• Title/Summary/Keyword: chemical index

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Fabrication of Optical Fiber Preform by MCVD Method (MCVD법을 이용한 광섬유 모재의 제작)

  • 이기완;홍봉식
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.14 no.4
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    • pp.307-320
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    • 1989
  • This paper presetns new design of the Modified Chemical Vapor Deposition(MCVD) system for optical fiber preform fabrication. It contains a glass working lathe, raw material supplier and exhaust gas treatment apparatus as fundamental instruments for MCVD process, graded index fiber design, characteristic of process and the experimenta arrangement to measure the refractive index profile of MCVD preforms, respectively. From the investigation results, it is shown that an ideal graded index fiber preform does not exhibit a center dip or bump.

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Photorefractive Performance of Poly[methyl-3-(9-carbazolyl) propylsiloxane] Based Composites Sensitized with Poly(3-hexylthiophene) in a 0.2-1wt % Range

  • Oh, Jin-Woo;Kim, Nak-Joong
    • Bulletin of the Korean Chemical Society
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    • v.31 no.1
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    • pp.41-46
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    • 2010
  • In this work, we report on the characterization of six low-$T_g$ poly[methyl-3-(9-carbazolyl) propylsiloxane] based photorefractive (PR) composites sensitized with poly(3-hexylthiophene) (P3HT) in different concentrations, ranging from 0.2 to 1 wt %. At 632.8 nm, photoconductivity, space charge field, refractive index modulation, and grating buildup time were measured versus external electric field. The photoconductivity was strongly dependent on the visible light absorption and mobility. The magnitude of space charge field was affected by the conductivity contrast $\sigma_{ph}/(\sigma_{ph}+\sigma_d)$. The refractive index modulation increased with the magnitude of space charge field and the PR grating buildup speed increased with the photoconductivity.

Synthesis and Characterization of Fluorinated Poly(phenylmaleimide-co-pentafluorophenylmaleimide) for Optical Waveguides

  • Choi, Jongwan;Oh, Jin-Woo;Kim, Nakjoong
    • Bulletin of the Korean Chemical Society
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    • v.34 no.4
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    • pp.1077-1080
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    • 2013
  • Fluorinated polymaleimides with high thermal stability and low optical absorption loss in the optical communication wavelength of $1.55{\mu}m$ were investigated for application in low-loss waveguide materials. The fluorinated polymaleimides were prepared from two monomers phenylmaleimide (H-PMI) and pentafluorophenylmaleimide (F-PMI). All synthesized copolymers had high thermal stability (decomposition temperature $(T_d)=380-430^{\circ}C$). The refractive index of the copolymers could be tuned from 1.4969 to 1.5950 in the TE mode and from 1.4993 to 1.5932 for the TM mode at 632.8 nm by copolymerizing different weight ratios of H-PMI and F-PMI. The refractive index of the copolymers decreased with increasing F-PMI content. In addition, when the amount of F-PMI was increased, optical loss and absorption loss at 632.8 nm and 1550 nm, respectively, decreased.

The Calculation of Physical Properties of Amino Acids using Molecular Modeling Techniques

  • Ui-Rak Kim;Kyung-Sub Min;Bong-Jin Jeong
    • Bulletin of the Korean Chemical Society
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    • v.15 no.2
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    • pp.106-112
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    • 1994
  • Six physical properties (molecular weight, heat capacity, side chain weight, side chain volume, standard entropy and partial molar volume) of amino acids, peptides and their derivatives were examined by molecular modeling techniques. The molecular connectivity index, Wiener distance index and ad hoc descriptor are employed as structural parameters to encode information about branching, size, cyclization, unsaturation, heteroatom content and polarizability. This paper examines the correlation of the molecular modeling techique's parameters and the physicochemical properties of amino acids and their derivatives. As a result, calculated values were in agreement with experimental data in the above six physical properties of amino acids, peptides and their derivatives and the molecular connectivity index was superior to the other indices in fitting the calculated data.

