• Title/Summary/Keyword: chemical composition, mineral

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Synthesizing and Assessing Fire-Resistant Geopolymer from Rejected Fly Ash

  • An, Eung-Mo;Cho, Young-Hoon;Chon, Chul-Min;Lee, Dong-Gyu;Lee, Sujeong
    • Journal of the Korean Ceramic Society
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    • v.52 no.4
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    • pp.253-263
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    • 2015
  • Ordinary Portland cement is a widely favored construction material because of its good strength and durability and its reasonable price; however, spalling behaviour during fire exposure can be a serious risk that can lead to strength degradation or collapse of a building. Geopolymers, which can be synthesized by mixing aluminosilicate source materials such as metakaolin and fly ash, and alkali activators, are resistant to fire. Because the chemical composition of geopolymers controls the properties of the geopolyers, geopolymers with various Si:Al ratios were synthesized and evaluated as fire resistant construction materials. Rejected fly ash generated from a power plant was quantitatively analyzed and mixed with alkali activators to produce geopolymers having Si:Al ratios of 1.5, 2.0, and 3.5. Compressive strength of the geopolymers was measured at 28 days before and after heating at $900^{\circ}C$. Geopolymers having an Si:Al ratio of 1.5 presented the best fire resistance, with a 44% increase of strength from 29 MPa to 41 MPa after heating. This material also showed the least expansion-shrinkage characteristics. Geopolymer mortar developed no spalling and presented more than a 2 h fire resistance rating at $1,050^{\circ}C$ during the fire testing, with a cold side temperature of $74^{\circ}C$. Geopolymers have high potential as a fire resistant construction material in terms of their increased strength after exposure to fire.

대홍활석광상 주위의 편마암류의 지화학적 특징과 공존광물의 화학적 평형

  • 이상헌;최기주
    • The Journal of the Petrological Society of Korea
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    • v.3 no.2
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    • pp.138-155
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    • 1994
  • Granitic gneiss containing biotite banded gneiss relict around the Daeheung talc deposit are widely distributed which were formed by regional metamorphism of both epidote-amphibolite and iater greenschist facies and granitization. They were derived from same silico-aluminous rocks of sedimentary origin. The mineral assemblages, which are common in the biotite banded gneiss, formed during regional metamorphisms, are survived in the granitic gneiss. The mineral assemblages of the latter greenschist facies may be formed retrogressively from the first epidote-amphibolite facies. The chemical compositions of biotite, muscovite, and chlorite, the important constituents of the gneisses, were controlled by the bulk composition, the chemical composition of the original mineral, and environment of the regional metamorphisms and granitization. The chemical equilibrium between coexisting'minerals, especially biotite and muscovite, is relatively well established, which was controlled mainly by tschermakitic and phengitic substitutions. Cholrite was formed mainly from either biotite or muscovite by retrogressive alteration or granitization, and have nearly similar chemical compositions regardless of the occurrences. The orientation trend of the foliation, joint and quartz vein developed in the gneisses was analyzed by equal area projection which the latter two show nearly identical trend in the strike and dip. This may suggest that the hydrothermal solution was introduced along joint during wet granitization.

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Effect of Well Depth, Host Rocks and Mineralization Zone on Hydrochemical Characteristics of Groundwater in the Umsung Area (음성지역 지하수의 수리화학적 특성에 대한 심도, 모암 및 광화대의 영향)

  • Jeong Chan Ho;Lee Byung Dae;Sung Ig hwan;Cho Byung Uk
    • The Journal of Engineering Geology
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    • v.14 no.4 s.41
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    • pp.469-485
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    • 2004
  • The purpose of this study is to investigate the hydrochemical characteristics of groundwater in the Umsung area, and to elucidate the effect of host rock type, well depth and mineralization zone on the groundwater chemistry. The geology of the study area consists of Jurassic granite and Cretaceous sedimentary rocks, which are bounded by a fault. Most of shallow groundwaters exploited in the Jurassic granite area are used for agricultural purpose, whereas the deep groundwaters in the Cretaceous sedimentary rocks are used for a drinking water. The shallow groundwater shows weak acidic pH, the electrical conductivity ranging from $142\;to\;903\;{\mu}S/cm$, and the chemical type of $Ca-HCO_3\;to\;Ca-Cl(SO_4,\;NO_3)$. A few of shallow groundwaters are contaminated by nitrate, and show high concentration of Fe, Mn and Zn, that reflects the effect of a mineralization zone. The deep groundwater shows neutral to weak alkaline pH, higher electrical conductivity than that of shallow groundwater, and the chemical type of $Ca-HCO_3$. The seepage water from the abandoned mines does not have the characteristics such as acidic pH, high concentration of heavy metals and high sulfate content. The hydrogen and oxygen isotopes of groundwater indicates an altitude effect of the recharge area between deep groundwater and shallow groundwater. In conclusion, the chemical composition of groundwater complicately reflects the effects of their host rocks, well depth, agricultural activity and mineralization zone in the study area.

