• Journal of Powder Materials
• /
• v.25 no.2
• /
• pp.109-119
• /
• 2018

The objective of this study is to reveal the sintering mechanism of mixed Ti-6Al-4V powders considering the densification and the homogenization between Ti and Al/V particles. It is found that the addition of master alloy particles into Ti enhances densification by the migration of Al into the Ti matrix prior to the self-diffusion of Ti. However, as Ti particles become coarser, sintering of the powders appears to be retarded due to slower inter-diffusion of the particles due to the reduced surface energies of Ti. Such phenomena are confirmed by a series of dilatometry tests and microstructural analyses in respect to the sintering temperature. Furthermore, the results are also consistent with the predicted activation energies for sintering. The energies are found to have decreased from 299.35 to $135.48kJ{\cdot}mol^{-1}$ by adding the Al/V particles because the activation energy for the diffusion of Al in ${\alpha}-Ti$ ($77kJ{\cdot}mol^{-1}$) is much lower than that of the self-diffusion of ${\alpha}-Ti$. The coarser Ti powders increase the energies from 135.48 to $181.16kJ{\cdot}mol^{-1}$ because the specific surface areas of Ti decrease.

• Journal of Korea Foundry Society
• /
• v.35 no.6
• /
• pp.170-177
• /
• 2015

Segregation during solidification and homogenization during thermal exposure in GTD 111 were investigated. The microstructures of as-cast, standard heat-treated, and thermally exposed specimens were observed by SEM. A compositional analysis of each specimen was conducted by EDS. The dendrite core was enriched in W and Co, though lower levels of Ti and Ta were observed. An unexpected phase, in this case like the ${\eta}$ phase, was observed due to segregation near the ${\gamma}-{\gamma}^{\prime}$ eutectic in the standard heat-treated specimen. Segregation also induced microstructural evolution near the ${\gamma}-{\gamma}^{\prime}$ eutectic during the standard heat treatment. A quantitative analysis and microstructural observations showed that the thermal exposure at a high temperature enhanced the chemical homogeneity of the alloy.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.24 no.4
• /
• pp.413-419
• /
• 2011

The nano-size hoenycomb structures have the higher ratio of the surface to the volume than macro-size honeycomb structures, and they can maximize the functionality of the electrical and chemical catalyst. The mechanical behaviors of the nano-sized structures are different from ones of the macro-size structure, and it is caused by the surface effect. This surface effect can be investigated by the atomistic simulation; however, the prediction of mechanical behaviors of the nano-sized honeycombs are practically impossible due to excessive computational resources and computation time. In this paper, by combining the bridging method considering the surface stress elasticity model with homogenization method, the mechanical behaviors of the nano-sized honeycombs are predicted efficiently.

• Journal of the Mineralogical Society of Korea
• /
• v.25 no.4
• /
• pp.211-220
• /
• 2012

The numerical modeling and simulation have been used increasingly as tools for examining and interpreting the bulk structure and properties of materials. The use of molecular dynamics (MD) simulations to model the structure of materials is now both widespread and reasonably well understood. In this research, we introduced the numerical method to calculate the physico-chemical properties such as a diffusion coefficient and a viscosity of clay mineral. In this research, a series of MD calculations were performed for clay mineral and clay-water systems, appropriate to a saturated deep geological setting. Then, by using homogenization analysis (HA), the diffusion coefficients are calculated for conditions of the spatial distribution of the water viscosity associated with some configuration of clay minerals. This result of numerical analysis is quite similar to the previous experimental results. It means that the introduced numerical method is very useful to calculate the physico-chemical properties of clay minerals under various environmental conditions.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.3
• /
• pp.956-960
• /
• 2011

The objective of this investigation was to develop nanostructured lipid carriers (NLCs) of tacrolimus by the hot homogenization technique by sonication. NLCs are commonly prepared by emulsification and lyophilization. The feasibility of fabricating tacrolimus-loaded NLCs was successfully demonstrated in this study. The developed NLCs were characterized in terms of their particle size, zeta potential, entrapment efficiency (EE) of tacrolimus, and morphology. Studies were conducted to evaluate the effectiveness of the NLCs in improving the penetration rate through hairless mouse skin. Tacrolimus-loaded NLCs were found to have an average size of $123.4{\pm}0.3\;nm$, a zeta potential of $-24.3{\pm}6.2\;mV$, and an EE of 50%. In vitro penetration tests revealed that the tacrolimus-loaded NLCs have a penetration rate that is 1.64 times that of the commercial tacrolimus ointment, Protopic$^{(R)}$.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.1
• /
• pp.157-161
• /
• 2011

For the fabrication of multifunctional biopolymer nanocomposites in the combination of carbon nanotubes (CNTs), recently increasing attention has been paid to an effective homogenization of CNTs within polymer matrices and a fine tuning of the concentration. We developed an efficient method to produce homogeneous CNT-polycaprolactone nanocomposites with various and controllable CNT concentrations using an ionically-modified multi-walled CNT, MWCNT-Cl. The modified MWCNTs could be homogeneously dispersed in tetrahydrofuran (THF). Polycaprolactone (PCL) as a biodegradable and biocompatible polymer was smoothly dissolved in the homogeneous MWCNT-Cl/THF solution without agglomeration of MWCNT-Cl. The physicochemical and mechanical properties of the resultant nanocomposites were examined and the biological usefulness was briefly assessed.

