.11
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    • pp.1172-1175
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    • 1997
  • Calcium isotopic ratios are precisely measured by removing isobaric interferences originated from water in the plasma. Liquid Ar cryogenic trap combined with membrane desolvator could eliminate backgrounds at m/z 42 and 44. Slow drift of ICP-MS is corrected by the frequent running of the standards. It is found necessary to separate Ca from the sample matrix using Ca oxalate precipitation technique. Currently, the RSD is 0.5-1.0% for 2 minutes of measurement but is expected to be improved if the measurement time is increased. The technique was applied to 42Ca enriched baby fecal samples and successfully determined 42Ca/44Ca ratio changes.

Preparation and Characterization of the Asymmetric Microporous Poly(vinylidene fluoride) (PVDF) Blend Membranes with Hydrophilic Surfaces

  • Hwang, Jeong-Eun;JeGal, Jong-Geon
    • Korean Membrane Journal
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    • v.9 no.1
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    • pp.1-11
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    • 2007
  • To prepare chemically stable asymmetric microporous membranes with a hydrophilic surface, which would be expected to have better antifouling properties, poly(vinylidene fluoride) (PVDF) blend membranes were prepared by the phase inversion process. PVDF mixture solutions in N-methylpyrrolidone (NMP) blended with several polar potential ionic polymers such as polyacrylonitrile (PAN), poly(methylmethacrylate) (PMMA) and poly(N-isopropylacrylamide) (NIPAM) were used for the formation of the PVDF blend membranes. They were then characterized with several analytical methods such as FESEM, FTIR, contact angle measurement, pore size distribution and permeability measurement. Regardless of different polar polymers blended, they all showed a finger-like structure with more hydrophilic surface than the pristine PVDF membrane. For all the PVDF blend membrane, due to the polar potential ionic polymers used, the flux of those was improved. Especially the PVDF blend membrane with NIPAM showed the highest flux among the membranes prepared. Also antifouling property of the PVDF membrane was improved by the use of the polar polymers.

A Study on the Improvement of Decomposition Efficiency of Organic Substances Using Plasma Process and Catalytic Surface Chemical Reaction (플라즈마 프로세스 및 촉매 표면화학반응에 의한 유기화합물 분해효율 향상에 대한 연구)

  • Han, Sang-Bo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.5
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    • pp.932-938
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    • 2010
  • This paper proposed the effective treatment method for organic substances using the barrier discharge plasma process and catalytic chemical reaction followed from ozone decomposition. The decomposition by the plasma process of organic substances such as trichloroethylene, methyl alcohol, acetone, and dichloromethane carried out, and ozone is generated effectively at the same time. By passing through catalysts, ozone easily decomposed and further decomposed organic substances. And, 2-dimensional distribution of ozone using the optical measurement method is performed to identify the catalytic surface chemical reaction. In addition, CO is easily oxidized into $CO_2$ by this chemical reaction, which might be induced oxygen atom radicals formed at the surface of catalyst from ozone decomposition.

Characteristics of Electroantennogram Parameters for the Detection of Odorants

  • Yun, Eung-Sik;Ko, Hwi-Jin;Sun, Jong-Hwan;Park, Tai-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.10 no.6
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    • pp.885-888
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    • 2000
  • Electroantennogram(EAG) can be applied to detect odorants since insects have highly specialized olfactory receptors inside their antennae. The characteristics of EAG parameters were investigated for the quantitative measurement of a general odorant using ammonia as a model odorant. The antennae of male silkworm moth, Bombyx mori, were used for the EAG. The electical signal curves generated from a pair of antennae originating from the same silkworm moth were never identical; however, they exhibited a typical type I or type II characteristic curve pattern for every pair of antennae. The correlation between the EAG parameters and the ammonia concentration was analyzed for the type I and type II antennae. The stability of each parameter was also investigated for each type of antenna. The results show the possibility of the quantitative measurement of general odorants using the EAG technique.

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