• Title/Summary/Keyword: chemical coagulation

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Permeability recovery and changes in fouling layer characteristics of PTFE membrane by enhanced backwash cleaning using NaOCl during coagulation and microfiltration (응집 및 정밀여과공정의 강화역세정시 NaOCl에 따른 PTFE막 투과능 회복과 막오염층 변화)

  • Kang, Sun Gu;Park, Keun Youg;Kwark, Dong-Geun;Kim, Yun-Jung;Kweon, Jihyang
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.2
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    • pp.233-241
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    • 2015
  • Polytetrafluoroethylene (PTFE) membrane has high resistance to chlorine, which is a great advantages in chemical cleaning to recover water flux during membrane processes in drinking water systems. A humic kaolin water with approximately 4 mg/L of DOC and 10 NTU of turbidity was prepared as a feed water. Coagulation pretreatment with or without settling was applied. The coagulation with settling showed the greatest water production. The reduced flux was effectively recovered by NaOCl cleaning, i.e., 21% recovery by 50 mg/L of NaOCl cleaning and 49% recovery by 500 mg/L NaOCl cleaning. The images of SEM and AFM analyses were corresponded to the water flux variation. However, when the floc was accumulated on the membrane surfaces, the efficiency of NaOCl cleaning was substantially limited. In addition, dynamic contact angle became greater after cleaning, which indicates changes in characteristics of fouling layer such as surface hydrophobicity. Proper cleaning technologies during enhanced backwash using NaOCl would expand application of PTFE membranes in drinking water systems.

Enhancement of Discfilter Removal Efficiency for Small-scale Wastewater Reclamation (소규모 하수 재이용을 위한 디스크필터의 처리 효율 증진에 관한 연구)

  • Choi, Nag-Choul;Kim, Bong-Ju;Park, Seong-Yong;Park, Hyeong-U;Lee, Sung-Jae;Park, Cheon-Young
    • Journal of Soil and Groundwater Environment
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    • v.20 no.4
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    • pp.66-72
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    • 2015
  • The aim of this study was to enhance of the Discfilter process (maximum treatment capacity - 500 ton/day) removal efficiency for small-scale wastewater reclamation under various influent wastewater conditions (with / without coagulation process, coagulant content and temperature). The result of chemical resistance test for fiber filter in the Discfilter that weight loss was obtained with 0.535% under pH 3, 0.092% under pH 9 and 0.028% under 10% NaClO. The removal efficiency test of Discfilter process on the with / without coagulation process showed that with coagulation process condition was occurred CODMn of 42.26 ± 0.61, BOD5 of 88.72 ± 0.44, T-P of 84.67 ± 0.72 and SS of 90.58 ± 0.61. The removal efficiency of Discfilter process on the coagulant content (4.5, 5.0 and 5.0 mL/min) and temperature (< 10℃, 10℃~ 20℃ and > 20℃) conditions were increased as coagulant content and temperature increased. This study demonstrated the potential application of Discfilter process for small-scale wastewater reclamation.

Preservation of Coagulation Efficiency of Moringa oleifera, a Natural Coagulant

  • Katayon, S.;Ng, S.C.;Johari, M.M.N.Megat;Ghani, L.A.Abdul
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.11 no.6
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    • pp.489-495
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    • 2006
  • In recent years, there has been an interest to use Moringa oleifera as the natural coagulant due to cost, associated health and environmental concerns of synthetic organic polymers and inorganic chemicals. However, it is known that M. oleifera as the natural coagulant is highly biodegradable and has a very short shelf life. This research was carried out to investigate the effects of storage temperature, packaging methods, and freeze-drying on the preservation of M. oleifera seeds powders. Non freeze-dried M. oleifera was prepared into different packaging namely open container, closed container and vacuum packing, whilst, freeze-dried M. oleifera was stored in closed container and vacuum packing. Each of the packaging was stored at room temperature ($30\;to\;32^{\circ}C$) and refrigerator ($4^{\circ}C$). The turbidity removal efficiencies of stored M. oleifera were examined using jar test at monthly interval for 12 months. The results indicated that non freeze-dried M. oleifera kept in the refrigerator ($4^{\circ}C$) would preserve its coagulation efficiency. In addition, closed container and vacuum packing were found to be more appropriate for the preservation of non freeze-dried M. oleifera, compared to open container. Freeze-dried M. oleifera retained its high coagulation efficiency regardless the storage temperature and packaging method for up to 11 months. Besides, higher increment in zeta potential values for water coagulated with freeze-dried M. oleifera indicated the higher frequency of charge neutralization and better coagulation efficiency of freeze-dried M. oleifera, compared to non freeze-dried seeds. As a coagulant, M. oleifera did not affect the pH of the water after treatment.