포항지역 지열수에 대한 지화학적 고찰

  • 김통권;이진수;이승구;송윤호
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.101-103
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    • 2004
  • To investigate the evidence for the influence of sea water on Pohang geothermal groundwater, the chemical data for geothermal groundwaters from which are pumped during 48 hours and other hot groundwaters, another groundwater on the well for the purpose of agriculture, were considered. And to predict possible the secondary mineral which are easily to make the clogging, geochemical modeling was carried out using EQ3NR equilibrium solubility code. The results are that 1.4%~3.3%(bulk composition) of sea water were mixed with geothermal groundwater. From the well logging data, when the level of groundwater is drow down, the conductivity is increased in the geothermal groundwater, the existence of transition zone are recognized in the well. The predicted possible secondary minerals are Antigorite [Mg48Si24O85(OH)62], Chrysolite [Mg3Si2O5(OH)4] , Cristobalite, Dolomite, Talc, Tremolite. The recommended cooling temperature of best condition to minimize the production of secondary minerals is same as temperature of geothermal water pumped from the well.

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Synthesis of Ultrafine Zr Based Alloy Powder by Plasma Arc Discharge Process

  • Lee, Gil-Geun;Park, Je-Shin;Kim, Won-Baek
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.420-421
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    • 2006
  • In the present study, ultrafined Zr-V-Fe based alloy powder prepared by a plasma arc discharge process with changing process parameters. The chemical composition of synthesized powder was strongly influenced by the process parameters, especially the hydrogen volume fraction in the powder synthesis atmosphere. The synthesized powder had an average particle size of 50 nm. The synthesized Zr-V-Fe based particles had a shell-core structure composed of metal in the core and oxidse in the shell.

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Semi-quantitative Analysis of Manganese Oxide Mineral in Manganese Nodule From the East Siberian Sea (동시베리아해 망가니즈단괴의 산화망가니즈광물 반정량 분석)

  • Yu, Hye Jin;Shin, Eun Ju;Koo, Hyo Jin;Cho, Hyen Goo
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.4
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    • pp.427-437
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    • 2020
  • Manganese nodules, which are evaluated as potential metal resources, have been found in the Arctic Ocean as well as in the abyssal plains of the Pacific and Indian Oceans. Manganese nodules exhibit strong variations in the morphology, internal texture, chemical composition and mineralogy as they grow. The relationship between the texture and chemical elemental composition during the growth process is well documented, but the mineral composition variation during the growth process is not. Because the manganese oxide minerals in nodules are fine-grained and poorly crystalline, quantitative analysis for the mineral composition is challenging for the bulk nodule sample. This study investigated the internal texture and Mn-oxide mineral composition of manganese nodules obtained from the East Siberian Sea. Semi-quantitative analysis was attempted for three main Mn-oxide minerals constituting the manganese nodules (i.e., todorokite, buserite and birnessite) using the peak area ratio of X-ray diffraction analysis graphs. In the East Siberian Sea manganese nodules, birnessite is more abundant than buserite or todorokite, and no correlation is found between the mineral composition and the internal texture. Instead a correlation is found between the relative content of todorokite and the lamellae depth. The todorokite content tends to increase from the surface to the core of the nodules, which can be attributed to a recrystallization process or difference in the growth rate within the nodule. This study shows that semi-quantitative analysis of manganese oxide minerals using the peak area ratio is useful in the mineralogical study of manganese nodules.

The Chemical Composition of Taraxacum officinale Consumed in Korea (한국산 서양민들레(Taraxacum officinale)의 화학적 조성)

  • 강미정;서영호;김종배;신승렬;김광수
    • Korean journal of food and cookery science
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    • v.16 no.2
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    • pp.182-187
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    • 2000
  • For centuries, dandelion(Taraxacum officinale) is widely used as a food and a medicinal herb. However, there is inadequate documented information on the chemical composition of T. officinale consumed in korea. This study was attempted to analyze proximate component, amino acid, free sugar, mineral and fatty acid composition in T. officinale to establish the value as an useful food material. Moisture, ash, crude protein and fat contents in leaf are 7.85, 11.35 21.6 and 5.12%, respectively. Moisture and ash contents of root were 7.73 and 4.82%. Crude protein and fat contents of root were 11.8 and 1.73%, respectively. The major free amino acid was asparagine, arginine, serine and proline etc. The total contents of free amino acid in leaf and root were 1476.98 and 2710.06 mg%, respectively. The major free sugar in T. officinale was glucose, fructose, sucrose and maltose. Sucrose was also detected in a large amount. The major fatty acid of T. officinale are palmitic acid, stearic acid, oleic acid, linoeic acid and linolenic acid. The fatty acid compositions of leaf and root were different each other. Linolenic acid(63.6%) was the major fatty acid of the leaf and linoleic acid(56.4%) was the major fatty acid of the root. Most of mineral contents were high in leaf and root. Especially K content was higher in leaf than root.

