• Title/Summary/Keyword: chain orientation

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The Effects of Long-Term Relationship Orientation on Green Supply Chain Management and Performance (기업 간 장기적 관계지향성이 그린공급사슬관리와 성과에 미치는 영향)

  • Lee, Seung GI;Kim, Byung-Keun;Park, Young Chan
    • Korean small business review
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    • v.39 no.1
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    • pp.59-87
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    • 2017
  • There is growing concern of the international community for the environmental issues including climate change. Scholars have examined various issues regrading Green Supply Chain Management (GSCM) but they mainly have focused on why firms introduce and implement GSCM from the persecutive of manufacturers. In particular, there has been few studies of green supply chain management in Korea. We investigate the effects of long-term relationships on green supply chain management and the relationship between GSCM and environmental performance. We also examine the relationship between long-term relationships and green information sharing, the effects of green information sharing on the GSCM. The data for this study were collected through a questionnaire survey on firms that participated in the Green Partnership Program of Korea Institute of Industrial Technology. Based on the responses of 155 firms the research model is empirically tested through a structural equation model. We found that long-term relationships facilitate GSCM significantly as it was expected. Green purchase and green product design also appears to improve environmental performance. Long-term relationship appears to affect positively green information sharing. Green information sharing does not have a statistically significant effect on environmental performance but show positive effect on GSCM including green purchase and green product design.

Efficiency of Rotational Operators for Geometric Manipulation of Chain Molecules

  • Seok, Chaok;Coutsias, Evangelos A.
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1705-1708
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    • 2007
  • Geometric manipulation of molecules is an essential elementary component in computational modeling programs for molecular structure, stability, dynamics, and design. The computational complexity of transformation of internal coordinates to Cartesian coordinates was discussed before.1 The use of rotation matrices was found to be slightly more efficient than that of quaternion although quaternion operators have been widely advertised for rotational operations, especially in molecular dynamics simulations of liquids where the orientation is a dynamical variable.2 The discussion on computational efficiency is extended here to a more general case in which bond angles and sidechain torsion angles are allowed to vary. The algorithm of Thompson3 is derived again in terms of quaternions as well as rotation matrices, and an algorithm with optimal efficiency is described. The algorithm based on rotation matrices is again found to be slightly more efficient than that based on quaternions.

The structure and synthesis of intercalation compound between a layered double hydroxide and an organic compound (유기화합물이 삽입된 층상이중수산화물의 합성과 구조)

  • 우은경;허영덕
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.36-41
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    • 1998
  • Intercalation compounds of alkyl sulfonates into layered double hydroxides (LDH) have been directly synthesized. From the X-ray diffraction data and the alkyl sulfonates size, the orientation of the intercalated alkyl sulfonate into the layered double hydroxide was determined. The intercalated alkyl sulfonate is arranged with molecular chain perpendicular to the hydroxide layer with an antiparallel pattern.

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DNA Light-strand Preferential Recognition of Human Mitochondria Transcription Termination Factor mTERF

  • Nam, Sang-Chul;Kang, Chang-Won
    • BMB Reports
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    • v.38 no.6
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    • pp.690-694
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    • 2005
  • Transcription termination of the human mitochondrial genome requires specific binding to termination factor mTERF. In this study, mTERF was produced in E. coli and purified by two-step chromatography. mTERF-binding DNA sequences were isolated from a pool of randomized sequences by the repeated selection of bound sequences by gel-mobility shift assay and polymerase chain reaction. Sequencing and comparison of the 23 isolated clones revealed a 16-bp consensus sequence of 5'-GTG$\b{TGGC}$AGANCCNGG-3' in the light-strand (underlined residues were absolutely conserved), which nicely matched the genomic 13-bp terminator sequence 5'-$\b{TGGC}$AGAGCCCGG-3'. Moreover, mTERF binding assays of heteroduplex and single-stranded DNAs showed mTERF recognized the light strand in preference to the heavy strand. The preferential binding of mTERF with the light-strand may explain its distinct orientation-dependent termination activity.

장기지향성과 자산특유성이 공급사슬관리 추진방식과 성과에 미치는 영향

  • Park, Jeong-Su;Kim, Su-Uk;Jang, Deok-Sin
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 2006.11a
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    • pp.346-361
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    • 2006
  • We establish two models -'intermediate' role model and 'infra-structural' role model - to confirm what role the concepts of 'long-term orientation' and 'asset specificity' execute in the context of supply chain management practices affect on SCM performances. We confirm the model's statistical significance with empirical investigation about 167 manufacturing companies in all over the country. As a result, we find that real data fits to 'infra-structural' role model with added paths of concepts and variables rather to 'intermediate' role model. We prove these results with empirical method of confirmatory factor analysis and structural equation model with AMOS program.