Pre-treatment of oily wastewater using a coagulation-DAF process with slit-nozzle (슬릿노즐기반 응집·공기부상공정을 통한 유류폐수 전처리)

  • Choi, Sangki;Kim, Youngmo
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.6
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    • pp.479-485
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    • 2018
  • Large amounts of oily wastewater discharged from various industrial operations (petroleum refining, machinery industries and chemical industries) cause serious pollution in the aquatic environment. Although dissolved air flotation (DAF) separating oil pollutants using microbubbles represents current practice, bubble size cannot be selectively controlled, and lots of power is required to generate microbubbles. Therefore, to investigate performance of the DAF process, this study examined the distribution of different sizes of microbubbles resulting from changes in physical shear force via modifying shapes of a slit-nozzle without an additional power supply. Three types of slit-nozzles (different angle, shape and length of the slit-nozzle) were used to analyze the distribution of bubble size. At a slit angle of $60^{\circ}$, shear force was 4.29 times higher than a conventional slit, and particle size distribution (PSD) in the range between 2 and $20{\mu}m$ more than doubled. Treatment efficiency of synthetic oily wastewater through the coagulation-DAF process achieved 90% removal of COD by injecting $FeCl_3$ and PACl of 250 mg/L and 100 mg/L, respectively, and the same performance resulted using $FeCl_3$ of 200 mg/L and PACl of 80 mg/L employing a slit-nozzle angle of $60^{\circ}$. This study shows that a coagulation-DAF process using a modified slit-nozzle can improve the pre-treatment of oily wastewater.

Evaluation of Oil Pollutants Removal in Seawater as Pretreatment Process for Reverse Osmosis Desalination Process (역삼투식 해수담수화의 전처리공정으로서 유분 제거의 평가)

  • ;Okada Mitsumasa
    • Proceedings of KOSOMES biannual meeting
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    • 2003.05a
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    • pp.205-209
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    • 2003
  • The various pretreatment processes were evaluated for removal of oil pollutants with weathered oil contaminated seawater in a reverse osmosis desalination process. Weathered oil contaminated seawater was made by biodegradation and photooxidation with oil containing seawater. Coagulation, ultrafiltration, advanced oxidation processes and granular activated carbon filtration was used with pretreatment for dissolved organic carbon. Crude oil was removed but. weathered oil contaminated seawater was not removed by biodegradation and coagulation. DOC and E260 was removed with about 20 % and 40 % by membrane filter of cut off molecular weight 500. So, the most of dissolved organic carbon in weathered oil contaminated seawater was revealed that molecular weight was lower than 500. It is difficult to remove DOC in weathered oil contaminated seawater by advanced oxidation processes treatment, but, E260 was removed more high. However, DOC in weathered oil contaminated seawater was easily adsorbed to GAC. It is revealed that DOC was removed by adsorption.

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A Study on the Treatment of Dyeing Wastewater Using TiO₂/H₂O₂/UV Processes (TiO₂/H₂O₂/UV 공정을 이용한 염색폐수처리에 관한 연구)

  • Jo, Il Hyeong;Jeong, Hyo Jun;Park, Gyeong Ryeol;Seong, Gi Seok;Lee, Yong Gyu;Lee, Hong Geun
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.27-27
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    • 2000
  • In order to treat the dyeing wastewater, the UV/TiO₂/H₂O₂ system was investigated, and proper pretreatment methods were examined to reduce the load on the system considering economical and technical efficiency. The results of this study were as follows: 1.UV/TiO₂/H₂O₂ system with pretreatment process was adopted, the result of Chemical coagulation and pH control units was pH 11→ coagulation → pH 4 and the optimum dosage of FeCl₃ was 600㎎/ℓ 2. Proper dosage of TiO₂in the UV/TiO₂/H₂O₂ system with pretreatment process was 2g/ℓ and H₂O₂ was 1000㎎/ℓ, UV contact time was 20min to get below 200㎎/ℓ of $COD_{Cr}$

A Study on the Treatment of Dyeing Wastewater Using $TiO_2/H_2O_2/UV$ Processes ($TiO_2/H_2O_2/UV$ 공정을 이용한 염색폐수처리에 관한 연구)