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Physico-Chemical Characteristics of Mongolian Goat, Sheep and Cow Milk

  • Chuluunbat, Tsend-Ayush;Yoon, Yoh-Chang;Kim, Soo Yeon
    • Journal of Dairy Science and Biotechnology
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    • v.31 no.2
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    • pp.93-98
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    • 2013
  • For purposes of substantiation of organizing measures on industrial processing of goat's and sheep's milk in Mongolia and the production of dairy products we have conducted the studied physico-chemical characteristics of the Mongolian goat's and sheep's milks especially to recognize amino acids, minerals and vitamins in the milk and compare with the Mongolian cow's milk. And also was studied fractional structure of goat's milk whey proteins.

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Diverse Application of ECC Designed with Ground Granulated Blast Furnace Slag

  • Kim, Jeong-Su;Kim, Yun-Yong;Kim, Jin-Keun
    • International Journal of Concrete Structures and Materials
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    • v.1 no.1
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    • pp.11-18
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    • 2007
  • In the recent design of high ductile engineered cementitious composites (ECC), optimizing both processing and mechanical properties for specific applications is critical. This study employs a method to develop useful ECC produced with slag particles (slag-ECC) in the field, which possesses different fluid properties to facilitate diverse types of processing (i.e., self-consolidating or spray processing). Control of rheological modulation was regarded as a key factor to allow the performance of the desired processing while retaining the ductile material properties. To control the rheological properties of the composite, the basic slag-ECC composition was initially obtained, determined based on micromechanics and steady-state cracking theory. The stability and consequent viscosity of the suspensions were then mediated by optimizing the dosage of the chemical and mineral admixtures. The rheological properties altered through this approach were revealed to be effective in obtaining ECC-hardened properties, represented by pseudo strain-hardening behavior in uniaxial tension, allowing the readily achievement of the desired function of the fresh ECC.

Seasonal Changes in Nutritive Value of Some Grass Species in West Sumatra, Indonesia

  • Evitayani, Evitayani;Warly, L.;Fariani, A.;Ichinohe, T.;Fujihara, T.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.12
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    • pp.1663-1668
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    • 2004
  • This study was carried out to evaluate the potential nutritive value of commonly found grasses collected at native pasture in West Sumatra, Indonesia during dry and rainy seasons. Variables measured included chemical composition, in vitro digestibility, concentration of Ca, P and Mg, gas production and metabolizable energy (ME) content of the grasses. The results showed that species and season had significant effect on chemical composition and mineral concentration. Crude protein content in the dry season ranged from 6.5% (B. decumbens) to 14.4% (P. maximum) and increased slightly from 7.8% (B. decumbens) to 14. 8% (A. compressus) in the rainy season. Data on fiber fraction showed that grass contained more NDF, ADF and ADL in dry season than in rainy season. Data on mineral concentration showed that C. plectostachyus and P. maximum in dry season had higher Ca than those of other species, while in rainy season P. maximum had highest Ca concentration. In dry season, the DMD varied from 50. 4% (P.purpuphoides) to 59.1% (P. purpureum), while in rainy season ranged from 50.3% (A. gayanus) to 61.8% (P. purpureum). The potential and rate of gas production were significantly (p<0.05) affected by species and season. During dry season, potential of gas production ranged from 21.8 ml/200 mg (A. compressus) to 45.1 ml/200 mg (C. plectostachyus), while in rainy season it varied from 35.6 ml/200 mg (A. gayanus) to 47.5 ml/200 mg (P. purpureum). ME content of grasses varied from 6.0 to 8.3 MJ/kg in dry season and increased slightly from 6.4 to 8.6 MJ/kg in rainy season. Both in dry and rainy seasons, the highest ME content was occurred in P. purpureum and C. plectostachyus. In conclusion, nutritive value of the observed grasses in West Sumatra, Indonesia was relatively higher during rainy season compared with dry season. Pennisetum purpureum and Cynodon plectostachyus had the best nutritive value in both dry and rainy seasons.