• Title/Summary/Keyword: chemical concentrations

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The prediction of emission concentrations in spark ignition engine using methanol as a fuel (Methanol을 연료로 한 전기점화 기관의 배출물 농도예측에 관한 연구)

  • 김응서;김상호
    • Journal of the korean Society of Automotive Engineers
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    • v.5 no.1
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    • pp.79-88
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    • 1983
  • A prediction of emission concentrations was made by calculating chemical equilibrium on the basis of an indicated pressure diagram in spark ignition engine using methanol as a fuel. A prediction according to Otto cycle was also made and for carbon dioxide, carbon monoxide and nitric oxide, emission test was performed using a conventional SI engine that was modified a little considering fuel characteristics. An investigation was made for those three cases-results from an indicated pressure diagram, Otto cycle and emission test. A good agreement between the measured values and the predicted ones existed for carbon dioxide and carbon monoxide, but not for nitric oxide. And good results existed for the other emission concentrations.

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A Study on the Effect of P Concentrations of PSG Interlayers on the Yield Characteristics of the NMOS Devices (층간 절연막으로 쓰이는 PSG막의 P농도가 NMOS소자의 수율에 미치는 영향에관한 연구)

  • 김성필;박재근;조병섭;곽계달
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.11
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    • pp.1637-1643
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    • 1989
  • In this study, phosphosilicate glass(PSG) film was deposited by the oxidation of phosphine (PH3) and silane(SiH4) in nitrogen ambient with a conventional conveyerized Atmospheric Pressure Chemical Vapor Deposition(APCVD)system and phosphorus concentration is measured by using FT-IR technique. The flow characteirstics and etch rate variations ofthe films, depending on phosphorus concentrations, are investigated. Special emphasis is focused on the yield variations of NMOS-based 256K DRAM with 1.2\ulcorner metallization spacing with increasing phosphorus concentrations. As a result, the data indicates that the fairly good yield can be obtained within the range of between 8 and 10wt% phosphorus concentration, which result in a slope of flow within 45\ulcorner10\ulcorner The analysi of failure mechanism is also accompanied.

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Factors Affecting Ambient Monoterpene Levels in a Pine Forest

  • Kim, Jo-Chun;Kim, Ki-Hyun
    • Journal of Environmental Science International
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    • v.11 no.8
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    • pp.811-818
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    • 2002
  • The concentration levels of monoterpenes, including ${\alpha}$- and ${\beta}$-pinene, were measured in a pine forest in Florida, USA, over about one year. Based on this measurement data, the current study then investigated the factors affecting the environmental behavior of monoterpenes. Despite a moderately weak temperature variability in the study area, the temperature dependence of the concentration variations was still evident. The concentrations of the two pinenes were significantly affected by changes in the air temperature, as indicated by strong correlations with temperature. A close relation among the measured parameters was also found between the ${\beta}$-pinene and ozone concentrations, which is also in line with previous findings from other studies. In addition, it was interesting to note that the ${\beta}$/${\alpha}$ pinene concentration ratio exhibited a strong inverse correlation to temperature, with the seasonal mean ranging from 0.51(summer) to 0.93(winter). Accordingly, the current results indicate that, in a forest environment, the major terpene species concentrations are affected by both meteorological conditions and chemical reactions.

Transport and Loadings of Nutrients and Dissolved Major and Trace Elements in the Yeongsan River, Korea

  • Cha Hyun-Ju;Cho, Yeong-Gil
    • Journal of the korean society of oceanography
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    • v.37 no.2
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    • pp.66-75
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    • 2002
  • Temporal variation of nutrients and dissolved major and trace elements have been studied in the Yeongsan River, Korea. There were significant temporal fluctuations in the concentrations of these elements depending upon the flow condition. $NH_4$, $PO_4$, Na, Mg, Ca, K, Mn, Cu, Ni, Zn, Co, As and U concentrations were inversely related to the flow; that is, they are the highest at low flow and the lowest at high flow. It indicates that these elements are derived from point sources such as rock weathering and/or human activities and then diluted by increasing flow. Meanwhile, Fe and Si concentrations varied proportionally to the flow indicating that they are derived from diffuse sources including reactions within soil. The concentration-flow relationships showed that hydrology of the river is the most important factor controlling the chemical composition of the Yeongsan riverwater, which was compatible of the results of R-mode factor analysis.

Monitoring of Stream water and Groundwater Contamination at the Ilgok landfull Site in kwangju, Korea (광주지역 일곡 매립지 주변에서의 하천수 및 지하수 오염 모니터링)

  • 차종문
    • Economic and Environmental Geology
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    • v.32 no.5
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    • pp.485-493
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    • 1999
  • In order to dermine the degree of contamination for the Ilgok landfill site, stream water, groundwater and stream sediment samples were collected in 1998 and 1999, and analyzed for physico-chemical properties. The stream water contains significanr concentrations of TDS $HCO_3^-$and $NO_3^-$, and ground-water is polluted by $NO_3^-$ up to the drinking water standard from landfill leachate. From the point of the horizontal movement of elements, stream water IL-2 at the conjunction point with landfill leachate reached the most high concentrations of $HCO_3^-,Cl^-,Na^+, K^+, NO_3^-,Mg{^2+}$ and $SO_4^{2-}$stream water Il-3 shows the high concentrations of $Ca^{2+}, Pb^{2+}$ and $Mg^{2+}$. The optimum contamination indicator of Ilgok landfill site is $HCO_3^-, C^l-, Na^+, Mn^{2+}$ and TDS from the calculation of contamination factor.

