• Title/Summary/Keyword: charged polymers

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Space Charge Analysis in Polymers Irradiated by Electron Beam (E-빔 조사에 의한 폴리머의 공간전하 해석)

  • Yun, Ju-Ho;Choi, Yong-Sung;Moon, Jong-Dae;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.309-310
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    • 2007
  • Spacecrafts such as most of commercial satellites that are operating in the geostationary orbit can be subjected to intense irradiation by charged particles. The surface made of dielectric materials can therefore become probable sites for damaging electrostatic discharges. Thanks to a specially equipped chamber, the spatial environment can be reproduced experimentally in the laboratory. In this paper, the behavior of high energy electrons injected in polymers such as PolyMethylMetaAcrylate (PMMA) and Kapton is studied. Results obtained by surface potential technique, pulse-electro acoustic device and a cell based on the split Faraday cup system are analyzed and discussed.

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Thermally Stimulated Currents in Gamma Irradiated Polymer (감마선에 조사된 중합체의 열자극 전류)

  • Chu, Sung-Sil
    • Journal of Radiation Protection and Research
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    • v.7 no.1
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    • pp.49-55
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    • 1982
  • Thermally stimulated currents of polymers have some properties as radiation dosimetry, especially polymer could be made as a good dosimeter in biological fields because of tissue equivalent material. We experimented the radiation response of polymers and attempted to apply it in clinical use. Polymers have the properties of thermoluminescence and thermally stimulated currents which are due to several kinds of charged particles such as dipoles, electronic trapped charges and mobile ions. Several peaks are datected in the thermally stimulated currents in polyethylene under vias field V, by heating from room temperature to $100^{\circ}C$ shortly after irradiation. As V increases, both the peak temperature $T_m$ and the activation energy H decreases, while the peak current $I_m$ increases. We plotted the $T_m-V\;and\;I_m-V$ curves and calculated the electron trap depth with the recombination operative TSC theory and compared the peak TSC with radiation doses.

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Creation of Bio-Inspired Fiber Materials and Their Biodegradation

  • Ohkawa, Kousaku;Yamamoto, Hiroyuki
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.43-44
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    • 2003
  • The new method for preparing hybrid fibers from aqueous solution is described. The method is based on interfacial polyionic complexation between the counter-charged polymers. Polysaccharides, chitosan and gellan, and polypeptides, poly(L-lysine) and poly(L-glutamic acid) were utilized as the components of the fibers. The chitosan-gellan and poly(L-lysine)-gellan hybrid fibers exhibited a high level biodegradability.

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Influence of Ion Exchange Capacity on the Performance of Ultrafiltration Membrane Prepared from Anion Charged Poly(bis[4-(3-aminophenoxy)phenyl]sulfone pyromellite)imide Derivatives (음이온성 Poly(bis[4-(3-aminophenoxy)phenyl]sulfone pyromellite)Imide Derivatives 한외여과막의 투과특성)

  • Jong-Young Jeon
    • Membrane Journal
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    • v.14 no.1
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    • pp.26-36
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    • 2004
  • Ultrafiltration membranes based on anion charged poly(bis[4-(3-aminophenoxy)phenyl]sulfone pyromellite) imide derivatives (ACPI) were prepared by the phase inversion method. The polymers have good solubility in aprotic polar solvents. The composition of casting solution and the casting conditions played an important role in determining the permeation characteristics of membrane because the membrane structure could be controlled by the preparation conditions. The extent of fouling-repression was observed by the relative ratio of permeate flux ($J_t$)/pure water flux ($J_0$) and the membrane filtration index (MFI). The characteristics were measured by aqueous solution of bovine serum albumin (BSA) over a pH range of 2.5-9.0. The ACPI membrane having a hydrophilic property was less fouled than the membrane prepared from the original polyimide. With increasing the ion exchange capacity of ACPI membrane, th $\varepsilon$ relative ratio of flux was higher while the membrane filtration index was lower as compared with the original polyimide membrane. From the further away from isoelectric point of bovin serum albumin, the permeation was higher as well as the formation of fouling was more diminish. ACPI membranes having various their properties could be obtained. Further, it was proved that their permeation properties could be determined from the preparation conditions, various operating conditions, and dim $\varepsilon$ rent ion exchange capacity of anion charged polyimide derivatives.

