• 공업화학
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• 제31권6호
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• pp.630-634
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• 2020

We developed a processing recipe to synthesize flexible polyurethane foam with a pore size of 335 ± 107 ㎛. The gelling reaction time was varied from 0 to 30 minutes and the physical properties of the foam were evaluated. The gelling reaction where the polypropylene glycol and tolylene 2,4-diisocyanate (TDI) were reacted to form urethane prepolymer, proceeded until a chemical blowing agent, deionized water, was introduced. Fourier transform infrared (FT-IR) spectra showed that the composition of the foam did not change but the foam height reached a peak value when the gelling reaction time was 10 minutes. We found that increasing the gelling time lessened the coalescence and helped the formation of cells. Lastly, the repeatability of polyurethane foam was confirmed by one-way analysis of variance (ANOVA) by synthesizing ten identical polyurethane foams under the same experimental conditions, including the gelling reaction time. Overall, the new time parameter in-between the gelling and blowing reactions will give extra stability in manufacturing identical polyurethane foams and can be applied to various polyurethane foam processes.

• Tribology and Lubricants
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• 제22권5호
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• pp.260-268
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• 2006

The dielectric constants of used gasoline engine oils were obtained at a few temperatures and a frequency. Through analyzing the characteristics of dielectric constant, the related correlation between the changes in dielectric constants of oil and the degree of oil deterioration is going to be found. The dielectric constant was calculated using cross capacitances measured by a sensor tube. As results of the measurement of the fresh engine oil's dielectric constant, it was found that the value of dielectric constant was set down below $60^{\circ}C$ regardless changing frequency. Further, above 6 kHz, the dielectric constant was set down even if temperature was above $100^{\circ}C$ Therefore, for the measurement of used oils, it was selected the frequency of 6 kHz,,and the temperature of $80^{\circ}C$ preventing a certain ionic-conduction effects on the measured dielectric constant and the evaporation of a certain fluid mixed with engine oil. Specially, the effects of the mixing fluid like coolant, water and fuel on the fresh engine oil's dielectric constant were studied. It was found that the oil mixed with coolant showed the highest value, next water, and the lowest fuel. As results of the measurement of the used engine oil's dielectric constant, it was found that the possible changed rate of the used engine oil's dielectric constant based on the warning limit for engine oil in service was below 4% for gasoline engine oil.

• Tribology and Lubricants
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• 제22권5호
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• pp.290-300
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• 2006

The dielectric constants of used diesel engine oils were obtained at a few temperatures and a frequency. Through analyzing the characteristics of dielectric constant, the related correlation between the changes in dielectric constants of oil and the degree of oil deterioration is going to be found. The dielectric constant was calculated using cross capacitances measured by a sensor tube. As results of the measurement of the fresh engine oil's dielectric constant, it was found that the value of dielectric constant was set down below $60^{\circ}C$ regardless changing frequency. Further, above 6 kHz, the dielectric constant was set down even if temperature was above $100^{\circ}C$. Therefore, for the measurement of used oils, it was selected the frequency of 6 kHz, and the temperature of $80^{\circ}C$ preventing a certain ionic-conduction effects on the measured dielectric constant and the evaporation of a certain fluid mixed with engine oil. Specially, the effects of the mixing fluid like coolant, water and fuel on the fresh engine oil's dielectric constant were studied. It was found that the oil mixed with coolant showed the highest value, next water, and the lowest fuel. As results of the measurement of the used engine oil's dielectric constant, it was found that the possible changed rate of the used engine oil's dielectric constant based on the warning limit for engine oil in service was below 10% for diesel engine oil.

• 한국의상디자인학회지
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• 제9권2호
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• pp.85-92
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• 2007

This study focused on bean-juice treatment method which have dyeing property to indigo, yellow soil, sappan wood, cochineal and also on the possibility of applying to mordanting. This is different from the active mordanting using chemicals. Natural mordants with development of dyeing are not harmful, also are the medicines for disease. Limestone and ash neutralize the acidic soil. bean-juice protein adhere to cellulose surface and change the physical properties of protein so that coloring of dye is better than before and film non-soluble in water is made. Therefore the color made from bean-juice process lasts after washing. This study try to show one of the ways to improve the current method using the heavy metal which can have bad effects for environment and human being. Bean-juice(raw bean, heated bean) treatment method can be the way to fix the natural dyeing problem of bad dyeing. Bean-juice had been treated under various condition with pre-treatment, post-treatment and raw bean, heated bean. Following results are obtained in this study. In the case of Indigo dyeing, pre-treatment of heated bean shows the biggest difference of color. In the case of yellow soil dyeing, pre-treatment of raw bean-juice shows the biggest gap of color. Pre-treatment of heated bean in sappan wood dyeing case and post-treatment of raw bean show bigger color difference than pre-treatment of raw bean. In cochineal dyeing, raw bean pre-treatment shows the biggest color difference.

