• Title/Summary/Keyword: changes of grain size

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AFM Study and Magnetic Properties of Nanocrystalline Fe73.5-xCrxSi13.5B9Nb3Au1 (x=1~5) Alloys

  • Le, Anh-Than;Chau Nguyen;Cuong Nguyen Duy;The Ngo Duc;Kim, Chong-Oh;Rhee, Jang-Roh;Lee, Hee-Bok
    • Journal of Magnetics
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    • v.11 no.1
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    • pp.43-50
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    • 2006
  • In this paper, the influences of microstructural and surface morphological developments on the soft magnetic properties and giant magneto-impedance (GMI) effect of the $Fe_{73.5-x}Cr_{x}Si_{13.5}B_{9}Nb_{3}Au_1$ (x = 1, 2, 3, 4, 5) alloys have been presented. It was found that the Cr addition slightly decreased the mean grain size of $\alpha-Fe(Si)$ grains. AFM results indicate a large variation of surface morphology of density and size of protrusions along the ribbon plane due to microstructural changes caused by thermal annealing with increasing Cr content. Ultrasoft magnetic properties of the nanocrystallized samples were noticeably enhanced by properly heat treatments at $T_a=540^{\circ}C$ such as an increase of the magnetic permeability and the decrease of coercivity, which is likely due to the formation of nanoscale $\alpha-Fe(Si)$ phase which reduced the magnetoelastic anisotropy of samples. Accordingly, the GMI effect was observed in the annealed samples. The correlation between the microstructure, surface morphology, and soft magnetic properties were explained by nucleation and growth model.

Characteristics of Seasonal Variation to Sedimentary Environment at the Estuary area of the Nakdong (낙동강 하구역의 계절적인 퇴적환경 변화특성)

  • Yoon, Eun-Chan;Lee, Jong-Sup
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.20 no.4
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    • pp.372-389
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    • 2008
  • In this study, we formed a detailed grid at the estuary area of the Nakdong and collected the surface sediments. Particle size analysis and comparison with existing data were conducted to investigate the characteristics of seasonal and long-term changes in the sediments. As a result of investigation, the distribution of the sediments showed a great change per season and was greatly influenced by the quantity of outfall discharge at the Nakdong estuary barrier and the incident wave climate. The sandy sediments showed dominant movement toward the front of Jinwoodo west of the estuary area of the Nakdong due to the influence of the ENE wave, the annually-dominant wave. And the muddy sediments showed deposition by being moved toward the deep open sea along with a current. The present conditions of the sediments at the estuary area of the Nakdong showed great differences from the results of previous studies.

Numerical simulation of dimensional changes during sintering of tungsten carbides compacts

  • Bouvard, D.;Gillia, O.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 1997.10a
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    • pp.7-7
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    • 1997
  • During sintering of very porous green bodies, as obtained by compaction of hard powders - such as tungsten carbide or ceramics - or by injection moulding, important shrinkage occurs. Due to heterogeneous green density field, gravity effects, friction on the support, thermal gradients, etc., this shrinkage is often non-uniform, which' may induce significant shape changes. As the ratio of compact dimension to powder size is very high, the mechanics of continuum is relevant to model such phenomena. Thus numerical techniques, such as the finite element method can be used to simulate the sintering process and predict the final shape of the sintered part. Such type of simulation has much been developed in the last decade firstly for hot isostatic pressing and next for die compaction. Finite element modelling has been recently applied to free sintering. The simulation of sintering should be based on constitutive equations describing the thermo-mechanical behaviour of the material under any state of stress and any temperature which may arise within the sintering body. These equations can be drawn either from experimental data or from micromechanical models. The experiments usually consist in free sintering and sinter-forging tests. Indeed applying more complex loading conditions at high temperature under controlled atmosphere is delicate. Micromechanical models describe the constitutive behaviour of aggregates of spheres from the deformation of two-sphere contact either by viscous flow or grain boundary diffusion. Such models are not able to describe complex microstructure and mechanisms as observed in real materials but they can give some basic information on the formulation of constitutive equations. Practically both experimental and theoretical approaches can be coupled to identify the constitutive equations. Such procedure has been performed for modelling the sintering of compacts obtained by die pressing of a mixture of tungsten carbide and cobalt powders. The constitutive behaviour of this material during sintering has been described by a linear viscous constitutive model, whose functions have been fitted from results of free sintering and sinter-forging experiments. This model has next been introduced in ABAQUS finite element code to simulate the sintering of heterogeneous green compacts of various geometries at constant temperature. Examples of simulations are shown and compared with experiments.