Characteristics of Membrane Fouling and Nitrification in Nitrifying Membrane Bioreactor (Nitrifying membrane bioreactor에서의 막 오염 및 질산화 특성)

  • Lim, Kyoung-Jo;Hong, Soon-Ho;Yoo, Ik-Keun
    • Journal of Environmental Science International
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    • v.20 no.9
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    • pp.1079-1085
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    • 2011
  • The purpose of this study is to find the operational characteristics of nitrifier-dominated membrane bioreactor (MBR), which has been extensively studied for organic removal, especially in terms of nitrite ($NO_2$-N) build-up and membrane fouling. Membrane fouling is one of the important factor which determines the economics of MBR system. The characteristics of membrane fouling was monitored in terms of the fouling indices such as sludge volume index (SVI), the concentration of total organic carbon (TOC) and extracellular polymeric substances (EPS) in a membrane permeate or sludge extract, the absorbance of supernatant at 260 nm. Most of index values except for protein concentration in EPS had a close relation with the increase of suction pressure and SVI value. Nitrifying MBR was superior to the conventional organic-oxidizing MBR in terms of membrane fouling since the fouling index value of nitrifying MBR was lower than that of BOD-oxidizing MBR.

Effectuality of Cleaning Workers' Training and Cleaning Enterprises' Chemical Health Hazard Risk Profiling

  • Suleiman, Abdulqadir M.;Svendsen, Kristin V.H.
    • Safety and Health at Work
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    • v.6 no.4
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    • pp.345-352
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    • 2015
  • Background: Goal-oriented communication of risk of hazards is necessary in order to reduce risk of workers' exposure to chemicals. Adequate training of workers and enterprise priority setting are essential elements. Cleaning enterprises have many challenges and the existing paradigms influence the risk levels of these enterprises. Methods: Information on organization and enterprises' prioritization in training programs was gathered from cleaning enterprises. A measure of enterprises' conceptual level of importance of chemical health hazards and a model for working out the risk index (RI) indicating enterprises' conceptual risk level was established and used to categorize the enterprises. Results: In 72.3% of cases, training takes place concurrently with task performances and in 67.4% experienced workers conduct the trainings. There is disparity between employers' opinion on competence level of the workers and reality. Lower conceptual level of importance was observed for cleaning enterprises of different sizes compared with regional safety delegates and occupational hygienists. Risk index values show no difference in risk level between small and large enterprises. Conclusion: Training of cleaning workers lacks the prerequisite for suitability and effectiveness to counter risks of chemical health hazards. There is dereliction of duty by management in the sector resulting in a lack of competence among the cleaning workers. Instituting acceptable easily attainable safety competence level for cleaners will conduce to risk reduction, and enforcement of attainment of the competence level would be a positive step.

Speciation and Ecological Risk Assessment of Trace Metals in Surface Sediments of the Masan Bay (마산만 표층퇴적물에서 미량금속의 화학적 존재형태 및 생태계 위해도 평가)

  • Sun, Chul-In;Lee, Young-Ju;An, Jung-Hyun;Lee, Yong-Woo
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.19 no.2
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    • pp.155-163
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    • 2014
  • Total concentration and chemical speciation of trace metals (Cu, Pb, Zn, Cd, and Ni) were determined to evaluate pollution level and potential ecological risk in surface sediments of the Masan Bay. The results showed that the trace metal concentrations, except for Ni, were high in the inner Masan Bay. Based on the chemical speciation of metals in sediments, the percentage of total concentrations of Cd and Pb in non-residual fraction was 92% and 88%, respectively, indicating that these metals originated mainly from anthropogenic sources. However, Ni (70%) was dominant in residual fraction. Pollution load index (PLI) and ecological risk index (ERI) values in the inner bay indicate the presence of anthropogenic pollution and considerable-moderate ecological risk, respectively. Ecological index (Ei) value for Cd was high at most stations in the Masan Bay, and Cd content was the highest in acid soluble fraction, which presents the highest ecological risk. The results obtained in this study indicate that Cd presents a high potential ecological risk to benthic biota in the Masan Bay.