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Ferroelectric P(VDF/TrFE) Copolymers in Low-Cost Non-Volatile Data Storage Applications

  • Prabu A. Anand;Lee, Jong-Soon;Chang You-Min;Kim, Kap-Jin
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.237-237
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    • 2006
  • P(VDF/TrFE(72/28) ultrathin films were used in the fabrication of Metal-Ferroelectric polymer-Metal (MFM) single bit device with special emphasis on uniform film surface, faster dipole switching time under applied external field and longer memory retention time. AFM and FTIR-GIRAS were complementary in analyzing surface crystalline morphology and the resultant change in chain orientation with varying thermal history. DC-EFM technique was used to 'write-read-erase' the data on the memory bit in a much faster time than P-E studies. The results obtained from this study will enable us to have a good understanding of the ferroelectric and piezoelectric behavior of P(VDF/TrFE)(72/28) thin films suitable for high density data storage applications.

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25,27-Bis(1-propyloxy)calix[4]arene-26,28-[(5',6')(14',15')-dibenzo]crown-7, $C_{54}H_{58}O_9$

  • Kim, Jong-Seung;Kim, Moon-Jib;Lee, Jin-Ho;Kim, Jin-Gyu;Suh, Il-Hwan
    • Korean Journal of Crystallography
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    • v.10 no.1
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    • pp.28-32
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    • 1999
  • The title compound consisting of a calix[4]arene molecule with four phenyl rings arranged alternately in anti-orientation fashion, two propyloxy groups attached on the upper rim of calix[4]arene, and polyther chain with two phyenyl rings attached on the lower rim of calix[4]arene offers a big cavity inside a molecule with might a potential for forming host-guest complexes.

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Constitutive equations for polymer mole and rubbers: Lessons from the $20^{th}$ century

  • Wagner, Manfred H.
    • Korea-Australia Rheology Journal
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    • v.11 no.4
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    • pp.293-304
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    • 1999
  • Refinements of classical theories for entangled or crosslinked polymeric systems have led to incommensurable models for rubber networks and polymer melts, contrary to experimental evidence, which suggests a great deal of similarity. Uniaxial elongation and compression data of linear and branched polymer melts as well as of crosslinked rubbers were analyzed with respect to their nonlinear strain measure. This was found to be the result of two contributions: (1) affine orientation of network strands, and (2) isotropic strand extension. Network strand extension is caused by an increasing restriction of lateral movement of polymer chains due to deformation, and is modelled by a molecular stress function which in the tube concept of Doi and Edwards is the inverse of the relative tube diameter. Up to moderate strains, $f^2$ is found to be linear in the average stretch for melts as well as for rubbers, which corresponds to a constant tube volume. At large strains, rubbers show maximum extensibility, while melts show maximum molecular tension. This maximum value of the molecular stress function governs the ultimate magnitude of the strain-hardening effect of linear and long-chain branched polymer melts in extensional flows.

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Effect of Micro Organic-Inorganic Complex on Hydration of Portland Cement(I) Formation of Interlamella Complex between Montmorillonite and PVA (마이크로 유기-무기 복합체가 포틀랜드 시멘트 수화에 미치는 영향(I) MontmorillonitPVA 층간 화합물의 형성)

  • 김배연;김창은;최진호
    • Journal of the Korean Ceramic Society
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    • v.22 no.4
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    • pp.21-25
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    • 1985
  • For studying the influence of addition of Polyvinyl alcohol (PVA)-montmorillonite complex on the hydration of Portland cement the PVA-montmorillonite derivatives were prepared in advance an characterized system-of Portland cement the PVA-montmorillonite derivatives were prepared in advance and characterized systema-tically. PVA with the polymerizationdegree ranging from 500 to 2000 have been intercalated into the lamellar structure of hydrated montmorillonites which were fractionated under 2㎛ by Stock's rule. In all cases the constant basal spacing of ∼20Å was determined whatever the molecular weight of PVA used. And the carbon chain orientation of PVA in the interfoliar space has been deduced to be parallel with bilayer structure.

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Dyeing Study on DMF-Modified Polyesters for Morphology Characterization

  • Park, Myung-Ja
    • The International Journal of Costume Culture
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    • v.5 no.2
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    • pp.53-65
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    • 2002
  • Morphology of polyester fiber was physically modified by solvent treatment. PET fiber was treated with N,N-dimethylformamide (DMF) at 100, 120, $140^{circ}C$ for 10 minutes without tension. The structural changes in the morphology of DMF-induced modified PET fiber were FTIR and SEM analysis. Also dyeing behavior of DMF-treated polyester fibers with various disperse dyes was studied to detect changes of amorphous area in fine structure. DMF treatment resulted in increases in total void content, degree of crystallinity, trans isomer content, chain folding, segmental mobility and molecular packing, but it resulted in decreases in amorphous orientation, intermolecular forces and individual void size through longitudinal shrinkage, lateral welling and removal of oligomers. Void-size distribution could be estimated from the dye uptake with various sizes of disperse dyes. In contrast to the large increases in dye uptake with small dye molecules, there is no and little dye uptake with the bulkiest dye, which means that void size is bigger or smaller than the volume of each dye. Diffusion rates of dye molecules showed increases. This dyeing study revealed that the disperse dyeing is very effective method for characterizing the internal morphology of polyester fiber.

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