Flexible and Transparent Plastic Electrodes Composed of Reduced Graphene Oxide/Polyaniline Films for Supercapacitor Application

  • Sarker, Ashis K.;Hong, Jong-Dal
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1799-1805
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    • 2014
  • In this article, we described about the preparation and electrochemical properties of a flexible energy storage system based on a plastic polyethylene terephthalate (PET) substrate. The PET treated with UV/ozone was fabricated with multilayer films composed of 30 polyaniline (PANi)/graphene oxide (GO) bilayers using layer-by-layer assembly of positively charged PANi and negatively charged GO. The conversion of GO to the reduced graphene oxide (RGO) in the multilayer film was achieved using hydroiodic acid vapor at $100^{\circ}C$, whereby PANi structure remained nearly unchanged except a little reduction of doping state. Cyclic voltammetry and charge/discharge curves of 30 PANi/RGO bilayers on PET substrate (shorten to PANi-$RGO_{30}$/PET) exhibited an excellent volumetric capacitance, good cycling stability, and rapid charge/discharge rates despite no use of any metal current collectors. The specific capacitance from charge/discharge curve of the PANi-$RGO_{30}$/PET electrode was found to be $529F/cm^3$ at a current density of $3A/cm^3$, which is one of the best values yet achieved among carbon-based materials including conducting polymers. Furthermore, the intrinsic electrical resistance of the PANi-$RGO_{30}$/PET electrodes varied within 20% range during 200 bending cycles at a fixed bend radius of 2.2 mm, indicating the increase in their flexibility by a factor of 225 compared with the ITO/PET electrode.

Encapsulation of Anthocyanin from Purple Potato by the Application of Food Polymers

  • Azad, Obyedul Kalam;Cho, Dong Ha;Park, Cheol Ho
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2018.10a
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    • pp.42-42
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    • 2018
  • Anthocyanins has a strong antioxidant capacity but exhibit poor stability in water. Therefore, stability of anthocyanin from purple potato (Solanum tuberosum L.) was encapsulated by the application of food polymers. Solid formulation of purple potato was prepared using whey protein, tapioca and lecithin by capillary rheometer at $80^{\circ}C$. The ratio of the polymer and potato powder was 2:8. Total phenolic compound, total flavonoid, total anthocyanin and antioxidant activity was investigated by the spectrophotometer. Result revealed that total phenolic compound (TP) ($5321{\mu}g/100g$), total flavonoid (TF) ($1352{\mu}g/100g$) total anthocyanin (TA) ($764{\mu}g/100g$) and free radical antioxidant activity (DPPH) (86%) was higher in 0.01 M acetic acid mediated lecithin based formulation compared to control (Potato powder) (TP: $1357{\mu}g/100g$; TF) ($634{\mu}g/100g$, TA) ($264{\mu}g/100g\;DPPH$) (64%). Lecithin is a strong emulsifier having capacity to extract bioactive compound and encapsulate extracted compound by nonpolar tail and negatively charged head. Therefore, it would be concluded that lecithin might be used as an encapsulating agent for the bioactive compound from purple potato.

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Encapsulation of Anthocyanin from Purple Potato by the Application of Food Polymers

  • Azad, Obyedul Kalam;Cho, Dong Ha;Park, Cheol Ho
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2018.10a
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    • pp.274-274
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    • 2018
  • Anthocyanins has a strong antioxidant capacity but exhibit poor stability in water. Therefore, stability of anthocyanin from purple potato (Solanum tuberosum L.) was encapsulated by the application of food polymers. Solid formulation of purple potato was prepared using whey protein, tapioca and lecithin by capillary rheometer at $80^{\circ}C$. The ratio of the polymer and potato powder was 2:8. Total phenolic compound, total flavonoid, total anthocyanin and antioxidant activity was investigated by the spectrophotometer. Result revealed that total phenolic compound (TP) ($5321{\mu}g/100g$), total flavonoid (TF) ($1352{\mu}g/100g$) total anthocyanin (TA) ($764{\mu}g/100g$) and free radical antioxidant activity (DPPH) (86%) was higher in 0.01 M acetic acid mediated lecithin based formulation compared to control (Potato powder) (TP: $1357{\mu}g/100g$; TF) ($634{\mu}g/100g$, TA) ($264{\mu}g/100g\;DPPH$) (64%). Lecithin is a strong emulsifier having capacity to extract bioactive compound and encapsulate extracted compound by nonpolar tail and negatively charged head. Therefore, it would be concluded that lecithin might be used as an encapsulating agent for the bioactive compound from purple potato.