• 대한화학회지
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• 제31권5호
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• pp.444-451
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• 1987

에틸렌디아민, 프로필렌디아민 및 디에틸렌트리아민의 구리(II), 카드뮴(II) 및 아연(II)착이온의 桓元에 대하여 압력에 따른 폴라로그래피적 파라미터의 依存性을 조사하였다. 水銀滴下電極, 고인수은전극 및 나선형 백금선을 각각 作業電極, 基準電極 및 補助電極으로 사용하였다. 압력이 1기압에서 1,500기압으로 증가함에 따라 금속착이온의 還元半波電位는 陰電位 쪽으로 이동하였으며, 擴散電流는 상당히 커졌다. 이러한 현상은 전해질용액의 물리적 성질 곧 密度, 粘性度, 誘電常數, 電氣傳導度 등이 압력이 증가함에 따라 커지기 때문이다. 압력을 증가시키면 log plot의 기울기 값이 커지므로 환원반응의 可逆性은 나빠지고 있다. 25$^{\circ}$C ~ 35$^{\circ}$C의 온도범위에서 측정한 확산전류의 溫度係數가 압력을 증가시켜도 2%정도이므로 高壓下에서 폴라로그래피적 환원반응은 擴散支配的이다. 또 실험압력 범위내에서 금속착이온의 확산전류와 농도 사이에는 線形關係가 성립하였다.

• 동아시아식생활학회지
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• 제14권5호
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• pp.425-437
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• 2004

Medicinal plants are of great importance in providing healthcare to a large portion of the population in Korea. A number of plants are described in Dong-Ui-Bo-Gam for use in the treatment of allergic disorders, namely psoriasis, eczema, bronchial asthma, etc. In this study, we evaluated the effect of AllerQ, which is multi-complexes of various plants extracts such like Mori folium, Scutellaria baicallensis, Glycyrrhiza uralnsis, Mentha sacharinensis and Poncirus trifoliata on compound 48/80 induced anaphylactic shock, ovalbumin induced asthma in vivo and anti-IgE antibody induced hypersensitivity in vitro. We found antianaphylactic or antiallergic properties of AllerQ when given orally. AllerQ for prophylactic treatment for anaphylactic shocks have produced good results. AllerQ may modulate various aspects of immune function and allergic inflammation. In the present study, we analyse the effects of AllerQ on mast cell degranulation, mortality, cAMP/cGMP, O₂, H₂O₂ level, cyokine production and on the elicitation of IgE-mediated mast cell-dependent allergic inflammation in vivo and in vitro. We have established that AllerQ inhibited histamine release, cAMP/cGMP, O₂, H₂O₂ level, IL-4, tumor necrosis factor-alpha(TNF-α) and IL-6 production without having any significant physical change. These effects have been observed in mast cell(in vitro) and serum(in vivo) derived from three different origins that were activated by either immunological or non-immunological stimuli. These results suggest that the antianaphylactic and antiasthma tic action of AllerQ may be associated with an increase in the intracellular inhibition of the cAMP phosphodiesterase. Furthermore, AllerQ identified as potent inhibitors on O₂, H₂O₂ and cytokine activity. these data suggest that AllerQ may have an inhibitory role in mast cell-mediated allergic inflammation, and thus might be considered as an useful functional food.

• 한국수소및신에너지학회논문집
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• 제34권1호
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• pp.59-68
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• 2023

In this study, the performance of high-pressure fuel pumps was compared to find a high-pressure pump suitable for dimethyl ether (DME) fuel, and to establish a database of basic data on flow rates. The use of DME in compression ignition engines can reduce pollutant emissions. The cetane value of DME is higher than that of diesel fuel. The physical properties of DME are similar to liquefied gasoline gas (LPG), and when pressurized at a pressure of 6 bar or more, it changes from gas to liquid. Two types of high pressure pumps used in this study were independent injection type pump and a wobble plate type pump. Two high-pressure pumps with different injection types were compared. By measuring and comparing the performance changes of the two high-pressure pumps, a pump suitable for DME was selected and performance improvement measures were proposed. The changed experimental conditions to measure the performance change of the high pressure pump were increased in the units of 100 to 1,000 rpm and 100 rpm, and the experiment was performed at common rail pressures 300 and 400 bar. it was confirmed that the DME inside the fuel supply system remained in a liquid state through temperature sensors, pressure sensors, and pressure gauges. As a result of the experiment, it was confirmed that the flow rate discharged from the high-pressure fuel pump increased as the motor rotational speed increased, and the flow rate of the high-pressure fuel pump