• Journal of the Korean Ceramic Society
• /
• v.44 no.1 s.296
• /
• pp.1-5
• /
• 2007

Fining and homogenization of melts during batch melting is closely related to the redox reaction of polyvalent element M (M: Sb, As etc), $M^{(x+n)+}+n/2O^{2-}{\rightarrow}M^{x+}+n/4O_2$. In this study, square wave voltammetry (SWV) measurements were performed to examine the redox behavior of an antimony ion in cathode ray tube (CRT) glass melts. According to results, well-separated two peaks are shown at low temperature while only one peak is shown at high temperature in voltammograms, which reveals that redox reaction of antimony consist of two steps: $Sb^{5+}/Sb^{3+}\;and\;Sb^{3+}/Sb^0$, depending on the temperature. Based on the peak potential shown in the voltammogram, the thermodynamic data and the redox ratio for two redox couple were determined.

• Journal of Powder Materials
• /
• v.10 no.5
• /
• pp.305-309
• /
• 2003

We report on the formation and chemical leaching of non-equilibrium $Al_{0.6}(Fe_{75}Co_{25})$ alloy produced by rod milling. X-ray diffractometry, transmission electron microscopy, differential scanning calorimetry, scanning electron microscopy, and vibrating sample magnetometry were used to characterize the as-milled and leached specimens. After 400 h, only the $Al_{0.4}Fe_{0.6}$ peak of the body-centered cubic type was present in the XRD pattern. The entire rod milling process could be divided into three different stages of milling: agglomeration, disintegration, and homogenization. The saturation magnetization, $M_s$ decreased with increased milling time, the $M_s$ of the powders before milling was about 113.8 emu/g, the $M_s$ after milling for 400 h was about 11.55 emu/g. Leaching of the Al in KOH of the Al at room temperature from the as-milled powders did not induce any significant change in the diffraction pattern. After the leached specimen had been annealed at $600^{\circ}C$ for 1 hour, the nanoscale crystalline phases were transformed into the bcc Fe, cubic Co, and $CoFe_2O_4$ phases. On cooling the specimen from 85$0^{\circ}C$, the degree of magnetization increased slightly, then increased sharply at approximately 364.8$^{\circ}C$, indicating that the bcc $Al_{0.4}Fe_{0.6}$ phase had been transformed to the Fe and Co phases.

• Advances in concrete construction
• /
• v.17 no.2
• /
• pp.111-126
• /
• 2024

During the clinkering stages of cement production, the chemical composition of fine raw materials such as limestone and clay, which include iron oxide (Fe₂O₃), silicon dioxide (SiO₂) and aluminum oxide (Al₂O₃), significantly influences the quality of the final product. Specifically, the chemical interaction of Fe₂O₃ with CaO, SiO₂ and Al₂O₃ during clinkerisation plays a key role in determining the chemical reactivity and overall quality of the final cement, shaping the properties of the concrete produced. As an extension, this study aims to investigate the physical effects of incorporating nanosized Fe₂O₃ particles as fillers in concrete matrices, and their impact on concrete structures, namely slabs. To accurately model the reinforced concrete (RC) slabs, a refined trigonometric shear deformation theory (RTSDT) is used. Additionally, the stochastic Eshelby's homogenization approach is employed to determine the thermoelastic properties of nano-Fe₂O₃ infused concrete slabs. To ensure comprehensive coverage in the study, the RC slabs undergo various mechanical loads and are exposed to temperature fields to assess their thermo-mechanical performance. Furthermore, the slabs are assumed to rest on a three-parameter viscoelastic foundation, comprising the Winkler elastic springs, Pasternak shear layer and a damping parameter. The equilibrium governing equations of the system are derived using the principle of virtual work and subsequently solved using Navier's technique. The findings indicate that while ferric oxide nanoparticles enhance the mechanical properties of concrete against mechanical loading, they have less favorable effects on its performance against thermal exposure. However, the viscoelastic foundation contributes to mitigating these effects, improving the concrete's overall performance in both scenarios. These results highlight the trade-offs between mechanical and thermal performance when using Fe₂O₃ nanoparticles in concrete and underscore the importance of optimizing nanoparticle content and loading conditions to improve the structural performance of concrete structures.

• Archives of Metallurgy and Materials
• /
• v.65 no.4
• /
• pp.1255-1259
• /
• 2020

This paper aims to investigate the microstructural evolution and mechanical properties of hot-deformed AlMg4 alloys with Mn, Fe, and Si as the main impurities. For this purpose, solidification behavior and microstructural evolution during hot-rolling and heat-treatment processes are investigated by using theoretical calculations and experimental characterization. The crystallization and morphological transformation of intermetallic Al₃Fe, Al₆Mn, and Mg₂Si phases are revealed and discussed in terms of the variation in chemical composition. Following a homogenization heat-treatment, the effect of heat treatment on the intermetallic compounds is also investigated after hot-rolling. It was revealed that the Mg₂Si phase can be broken into small particles and spherodized more easily than the Al₃Fe intermetallic phase during the hot-rolling process. For the Mn containing alloys, both yield and ultimate tensile strength of the hot-rolled alloys increased from 270 to 296 MPa while elongation decreased from 17 to 13%, which can be attributed to Mn-containing intermetallic as well as dispersoid.