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THE COMPARISONS OF VOLATILE OILS OF FLUE-CURED TOBACCO PRODUCED IN KOREA AND IN THE UNITED STATES (한미산 황색종 잎담배의 휘발성 정유성분 비교연구)

  • 장기운
    • Journal of the Korean Society of Tobacco Science
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    • v.7 no.2
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    • pp.151-167
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    • 1985
  • Generally, the same quality tobacco may give similar concentration of each chemical component. This research investigation was studied to obtain the differences in concentrations of volatile oil compounds in physically similar tobacco produced in different environment and managements-in Korea and in the United States. The flue-cured leaf tobacco produced in Korea and America was regraded to B3L and P3L by American grading system and analyzed for volatile oils relating to tobacco flavor and aroma. Sixty compounds of the more than 100 peaks distinguishable on the total neutral volatile oils were identified by G5-MS and quantified. Their concentrations are compared between B3 L and P3L produced in Korea and in the United States. The most volatile oil concentrations of B3 L and P3L grade tobacco arc higher in American than in Korean. Only a few components such as benzaldehyde, pulegonc, 4, 6, 9 - megastigmatriene - 3 - one, and coumaran are less in American.

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Environmental Pollutants Drained From Highway Pavement Road

  • Takemura, Shinsaku;Goto, Naoshige;Mitamura, Osamu
    • Korean Journal of Ecology and Environment
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    • v.38 no.spc
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    • pp.58-61
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    • 2005
  • Environmental polluting materials from road surface drainage are a significant nonpoint source influenced to the eutrophication of lake and ecosystems with a transport development in recent years. To elucidate the discharge characteristics, the changing patterns in concentrations of polluting materials such as suspended solid (SS), chemical oxygen demand (COD), nitrogenous and phosphorus nutrients in drainage waters, were investigated during rainfall. Load variation of COD concentration in drainage water samples was closely related to that of SS concentration. This indicates that SS contained a greater part of organic matter. A quite difference between the past pavement and the new well-drainage pavement system was observed in the concentrations of SS and COD in drainage waters. Appreciable concentrations of nitrite and nitrate were determined in drainage waters. The present results indicate that the drainage water from road surfaces is a significant nonpoint source, and that the well-drainage pavement system introduced to skid prevention has an effect on the decreases of pollutants.

Dispersion Polymerization of Acrylamide in Methanol/Water Media

  • Lee, Ki-Chang;Lee, Seung-Eun;Song, Bong-Keun
    • Macromolecular Research
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    • v.10 no.3
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    • pp.140-144
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    • 2002
  • Dispersion polymerization of acrylamide was carried out in the media of methyl alcohol/$H_2O$ mixtures using hydroxypropyl cellulose and ammonium persulfate as steric stabilizer and initiator, respectively. The effects of concentrations of initiator and steric stabilizer, amount of monomer, polymerization temperature, methyl alcohol/$H_2O$ ratio, and purification of monomer and nitrogen purge on the particle size of the latices and molecular weight of the polymers were investigated. The average particle diameter increased with increasing concentration of initiator, water content in methyl alcohol/$H_2O$ media, and polymerization temperature, but decreased with monomer and stabilizer concentrations. The viscosity average molecular weight increased with increasing concentrations of monomer, steric stabilizer, and water content in dispersion media, but decreased with initiator concentration and polymerization temperature. The PAM polymers prepared with the purified monomer and the nitrogen purging before the reaction showed the highest molecular weight.

Experimental Assessment of Biomass Gasification for Hydrogen Production (수소생산을 위한 바이오매스 가스화 반응의 실험적 고찰)

  • Hong, Seong Gu;Um, Byung Hwan
    • Journal of The Korean Society of Agricultural Engineers
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    • v.64 no.5
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    • pp.1-8
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    • 2022
  • Hydrogen can be produced by gasification of biomass and other combustible fuels. Depending on oxydant agents, syngas or producer gas compositions become quite different. Since biomass has limited amount of hydrogen including moisture in it, the hydrogen concentration in the syngas is about 15% when air is supplied for oxidant agent. Experiments were conducted to investigate the channges in hydrogen concentrations in syngas with different oxidant agent conditions, fuel conditions, and external heat supply. Allothermal reaction resulted in higher concentrations of hydrogen with the supply of steam over air, reaching over 60%. Hydrogen is produced by water-gas and water-gas shift reactions. These reactions are endothermic and require enough heat. Autothermal reaction occurred in the downdraft gasifier used in the experiment did not provide enough heat in the reactions for hydrogen production. Steam seems a more desirable oxidant agent in producing the syngas with higher concentrations of hydrogen from biomass gasifications since nitrogen is included in syngas when air is used.

PRODUCTION OF GINSENOSIDES THROUGH IN VITRO CULTURE OF GINSENG(Panax ginseng C.A. MEYER)

  • Choi K.T.;Ahn I.O.;Park J.C.
    • Proceedings of the Ginseng society Conference
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    • 1993.09a
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    • pp.143-149
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    • 1993
  • Ginseng root explants and calli induced from selected cell lines were cultured on modified Murashige and Skoog's media supplemented with different concentrations of organic or inorganic compounds and plant growth requlators to clarify the effects of chemical composition and plant growth regulators in the medium on the growth of ginseng calli and the production of ginseng saponin. For optimum growth of calli, the concentrations of 2, 4-D and sucrose were the range of 1 to 3 mg/${\ell}$l and 1 to $3\%,$ respectively. And it was clarified that sucrose, nitrogen, phosphate, calcium, magmesian plant growth regulators and their concentrations influcenced the relative biosynthesis of saponin in tissue cultures of Panax ginseng. The patterns of ginsenosides, pharmacologically useful component, were different among the cell lines and contents of ginsenosides were much higher in selected cell lines than in original cell line.

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