• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 가을학술발표대회논문집
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• pp.85-86
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• 2023

In this study, charring properties such as charring layer and mass change of wood with temperature were investigated through cone calorimeter test on douglas-fir, which is representative of various wood structures. the results showed that ignitions at 390 degrees and a charring layer is formed.

• 한국유체기계학회 논문집
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• 제14권1호
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• pp.34-41
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• 2011

Fire characteristics can be analyzed more realistically by using more accurate properties related to the fire dynamics and one way to acquire these fire properties is to use one of the inverse property estimation techniques. In this study two optimization algorithms which are frequently applied for the inverse heat transfer problems are selected to demonstrate the procedure of obtaining pyrolysis properties of charring material with relatively simple thermal decomposition. Thermal decomposition is occurred at the surface of the charring material heated by receiving the radiative energy from external heat sources and in this process the heat transfer through the charring material is simplified by an unsteady 1-dimensional problem. The basic genetic algorithm(GA) and repulsive particle swarm optimization(RPSO) algorithm are used to find the eight properties of a charring material; thermal conductivity(virgin, char), specific heat(virgin, char), char density, heat of pyrolysis, pre-exponential factor and activation energy by using the surface temperature and mass loss rate history data which are obtained from the calculated experiments. Results show that the RPSO algorithm has better performance in estimating the eight pyrolysis properties than the basic GA for problems considered in this study.

• 한국전산유체공학회지
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• 제10권1호
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• pp.16-23
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• 2005

The objective of this research is to estimate two dimensional ablating and charring of heat shield materials in severe aero-thermal heat transfer. This estimation requires an accurate and rapid technique for its serious heat transfer with a moving boundary. Aerodynamic heating is obtained by an explicit relation which is a function of Mach number and air condition, while a fully implicit method is used for heat transfer calculations. Moving boundary is captured by FLIAR method which is a subgroup of VOF. Thickness of ablating and charring of heat shield, temperature of the moving surface and rate of radiation heat are calculated and compared with references. The results are in good agreement with other calculations.

• 한국대기환경학회지
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• 제31권5호
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• pp.449-460
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• 2015

Carbonaceous aerosol is generally classified into OC (organic carbon) and EC (elemental carbon) by thermal optical analysis. Both NIOSH (National institute of occupational safety and health) with high temperature (HighT) and IMPROVE-A (Interagency monitoring of protected visual environments) with low temperature (LowT) protocols are widely used. In this study, both protocols were applied for ambient $PM_{2.5}$ samples (Daejeon, Korea) in order to underpin differences in OC and EC measurements. An excellent agreement between NIOSH and IMPROVE-A protocol was observed for TC (total carbon). However, significant differences between OC and EC appeared and the differences were larger for EC than OC. The main differences between two protocols are temperature profile and charring correction method. For the same charring correction method, HighT_OC was 10% higher than LowT_ OC, while HighT_EC was 15% and 33% lower than LowT_EC for TOT (thermal-optical transmittance) and TOR (thermal-optical reflectance), respectively. This difference may be caused by the temperature of OC4 in He step and possibly difference in POC (pryorilized OC) formation. For the same temperature profile, OC by TOT was about 26% higher than that by TOR. In contrast, EC by TOT was about 50% lower than that by TOR. POC was also dependent on both temperature profile and the charring correction method, showing much distinctive differences for the charring correction method (i.e., POC by TOT to POC by TOR ratio is about 2). This difference might be caused by different characteristics between transmittance and reflectance for monitoring POC formation within filters. Results from this study showed that OC and EC depends on applied analysis protocol as shown other studies. Because of the nature of the thermal optical analysis, it may not be possible to have an absolute standard analysis protocol that is applicable for any ambient $PM_{2.5}$. Nevertheless, in order to provide consistent measurement results for scientists and policy makers, future studies should focus on developing a harmonized standard analysis protocol that is suitable for a specific air domain and minimizes variations in OC and EC measurement results. In addition, future elaborate studies are required to find and understand the causes of the differences.