  • 조일형;정효준;박경렬;성기석;이용규;이홍근
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.26-34
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    • 2000
  • In order to treat the dyeing wastewater, the $UV/TiO_2/H_2O_2$ system was investigated, and proper pretreatment methods were examined to reduce the load on the system considering economical and technical efficiency. The results of this study were as follows: 1. $UV/TiO_2/H_2O_2$ system with pretreatment process was adopted, the result of Chemical coagulation and pH control units was $pH{\;}11{\;}{\rightarrow}{\;}coagulation{\;}{\rightarrow}{\;}pH{\;}4$ and the optimum dosage of $FeCl_3$ was $600mg/{\ell}$. 2. Proper dosage of $TiO_2$ in the $UV/TiO_2/H_2O_2$ system with pretreatment process was $2g/{\ell}$ and $H_2O_2$ was $1000mg/{\ell}$, UV contact time was 20min to get $200mg/{\ell}$ of $COD_{Cr}$.

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Radiation Induced Cystitis and Proctitis - Prediction, Assessment and Management

  • Mallick, Supriya;Madan, Renu;Julka, Pramod K;Rath, Goura K
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.14
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    • pp.5589-5594
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    • 2015
  • Cystitis and proctitis are defined as inflammation of bladder and rectum respectively. Haemorrhagic cystitis is the most severe clinical manifestation of radiation and chemical cystitis. Radiation proctitis and cystitis are major complications following radiotherapy. Prevention of radiation-induced haemorrhagic cystitis has been investigated using various oral agents with minimal benefit. Bladder irrigation remains the most frequently adopted modality followed by intra-vesical instillation of alum or formalin. In intractable cases, surgical intervention is required in the form of diversion ureterostomy or cystectomy. Proctitis is more common in even low dose ranges but is self-limiting and improves on treatment interruption. However, treatment of radiation proctitis is broadly non-invasive or invasive. Non-invasive treatment consists of non-steroid anti-inflammatory drugs (NSAIDs), anti-oxidants, sucralfate, short chain fatty acids and hyperbaric oxygen. Invasive treatment consists of ablative procedures like formalin application, endoscopic YAG laser coagulation or argon plasma coagulation and surgery as a last resort.

Analysis of brightness decrease originated from mixing of flexo printed ONP and OCC in ONP recycling process (플렉소 인쇄 신문지와 OCC 배합에 따른 ONP 탈묵펄프의 백색도 변화)

  • Ryu, Jeong-Yong;Song, Bong-Keun
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.10a
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    • pp.119-123
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    • 2011
  • The application of flexo printed ONP and OCC leads to brightness decrease of deinked stock in ONP recycling system. The largest problems are due to accumulation of flexo ink & introduction of brown fibers. All these are emphasized by variations in the amount of flexo printed ONP and OCC in recovered ONP stock. Most of the brightness problems caused by flexo ink can be helped and solved by applying a proper polyelectrolytes as coagulation agent and flocculation agent. This requires exact evaluation of sedimentation or dissolved air flotation potentials of flexo ink and polyelectrolytes. Effect of bleaching chemical (H2O2) addition level on the increase of brightness of OCC included stock has been investigated by lab scale test.

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Effective Coagulation and Fenton Reagent Oxidation of Effluent from Biological Landfill Leachate Treatment (생물학적 처리 침출수의 응집 및 펜톤산화 처리)

  • Won, Jong-Choul;Namkoong, Wan;Park, Ki-Hyuk;Cho, Joon-Ho;Yoon, Cho-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.811-817
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    • 2000
  • The objectives of this study are to determine optimal operation condition of chemical coagulation with ferric chloride($FeCl_3$) and fenton reagent oxidation for effluents of a biological denitrification treatment and an existing lagoon treatment of landfill leachate, and to investigate the effect of alkalinity on fenton oxidation. In jar-tester, optimum dosage of ferric chloride for removal of COD was $1,500mgFe^{3+}/L$, removal efficiencies of $COD_{Cr}$ and $COD_{Mn}$ under this condition were about 55% and 64%, respectively. After chemical precipitation($1,500mgFe^{3+}/L$) of biological treatment effluent, optimum $Fe^{2+}/H_2O_2$ ratio of fenton oxidation was 1.5, the maximum removal efficiency of COD was about 80%, and optimum dosages of ferrous sulfate and hydrogen peroxide were $600mgFe^{2+}/L$ and $400mgH_2O_2/L$, respectively. The removal efficiency of COD was decreased as alkalinity was increased.

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