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Evaluation of mechanical properties on friction stir lap jointed Al6061/HT590 alloys (겹치기 마찰교반접합 된 Al6061/HT590 합금의 기계적 특성 평가)

  • Kim, Eun-Hye;Lee, Kwang-Jin;Song, Kuk-Hyun
    • Journal of Welding and Joining
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    • v.33 no.2
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    • pp.8-13
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    • 2015
  • This study was carried out to evaluate mechanical properties of the jointed Al6061/HT590 alloys by friction stir welding (FSW). FSW was conducted under the conditions with tool rotating speed of 500 RPM and traveling speed of 300 mm/min., where Ar gas was introduced to prevent the materials from corrosion during the welding process. Electron back-scattering diffraction (EBSD) was used to characterize microstructures such as grain size, misorientation angle and crystal orientation. Evolution of intermetallic compounds in Al6061 during the process were examined in terms of morphology, size and aspect ratio at three distinct zones Al base material, heat affected zone and stir zone, where transmission electron microscope (TEM) was used. It was revealed that FSW gave rise to refinement of grains as well as growth of intermetallic compounds in Al6061. The morphological changes of intermetallic compounds exerted an influence on mechanical properties, resulting in occurrence of fracture in the part of the base material instead of the jointed parts (heat affected zone and stir zone). This study systematically evaluated the microstructural evolutions during the FSW for joining Al6061 with HT590 and their effect on mechanical properties.

Spatial and Temporal Variation of Grain Size of the Surface Sediments in Kwangyang Bay, South Coast of Korea (한반도 남해안 광양만 표층퇴적물 입도의 시ㆍ공간적 변화)

  • 류상옥
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.8 no.3
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    • pp.340-348
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    • 2003
  • Sedimentological investigations on surface and suspended sediments were performed in Kwangyang Bay of the middle South Sea in order to reveal recent changes in depositional environments concerning anthropogenic influence. A variety of coastal developments caused the texture of the surface sediments to become distinctively finer, particularly in the southwestern part of the bay. Accordingly, the westward lining sedimentary facies was somewhat simplified from triple-mode distribution to the dual-mode one by the construction of POSCO. This east-west distribution to the sedimentary facies has recently graded into the north-south distribution by further construction of other industrial complexes including Kwangyang Port. The prominent textural changes in surface sediments are most likely associated with weakening of tidal currents related to the developments which is anticipated to be .still continued. The distribution and flux estimation of suspended sediments suggest a noticeable import of fine particles into the bay predominantly through a northern entrance rather than the southern entrance. The movements of suspended sediments in the water level near the seabed prevailed over those of the mid and surficial levels.

Characterization of Clastic and Organic Sediments Near Dokdo, Korea (독도 인근 해저퇴적물과 유기 퇴적물 분포 특성)

  • Jun, Chang Pyo;Kim, Chang Hwan;Lee, Seong-Joo
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.2
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    • pp.65-80
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    • 2013
  • Sediment transport mechanism and distribution of organic sediments are elucidated by the study of particle size, mineralogy, organic matters and microfossils of the surface samples collected from seafloor adjacent Dokdo island. Shallow marine sediments are dominated by coarse- grained sediments including gravel and sand, and their sedimentation has mainly been controlled by traction. While the samples collected from oceanic zone are characterized by high contents of fine- grained sediments such as silt and mud in bulk sediments, and the changes of mineral compositions including clay minerals and feldspar, and the fine sediments have been deposited mainly by suspension. The change of organic sedimentary communities is detected between neritic and oceanic zone. Although marine organic matter is predominant in neritic zone, terrestrial organic matter is monopolized according to increasing water depth. This trend is associated with grain size of sediments. The results also suggest that high pollen concentrations in whole organic matters may played an important role in excessive organic carbon in sediment.

Study on Engineering Properties of Earth Materials (흙의 공학적 성질에 관한 연구)

  • 김주범;윤충섭
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.17 no.3
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    • pp.3815-3832
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    • 1975
  • This study was made to investigate various engineering properties of earth materials resulting from their changes in density and moisture content. The results obtained in this study are summarized as follows: 1. The finner the grain size is, the bigger the Optimum Moisture Content(OMC) is, showing a linear relationship between percent passing of NO. 200 Sieve (n) and OMC(Wo) which can be represented by the equation Wo=0.186n+8.3 2. There is a linear relationship of inverse proportion between OMC and Maximum Dry Density (MDD) which can be represented by the equation ${\gamma}$d=2.167-0.026Wo 3. There is an exponential curve relationship between void ratio (es) and MDD whose equation can be expressed ${\gamma}$d=2.67e-0.4550.9), indicating that as MDD increases, void ratio decreases. 4. The coefficent of permeability increases in proportion to decrease of the MDD and this increase trend is more obvious in coarse material than in fine material, and more obvious in cohesionless soil than in cohesive soil. 5. Even in the same density, the coefficient of permeability is smaller in wet than in dry from the Optimum Moisture Content. 6. Showing that unconfined compressive strength increases in proportion to dry density increase, in unsaturated state the compacted in dry has bigger strength value than the compacted in wet. On the other hand, in saturated state, the compacted in dry has a trend to be smaller than the compacted in wet. 7. Even in the same density, unconfined compressive strength increases in proportion to cohesion, however, when in small density and in saturated state, this relationship are rejected. 8. In unsaturated state, cohesion force is bigger in dry than in wet from OMC. In saturated state, on the other hand, it is directly praportional to density. 9. Cohesion force decreases in proportion to compaction rate decrease. And this trend is more evident in coarse matorial than in fine material. 10. Internal friction angle of soil is not influenced evidently on the changes of moisture content and compaction rate in unsaturated state, On the other hand in saturated state it is influenced density. 11. Cohesion force is directly proportional to unconfined compressive strength(qu), indicating that it has approximately 35 percent of qu in unsaturated state and approximately 70 percent of qu in saturated state.