• 한국군사과학기술학회지
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• 제5권4호
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• pp.88-96
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• 2002

The CSCM Upwind method and Material Transport Analysis(MTA) have been used to predict the thermal response and shape changes for charring/non-charring material which can be used as thermal protection material(TPM) on blunt-body nose tip. We performed intensive flight trajectory simulations to compare 1-D MTA results with those of 2-D/Axisymmetric MTA by using MTAs and Navier-Stokes code. Theheat-transfer rate and pressure distribution were predicted at selected altitudes and wall temperature along the flight trajectory and the shape changes of blunt-body nose tip were predicted subsequently by using current procedure.

• 대한기계학회논문집
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• 제16권5호
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• pp.943-951
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• 1992

본 연구에서는 삭막에 의한 표면후퇴 현상을 해석하기 위하여 Brogan이 제시 한 front node dropping기법을 적용하여 여러개의 상이한 재료로 구성된 조합 내열 부품에서 삭마와 숯이 동시에 발생하는 경우에 대한 내부 열반응 예측도 가능하게 하 였다. 이 수치기법은 해석하고자 하는 부분에 대한 격자생성(mesh generation)을 수 행하여 각 격자점의 좌표를 고정한 후, 삭마에 의하여 표면이 후퇴될 때 첫번째 격자 점은 두번째 격자점과 일치될 때 까지 존재하다가 제거되고, 두번째 격자점도 세번째 격자점과 일치될 때까지 존재하다가 제거된다. 이때 나머지 격자점의 위치는 항상 일정하게 고정되며 삭마가 정지될 때까지 이 과정이 계속된다. 또한 본 연구분야에 수치해석 기법으로 유한해석법(FAM:finte analytic method)을 국내외 최초로 적용하여 비선형성이 심한 것을 효과적으로 처리하므로써 안정한 해를 얻을 수 있었다. 유한 해석법은 1981년 Chen이 제안한 기법으로, 국소 격자계에 대하여 선형화된 지배 방정 식의 엄밀해를 구하여 전체 문제 영역에 확장하는 방법이다. 이 방법은 수치 계산식 의 유도과정이 매우 복잡하기는 하나, 그 결과가 정확하고 안정한 해를 얻을 수 있어 서 점차 적용 사례가 증가하고 있으며 본 문제의 수치 해석에 매우 적합한 기법으로 판단된다.

• Journal of the Korean Wood Science and Technology
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• 제34권4호
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• pp.1-8
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• 2006

제조 온도에 따른 목탄의 해부학적 특성을 주사전자현미경법으로 조사하였다. 목탄은 실험실용 전기로를 이용하여 $400^{\circ}C$, $600^{\circ}C$, $800^{\circ}C$, $1000^{\circ}C$의 각 온도 조건에서 굴참나무재를 10분간 탄화시켜 제조하였다. 관찰 결과 목탄의 구조는 제조 온도에 따라 큰 차이를 보였다. $400^{\circ}C$에서 제조한 목탄의 횡단면은 깨끗하게 나타났으나 온도 증가에 따라 거칠고 할렬이 많은 단면을 나타냈다. 세포벽은 벽층 구조가 소실되고 유리와 같이 매끄럽고 균질한 구조를 보여주었다. $400^{\circ}C$에서 제조한 목탄은 유세포 상호간에 간극이 거의 없었으나 $600^{\circ}C$ 이상에서는 유세포 간에 분리가 발생하여 간극이 관찰되었다. 방사유세포와 축방향유세포의 표면에는 직경 $2{\sim}4{\mu}m$의 사마귀 모양의 돌기물이 다수 관찰되었고, $600^{\circ}C$ 이상에서 광방사조직에 커다란 할열할렬이 자주 발생하였다. 결정 세포 중에 존재하는 결정의 표면은 제조 온도에 따라 다르게 나타났다. 즉, $400^{\circ}C$와 $600^{\circ}C$에서 제탄한 목탄 중의 결정은 매끄러운 표면을 나타내고 있으나 $800^{\circ}C$ 이상에서 제조한 목탄의 것은 표면이 거칠고 작은 구멍이 나타나 스폰지와 같은 외형을 보여주었다.

