• Title/Summary/Keyword: chain decay

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Analysis of the Surface Degradation in UV-irradiated High-Temperature Vulcanized Silicone Rubber (자외선 조사된 HTV 실리콘 고무의 표면열화 분석)

  • 연복희;이태호;허창수;이종한
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.5
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    • pp.411-419
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    • 2000
  • In this paper we have investigated the surface degradation by ultraviolet-irradiation in high-temperature vulcanized silicone rubber. Through the measurement of surface potential decay by corona-charging and of contact angle it is found that the change of surface electrostatic properties and the decrease of contact angle under UV-radiation. For the changes in micro-morphological and chemical structure of the UV-treated silicone rubber we utilized several analytical techniques such as SEM, ATR-FTIR,XPS. From this study it is shown that the chemical reactions(scissoring of side chain(S-$CH_3$) cross-linking and branching) occur on the surface of silicone rubber during the UV-irradiation. Also we obtained the results of the loss of low molecular weight chain by cross-linking and oxidation reaction.

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Calculation of Low-Energy Reactor Neutrino Spectra for Reactor Neutrino Experiments

  • Riyana, Eka Sapta;Suda, Shoya;Ishibashi, Kenji;Matsuura, Hideaki;Katakura, Jun-ichi
    • Journal of Radiation Protection and Research
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    • v.41 no.2
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    • pp.155-159
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    • 2016
  • Background: Nuclear reactors produce a great number of antielectron neutrinos mainly from beta-decay chains of fission products. Such neutrinos have energies mostly in MeV range. We are interested in neutrinos in a region of keV, since they may take part in special weak interactions. We calculate reactor antineutrino spectra especially in the low energy region. In this work we present neutrino spectrum from a typical pressurized water reactor (PWR) reactor core. Materials and Methods: To calculate neutrino spectra, we need information about all generated nuclides that emit neutrinos. They are mainly fission fragments, reaction products and trans-uranium nuclides that undergo negative beta decay. Information in relation to trans-uranium nuclide compositions and its evolution in time (burn-up process) were provided by a reactor code MVP-BURN. We used typical PWR parameter input for MVP-BURN code and assumed the reactor to be operated continuously for 1 year (12 months) in a steady thermal power (3.4 GWth). The PWR has three fuel compositions of 2.0, 3.5 and 4.1 wt% $^{235}U$ contents. For preliminary calculation we adopted a standard burn-up chain model provided by MVP-BURN. The chain model treated 21 heavy nuclides and 50 fission products. The MVB-BURN code utilized JENDL 3.3 as nuclear data library. Results and Discussion: We confirm that the antielectron neutrino flux in the low energy region increases with burn-up of nuclear fuel. The antielectron-neutrino spectrum in low energy region is influenced by beta emitter nuclides with low Q value in beta decay (e.g. $^{241}Pu$) which is influenced by burp-up level: Low energy antielectron-neutrino spectra or emission rates increase when beta emitters with low Q value in beta decay accumulate Conclusion: Our result shows the flux of low energy reactor neutrinos increases with burn-up of nuclear fuel.

Algorithm for Calculating Uncertainty in the Computational Simulation for Radiochronometry of Nuclear Materials (핵물질 연대추정을 위한 전산모사 불확도 계산 알고리즘)

  • Jae-Chan Park;Tae-Hoon Jeon;Jin-Young Chung;Jung-Ho Song
    • Journal of the Korean Society of Radiology
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    • v.17 no.7
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    • pp.1075-1089
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    • 2023
  • Nuclear forensics is an essential part of nuclear material control and nuclear non-proliferation verification. Radiochronometry for nuclear forensics is used to estimate the timing of refinement and production of nuclear materials based on decay chain characteristics and the Bateman equation. The results of radiochronometry have uncertainties because the decay constant and number of nuclides are statistics derived from analyses or repeated experiments and involve uncertainties. The aim of this study was to develop an uncertainty calculation algorithm by performing computational simulation to overcome the limitations of the existing uncertainty calculation method for radiochronometry based on the Bateman equation. The results of the proposed uncertainty calculation algorithm were comparable to those of the existing method. The algorithm allowed for more than two generations of uncertainty calculations and mitigated the underestimation of the decay constant during the uncertainty calculation.