• Journal of Biosystems Engineering
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• 제35권4호
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• pp.244-249
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• 2010

This study was conducted to define the optimal Lycium chinense miller washing method for developing the Lycium chinense cleaner and we analyzed the Lycium chinense miller washing characteristics for removing pesticides and microorganism according to washing methods; habitual washing method, air bubble washing method and nozzle spray washing method. The results were summarized as follows; 1. In case of measuring physical properties according to the varieties, maximum yield strength of Hokwang was 2.562 kgf, minimum yield strength of Hokwang was 0.269 kgf and average yield strength was about 1 kgf. 2. In case of measuring change of bacteria according to washing methods, the number of bacteria of non-washing method was more than the number of bacteria of habitual washing method or mechanical washing method and the number of nozzle spray washing method was least. 3. Ahjoksiseuteurobin of 0.218 ppm was detected in the untreated sample, 0.051 ppm was detected in the habitual washing method, 0.047 ppm was detected in the air bubble washing method and 0.034 ppm was detected in nozzle spray washing method. Every amount detected were less than 2 ppm that is reference value and the detected amount was least in case of nozzle spay cleaning method. Cypermethrin of 0.772 ppm was detected in the non-cleaned sample, 0.089ppm was detected in habitual washing method, 0.26 ppm was detected in the air bubble washing method and 0.292 ppm was detected in the nozzle spray washing method. Every detected amount of Cypermethrin were less than 5 ppm that is reference value and the detected amount was least in case of habitual washing method.

• KCI Concrete Journal
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• 제13권1호
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• pp.3-9
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• 2001

This research concerns the effect of kaolin as material of cement admixture. which has the advantage of low price and high adaptability. Kaolin, a kind of soil, is well known as a raw material of pottery. which is widely scat-tered on the earth (especially in Korea). This research shows the method and process for activating kaolin to have the properties of a cement admixture through experiment. In the experiments, kaolin is baked in high temperature and then cooled suddenly to be activated. The temperature zone and time span, on which kaolin is activated are examined. The research looks over the effect of the activated kaolin based on several criteria regarding to chemical and physical characteristic of general admixtures. The results of this research are as follows; kaolin start activation at the temperature above 50$0^{\circ}C$ and make ends of activation at the temperature below 95$0^{\circ}C$ and there was little effect by the change of duration. It is concluded that compressive strength can be increased by putting activated kaolin in the concrete and the activated kaolin is good for water resistance and anti-chemical , and that it is effective for protecting the leakage of hazardous article like Cl- and for protecting damage by an organic salt like acid. The activated kaolin of proper temperature and time is effective in compressive strength, salt resistance and acid resistance. The adaptability of activated kaolin as a cement admixture was shown through this research.

• 한국환경과학회지
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• 제19권3호
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• pp.379-387
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• 2010

Sediments of Little Scioto (LS) River in Ohio was contaminated by poor disposal of creosote from Baker Wood Creosoting Facility. Among the primary compounds of creosote, Polycyclic Aromatic Hydrocarbons (PAHs) are the most common ingredient PAHs are known for toxic, carcinogenic and mutagenic compounds. There are many difficulties to remove the PAHs in nature environment because their characteristics are having a less water-solubility, volatile and low mobility properties as increasing the molecular weight. The generation of hydroxyl radicals (${\cdot}OH$) and hydrogen peroxide ($H_2O_2$) forms as well as high temperature (5000 K) and pressure (1000 atm) by a physico-chemical effects of ultrasound during a cavitation collapse can promote the degradation and desorption of PAHs in sediment And it can also produces shock wave and microjets which are able to change the size and surface of particle in solid-liquid system as one of physical effects. Therefore, we explored to understand the role of particle size, the effect of elimination for PAHs concentration by ultrasound and optimize the conditions for ultrasonic treatment. The condition of various size of particles (> $150{\mu}m$, < $150{\mu}m$) and solid-liquid ratio (12.5g/L, 25g/L) for the treatment was considered and ultrasonic power (430 W/L) with liquid - hexane extraction and microwave extraction method were applied after ultrasound treatment.