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Analysis of Scale Sensitivity of Landscape Indices for the Assessment of Urban Green Areas (도시녹지 평가를 위한 경관지수의 스케일 민감성 분석)

  • Lee, In-Sung;Yoon, Eun-Joo
    • Journal of the Korean Institute of Landscape Architecture
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    • v.36 no.2
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    • pp.69-79
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    • 2008
  • Landscape indices are effective tools to explain the spatial structure and patterns of ecological landscape including area/density, shape, core area, isolation/proximity, contagion/interspersion, and connectivity. More than 100 indices have been developed and an increasing amount of research explains changes in urban spaces using the indices. However, landscape indices have a high level of sensitivity to the scale of analysis - grain size and extent. If the scale sensitivity of indices is not considered, the research may produce inaccurate results. This study examines the scale sensitivity of landscape indices to find relatively stable indices in the complex geographical features of Korea. The scale sensitivity was analyzed using 20 categories of grain size and 41 categories of extent change. Landsat TM and ETM+ images of five years - 1985, 1991, 1996, 2000 and 2003 - were used, and 54 class level indices mounted on the FRAGSTATS program were examined. The results are as follows: First, according to the analysis of the scale sensitivity, 19 out of 54 class level indices were found to be stable to scale change. Second, the scale sensitivity was closely related to the green area ratio, and the typical threshold of change was $40{\sim}50%$. Third, among the 16 indices which were frequently used in the research in Korea, only 6 indices were relatively stable to the scale change. These results can be an effective basis for the selection of indices in the landscape ecology research in Korea.

Temporal Adjustment of Channel Geometry and Spatial Changes in Riverbed Materials along the Downstream Channels of Large Dams in the Geum River basin (금강유역 대형댐 하류 하도지형 경년변화 및 하상재료 종적변이 연구)

  • Ock, Giyoung;Choi, Mikyoung;Park, Hyung-Geun
    • Ecology and Resilient Infrastructure
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    • v.6 no.4
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    • pp.287-294
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    • 2019
  • This study investigated longitudinal changes in riverbed materials properties and temporal alteration of river channel geomorphology in the Geum River basin, where two multipurpose dams(Yongdam Dam and Daecheong Dam) were built in upstream area. We carried out grain size distribution analyses and measured soil organic matter contents of riverbed materials taken at the upper and lower sites of the two large dams. We also estimated the channel width, bar area and vegetation encroachment using the oldest map and aerial photographs taken before and after the construction of the dams. The results can contribute to increasing understandings of dam induced habitat alteration in river ecosystem.

The Effects of Electrodeposited Lead Dioxide Structure on the Ozone Evolution (전착이산화납 결정구조가 전해에 의한 오존발생에 미치는 영향)

  • Kim, In Hwan;Lee, Choong Young;Nam, Chong Woo
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.280-288
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    • 1996
  • In the ozone evolution using $PbO_2$, which was electrodeposited on Ti plate at various conditions in electrolyte, the effects of lead dioxide structure on the current efficiency and surface structure changes of lead dioxide were investigated. Also the effects of oxygen transfer reaction on the ozone evolution were investigated by means of a $PbO_2$ electrodeposited on the platinum rotating disk electrode. In order to develope an electrode for ozone evolution, durability of lead dioxide and optimum current density were investigated. At the electrodeposited lead dioxide with the larger grain size and higher crystallinity, the efficiency for ozone evolution was higher. Optimum current density to electrodeposite lead dioxide with large grain size and high crystalinity was $50mA/cm^2$. Lead dioxide deposited in the presence of glycerin showed the best advantage of ozone evolution. Also lead dioxide electrodeposited at less than $10mA/cm^2$ or at more than $100mA/cm^2$ has poor performance of ozone evolution and poor adhesive strength to substrate. In the beginning of ozone evolution, surface structure of lead dioxide was changed and this change resulted in good effects on ozone evolution. Lead dioxide doped with other elements was favorable not to ozone evolution but to oxygen evolution, so it is speculated that ozone evolution has not intermediate stage of oxygen evolution and occurs competitively with oxygen evolution. When ozone was evolved at $0.7{\sim}0.8A/cm^2$, the current efficiency was highest.

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