PHYSICAL PROPERTIES OF VAR10US BRANDS OF ELASTOMERIC CHAINS (수종의 합성 고무탄성재의 성질에 관한 연구)

  • Kim, Kyung-Ho;Hwang, Chung-Ju;Sung, Sang-Jin
    • The korean journal of orthodontics
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    • v.27 no.6 s.65
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    • pp.943-954
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    • 1997
  • Forces needed for orthodontic tooth movement are obtained from various appliances such as orthodontic wires or elastic rubber. Orthodontic elastic rubber is widely used clinically, but permanent deformation and force decay may occur from the environmental changes, time of clinical use and the extent of the stretch, making the Prediction of force being applied difficult. The Present study examined and compared the changes in residual force between three brands of elastomeric chains (Ormco Generation II Power Chains ; brand A, RMO : Energy-Chain ; brand B, Unitek : AlastiK ; brand C) under various environmental conditions, amount of initial force, types of elastomer and the rate of extension. The characteristic physical properies of the elastomeric chains were as follows. 1. In all three brands, the residual force ratio was largest when the chains were stored in air, with no difference between water and saliva. 2. In all three brands, after 24 hours, there was no statistical difference in residual force ratio according to the initial force level. 3. In Brand A and B, the presence of filament had no correlation with the residual force ratio. In Brand C force decay was more severe when the chain contained filament. 4. In each brand, rate of extension had no effect on residual force ratio. 5. Brand B showed relatively higher residual force ratio compared to other brands.

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Analysis of the Surface Degradation in UV-irradiated Poly(ethylene terephthalate) films (자외선 조사된 Poly(ethylene terephthalate) 필름의 표면 열화 분석)

  • Lim, K.B.;Lee, B.S.;Hwang, M.H.;Kim, Y.Y.;Lim, H.C.;Chi, C.S.;Nam, K.W.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1457-1459
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    • 2001
  • This paper deals with the change of surface Potential decay, surface resistivity, contact an91e and XPS of ultraviolet-treated PET films. From the experimental results on the surface Potential decay of UV degraded-samples, it was found that the accumulation of charge is decreased and the surface potential decay time is shortened. Also, from the result of XPS, it was found that the changes affected by the surface degradation of PET film were caused by the generation of carboxyl groups through the chain decomposition and recombination with oxygen molecules in the air.

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Effects of Water Treating on Surface Properties of Epoxy Insulation Materials (Epoxy 절연재료이 표면특성에 미치는 수분처리의 영향)

  • Lim, Kyung-Bum;Lee, Duck-Chool
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.10
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    • pp.553-558
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    • 2000
  • This paper deals with change of contact angle, surface potential decay, surface resistivity and XPS of water-treated epoxy insulator. From the experimental results on the contact angle was reduced from $74^{\circ}$to $24^{\circ}$ due to the formation of polar hydroxyl groups on surface which was associated with intermolecular reaction between epoxy chains of three-dimensional network structure and water molecules. From the experimental results in the surface potential decay of water treated-samples, it was found that the accumulation of charge is decreased and the surface potential decay time is shortened by the interaction of polar hydroxyl groups induced on the treated surface as the increment of treatment time. The positive charging on the treated surface compared with negative charging is relatively lowered by the induction of polar hydroxyl groups. The surface resistivity was changed from $10^{15}[{\Omega}/cm^2$] to $10^{12}[{\Omega}/cm^2$] caused by water treatment. From XPS, it was found that the changes affected by the surface degradation of epoxy were caused by the generation of carboxyl groups through the chain decomposition and recombination with oxygen molecules in the air.

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Stability of matching boundary conditions for diatomic chain and square lattice

  • Ji, Songsong;Tang, Shaoqiang
    • Coupled systems mechanics
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    • v.7 no.3
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    • pp.255-268
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    • 2018
  • Stability of MBC1, a specific matching boundary condition, is proved for atomic simulations of a diatomic chain. The boundary condition and the Newton equations that govern the atomic dynamics form a coupled system. Energy functions that decay along with time are constructed for both the boundary with the same type atoms and the one with different type atoms. For a nonlinear chain, MBC1 is also shown stable. Numerical verifications are presented. Moreover, MBC1 is proved to be stable for a two dimensional square lattice.

Characteristics of Polarization hologram in a side-chain polymalonic ester (측쇄형 광기능성 고분자 PCN에서의 편광홀로그램 특성)

  • 주원제;오차환;송석호;김필수;김봉철;한양규
    • Korean Journal of Optics and Photonics
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    • v.10 no.5
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    • pp.386-390
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    • 1999
  • Erasable polarization holographic grating was recorded with two-wave mixing in PCN which was side-chain liquid crystalline polymalonic esters containing two symmetrical 4-cyanoazobenzene as photoresponsive groups. The diffraction efficiency of recorded grating was measured and the characteristics of recording, decay in a dark room and erasing by circularly polarized light were investigated. As the results, birefringence, $\Delta$n of PCN was measured $6.5{\times}10^{-2}$, which was 0~100 times higher than those of crystals such as Fe:$LiNbO_3$, Ce:$BaTiO_3$ crystals. Dark decay rates was $4.3{\times}10^{-5}$ %/hour, which showed the possibility of application as data storage media.

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