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Preparation and Characterization of Multilayer Microcapsules using Biocompatible Polymers (생체적합성 고분자를 사용한 다층 조립 구조 캡슐의 제조와 특성)

  • Jeon, Woohong;Kim, Gwang Yeon;Kim, Gue-Hyun;Ha, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.178-184
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    • 2010
  • The aim of this work is the fabrication of polyelectrolyte microcapsules composed of biocompatible polymers such as chitosan, heparin and alginate, to encapsulate the fluorescein isothiocyanate(FITC)-albumin, and to investigate the protein release behavior therefrom. Polyelectrolyte capsules with 4-layer structures could be prepared with biocompatible materials by oppositely charged adsorption using melamin-foramide as a template. Transmission electron microscope(TEM), scanning electron microscope(SEM) and optical microscope confirmed hollow capsule structures. Protein release before and after encapsulation was monitored with a UV-Vis spectrometer. Microcapsules have different behaviors depending on the kind of polyelectrolyte polymers, chitosan-heparin capsules or chitosan-alginate capsules. In conclusion, the polyelectrolyte multilayer shells can be switched between an open and closed state by means of tuning the pH value.

A Research Trend on Space Charge Analysis in Polymer Irradiated by Electron Beam (전자빔 조사에 의한 중합체 내의 공간 전하 분석 연구 동향)

  • Kim, Byung-Woo;Lee, Hyung-Chul;Ahn, Jong-Hyun;Hwang, Jong-Sun;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1990-1991
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    • 2007
  • Spacecrafts such as most of commercial satellites that are operating in the geostationary orbit can be subjected to intense irradiation by charged particles. The surface made of dielectric materials can therefore become probable sites for damaging electrostatic discharges. Thanks to a specially equipped chamber, the spatial environment can be reproduced experimentally in the laboratory. In this paper, the behavior of high energy electrons injected in polymers such as PolyMethylMetaAcrylate (PMMA) and Kapton is studied. Results obtained by surface potential technique, pulse-electro acoustic device and a cell based on the split Faraday cup system are analyzed and discussed.

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Total Dietary Fiber and Mineral Absorption

  • Gordon, Dennis-T.
    • Journal of Nutrition and Health
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    • v.25 no.6
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    • pp.429-449
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    • 1992
  • The consumption of foods rich in TDF should not be associated with impaired mineral absorp-tion and long-term mineral status. In surveys of populations consuming high amounts of TDF e.g Third World populations and vegetarinas gross deficiencies in mineral nutrition have not been noted. If mineral status is low among these groups it is most likely caused by the inadequacy or imbalance of the diet and not by the TDF. The key word is interaction which should be inte-rpreted in dietary imbalances that produce nut-rient deficiencies. There are no strong data to support the concept that TDF inhibits mineral absorption through a binding chelation mechanism. Limited data sug-gest that positively charged groups on polymers such as chitosan and cholestyramine will decrease iron absorption in humans and animals. Because TDF does not contain positively charged groups future research should be directed at the possible role of protein consumed along with TDF and the combination of effects on mineral nutrition Phytic acid is acknowledged as a potent chela-tor of zinc. However its association with zinc and its propensity to lower Zn bioavaiability may enhance the absorption of other elements notably copper and iron. The importance of interactions among nutrients including TDF will gain addi-tional attention in the scientific community. Soluble and insoluble dietary fiber function di-fferently in the intestine. Insoluble fibers accele-rate movement through the intestine. Soluble die-tary fibers appear to regulated blood concentra-tions of glucose and cholesterol albeit by some unknown mechanism. In creased viscosity produ-ced by the SDF in the intestine may provide an explanation of how this class of polymers affects plasma glucose cholesterol and other nutrients. Employing a double-perfusion technique in the rat we demonstrated that viscosity produced by SDF will delay transfer of zinc into the circulatory system. This delayed absorption should not be interpreted as decreased utilization. A great deal of additional research is required to prove the importance of luminaly viscosity produced by SDF on slowing nutrient absorption or regulating bllod nutrient homeostasis. Increased intake of TDF in the total human diet appears desirable. A dietary intake of 35g/day should not be considered to have a negative effect on mineral absorption. It is important to educate people that an intake of more than 35g TDF/day may cause an imbalance in the diet that can adve-rsely affect mineral utilization. Acknowledgments. Appreciation is given to Dr. George V. Vahouny(deceased) who was intense a great competitor in and out of science and who gave the author inspiration Portions of this work were supported by the University of Missouri Ag-ricultural Station and by a grant from the Univer-rch Support Grant RR 07053 from the National Institutes of Health. Contribution of the Missouri Agriculatural Experiments Station Journal Series No. 10747.

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