Uncertainty and Manufacturing Stock Market in Korea

  • Jeon, Ji-Hong
    • The Journal of Industrial Distribution & Business
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    • v.10 no.1
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    • pp.29-37
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    • 2019
  • Purpose - We study the dynamic linkages of the economic policy uncertainty (EPU) in the US on the manufacturing stock market returns in Korea. In detail, we examine the casual link between EPU index in the US and the manufacturing stock indexes in Korea. Research design, data, and methodology - We measure mainly the distribution effect of the US EPU on the manufacturing stock market in Korea of 1990-2017 by the vector error correction model (VECM). Result - In result, we estimate the impact of the US EPU index has significantly a negative response to the manufacturing stock market in Korea such as non-metal stock index, chemical stock index, food stock index, textile·clothes stock index, automobile·shipbuilding stock index, machinery stock index, steel·metal stock index. Also the remaining variables such as electric·electronics stock index, S&P 500, and producer price index in Korea have a negative relationship with US EPU index. Conclusions - We find out that the relationship between EPU index of the US and the manufacturing stock market in Korea has the negative relationships. We determine the EPU of the US has the spillover effect on the industry stock markets in Korea.

Indoor exposure to hazardous air pollutants and volatile organic compounds in low-income houses in Lagos, Nigeria

  • Luqmon, Azeez;Musa, Olaogun;Mariam, Adeoye;Abdulazeez, Lawal;Babatunde, Agbaogun;Ibrahim, Abdulsalami;Adija, Majolagbe
    • Advances in environmental research
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    • v.1 no.4
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    • pp.277-288
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    • 2012
  • This study investigated exposure to air pollutants in rooms in low-income houses at Shomolu (R1), Mafoluku (R2) and Mushin (R3) in Lagos state. The concentrations of most measured exceeded limits of Illinois Department of Public Health (IDPH) for indoor air quality. Air quality index (AQI) in rooms studied was unhealthy for sensitive people in terms of CO, unhealthy in terms of $SO_2$ and very unhealthy in terms of $NO_2$ while moderate air quality was obtained in terms of $PM_{10}$ in most rooms. High concentrations of carbontetrachloride, formaldehyde and xylene measured could have been responsible for some of the health complaints of the occupants. Factor analysis shows that cooking with kerosene, use of gasoline generator and insecticide were the major contributors to indoor air pollution in these rooms. Therefore, there is need to urgently tackle poverty as all affected by these pollutants were poor who live in substandard houses without kitchens.

Thermophysical Properties of Acetophenone with Ethylchloroacetate at Temperatures of 303.15, 313.15 and 323.15 K

  • Saravanakumar, K.;Baskaran, R.;Kubendran, T.R.
    • Journal of the Korean Chemical Society
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    • v.56 no.4
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    • pp.424-430
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    • 2012
  • Densities, viscosities, refractive indices and speed of sounds of the binary mixtures of Acetophenone with Ethylchloroacetate were measured over the entire mole fractions at (303.15, 313.15 and 323.15) K. From these experimental results, excess molar volume $V^E$, viscosity deviation ${\Delta}{\eta}$, refractive index deviation ${\Delta}n_D$, deviations in speed of sound ${\Delta}u$, deviations in isentropic compressibility ${\Delta}k_s$ and excess intermolecular free length ${\Delta}L_f$ were calculated. The viscosity data have been correlated with the equations of Grunberg and Nissan, Hind et al., Tamura and Kurata, Katti and Chaudri, Sedgwick, Krishnan-Laddha and McAllister. The thermo physical properties under study were fit to the Jouyban-Acree model. The excess values were correlated using Redlich-Kister polynomial equation to obtain their coefficients and standard deviations. It was found that in all cases, the data obtained fitted with the values correlated by the corresponding models very well. The results are interpreted in terms of molecular interactions occurring in the solution.