• Journal of Forest and Environmental Science
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• 제28권4호
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• pp.263-267
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• 2012

Characteristics of charcoals manufactured in each temperature as 400, 600 800, 1,000 and $1,200^{\circ}C$ were examined. Sapwood and heartwood of Quercus variabilis that one of major species in charcoal materials were used for this experiment. Charcoal density was decreased highly 38-60% compared with wood density and density of sapwood was slightly decreased but heartwood was not changed with increasing carbonization temperature increase. Weight loss of sapwood and heartwood charcoal increased as carbonization temperature increases, and there is no difference between sapwood and heartwood charcoal. Refining degree of sapwood and heartwood charcoal was zero in charring over $800^{\circ}C$. Moisture and ash of sapwood and heartwood charcoal in each carbonization temperature were not differed between sapwood and heartwood. Volatile of sapwood charcoal was slightly higher than that of heartwood, and decreased as carbonization temperature increases. As the carbonization temperature increased, fixed carbon of sapwood and heartwood charcoal increased. Calorific values of charcoal prepared at $600^{\circ}C$ were 7,200-7,300 cal/g and then decreased slightly as carbonization temperature increased.

• 대한화학회지
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• 제40권2호
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• pp.109-116
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• 1996

물시료 중 존재하는 흔적량 게르마늄을 전열 원자흡수 분광광도법으로 정랑하기 위해 사용되는 매트릭스 개선제의 종류와 사용량, 이에 따를 회화 및 원자화 온도의 변화, 보조제의 사용여부 및 양에 관하여 연구하였다. 게르마늄은 회화단계에서 이산화 게르마늄이 흑연로 성분인 탄소로 인해 휘발성 일산화 게르마늄으로 환원되에 감도 및 재현성을 저하시킨다. 따라서 개선제를 사용하여 게르마늄을 열적 및 화학적으로 안정화시켜야 한다. 이를 위해 단일 개선제를 사용할 경우 파라듐이 가장 좋은 효과를 나타내었다. 이 경우 원자화온도는 변화시키지 않지만, 회화온도는 800.deg.C에서 1, 000.deg.C로 올릴수 있었고 흡광도도 증가하였다. 이런 조건에서 팔라듐의 농도가 게르마늄에 대해 몰비로 14-100인 10-70.mu.g/mL까지 흡광도가 일정하였다. 보조개선제의 사용도 검토하였는데, 1% 수산화암모늄을 가하여 회화온도를 1, 000.deg.C까지 증가시켰다. 이제까지 검토한 최적조건을 바탕으로 광천수 3가지를 분석한 결과 게르마늄이 2.46, 1.60 및 0.020.mu./mL이었다. 끝으로, 시료에 일정량의 게르마늄을 첨가하여 얻은 회수율은 모두 95%이상으로 정량적이라고 할 수 있고, 검출한계는 6.9ng/mL로 흔적량 게르마늄 분석에 유용한 것으로 판단되었다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집E
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• pp.282-287
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• 2001

The CSCM Upwind method and Material Transport Analysis (MTA) have been used to predict the thermal response and ablation rate for non-charring material to be used as thermal protection material (TPM) in KSR-III test rocket nozzle. The thermal boundary conditions such as cold wall heat-transfer rate and recovery enthalpy for MTA code are obtained from the upwind Navier-Stokes solution procedure. The heat transfer rate and temperature variations at rocket nozzle wall were studied with shape change of the nozzle surface as time goes by. The surface recession was severely occurred at nozzle throat and this affected nozzle performance such as thrust coefficient substantially.