• Title/Summary/Keyword: ceramic pellet

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Influence of sintering temperature of MgO pellet on the electro-optical characteristics of alternating current plasma display panel (AC-PDP)

  • Hong, Sung-Hee;Son, Chang-Gil;Jung, Seok;Kim, Jung-Seok;Paik, Jong-Hoo;Choi, Eun-Ha
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.400-403
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    • 2008
  • We have investigated the electro-optical characteristics of AC-PDP with different MgO protective layers, which have been deposited by electron beam evaporation from various sintered pellets with different temperatures. We have measured the secondary electron emission coefficient ($\gamma$) by using the Gamma Focused Ion Beam ($\gamma$-FIB) system, the static margin, and the address delay time. Also, we have investigated photoluminescence (PL) characteristics for understanding the energy levels of MgO pellets and protective layers.

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A New Type of Nonthermal Plasma Reactor

  • Geum, Sang-Taek;Moon, Jae-Duk;Jun, Sun-Gon
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.245-249
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    • 1999
  • A new type of nonthermal plasma reactor utilizing ferroelectric pellets is proposed to generate nonthermal plasma efficiently, which is used for simultaneous control of various pollutant gases. Electric charges stored on ferroelctric pellets by corona discharge between a corona tip and a mesh electrode provide partial electrical discharges among ferroelectric pellets. These partial electrical discharges can enhance partial discharges around the surface of ferroelectric pellets. This method utilizes wide reacting area of ferroelectric pellets and partial discharge. Positive and negative dc voltage are applied to the corona tip to generate partial discharges, and corona currents are estimated to investigate charge storage on ferroelectric pellets as function of time and charge relaxation time constants of ferroelectric pellects. As a result, charge relaxationtime, dielectric constants of ferroelectric pellets, polarity of applied voltage and applied time influence partial discharges among ferroelectric pellect.

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Microstructure Observation of the Grain Boundary Phases in ATF UO2 Pellet with Fission Gas Capture-ability (핵분열 기체 포획 기능을 갖는 사고저항성 UO2 펠렛에서 형성되는 입계상의 미세구조 관찰)

  • Jeon, Sang-Chae;Kim, Dong-Joo;Kim, Dong Seok;Kim, Keon Sik;Kim, Jong Hun
    • Journal of Powder Materials
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    • v.27 no.2
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    • pp.119-125
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    • 2020
  • One of the promising candidates for accident-tolerant fuel (ATF), a ceramic microcell fuel, which can be distinguished by an unusual cell-like microstructure (UO2 grain cell surrounded by a doped oxide cell wall), is being developed. This study deals with the microstructural observation of the constituent phases and the wetting behaviors of the cell wall materials in three kinds of ceramic microcell UO2 pellets: Si-Ti-O (STO), Si-Cr-O (SCO), and Al-Si-Ti-O (ASTO). The chemical and physical states of the cell wall materials are estimated by HSC Chemistry and confirmed by experiment to be mixtures of Si-O and Ti-O for the STO; Si-O and Cr-O for SCO; and Si-O, Ti-O, and Al-Si-O for the ASTO. From their morphology at triple junctions, UO2 grains appear to be wet by the Si-O or Al-Si-O rather than other oxides, providing a benefit on the capture-ability of the ceramic microcell cell wall. The wetting behavior can be explained by the relationships between the interface energy and the contact angle.

Development of gas sensor using $Pt/MoO_{3}$ system ($Pt/MoO_{3}$ 구조를 이용한 가스 센서의 개발)

  • 김창교;김진걸;유광수;최용일;한득영
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.2
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    • pp.213-219
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    • 1996
  • Pellet type $Pt/MoO_{3}$ gas sensor which is operating at much lower temperature than conventional ceramic sensors such as $SnO_{2}$ or ZnO was fabricated. Morphology and crystal structure of $Pt/MoO_{3}$ according to calcination temperature have been characterized with Transmission Electron microscopy and X-Ray powder diffraction. The characterization indicates that as calcination temperature is increased, overlayers of $MoO_{3}$ on Pt are produced, but additionally, the Cl content associated with the Pt phase diminishes. The gas dasorption test showed that the change in surface morphology is closely related to hydrogen storage capacity of the sample. The gas sensitivities at $50^{\circ}C$ and $150^{\circ}C$ are very high.

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Characteristics of Electrical Properties, Ozone Generation and Decomposition of Volatile Organic Compounds by Nonthermal Plasma Reactor Packed with SBT Ferroelectric (SBT 강유전체 충전층 저온 플라즈마 반응기의 전기적 특성, 오존생성 및 휘발성유기화합물의 분해)

  • Eo, Joon;Kim, Il Won;Park, Jin Do;Lee, Joo Young;Lee, Hak Sung
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.249-254
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    • 2011
  • A nonthermal plasma reactor in conjunction with a tubular type with a ferroelectric (high-dielectric ceramic) pellet layer was designed and constructed. $SrBiTaO_9$ (SBT) pellets with 2.0 mm in diameter were held within the tube arrangement by two metal mesh electrodes (20 mm separation) connected to a high-voltage AC power supply. The dielectric constant of SBT pellets was 150 at room temperature and 500 at curie temperature ($335^{\circ}C$). The generation rate of ozone in the plasma reactor almost linearly increased with increasing applied voltage. In the case of the plasma reactor packed with SBT pellets the generation rate of ozone sharply increased at the applied voltage more than 20 kV. The ozone generation rate at the negative corona discharge was higher than that of the positive corona discharge. However, the destruction efficiency of toluene and methylene chloride was not increased in proportion to ozone concentration.

Effect of CH3COOH Concentration on Characteristics of Fe2O3Supported δ-alumina Catalyst by Hydrothermal Method (CH3COOH 농도가 수열법으로 제조된 Fe2O3 담지 감마알루미나 촉매의 특성에 미치는 영향)

  • 박병기;이정민;서동수
    • Journal of the Korean Ceramic Society
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    • v.40 no.8
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    • pp.758-764
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    • 2003
  • The cylindrical ${\gamma}$-alumina pellets were prepared by forming, hydration, drying and calcination after mixing amorphous alumina and pore generating agent with water. Concentration of Fe(NO$_3$)$_3$ㆍ9$H_2O$ that was catalyst precursor was fixed and made mixing solution that changed concentration of $CH_3$COOH in range of 2.5~20%, and here ${\gamma}$-alumina pellets were immerged and were hydrothermaly treated for 3 h at $200^{\circ}C$. And then we investigated creation and change of crystal, pore characteristics, $N_2$ adsorption and desorption isotherms, changes of acid site and mechanical strengths etc. According to the concentration of $CH_3$COOH, the crystals grew to acicular shape of 0.5~2${\mu}m$ length, and crystal structure showed the pseudo-boehmite structure. When hydrothermaly treated in 10% $CH_3$COOH solution, pore volume between 100~1000 $\AA$ was highest by 0.86 cc/g, and width of hysteresis curved line due to $N_2$ adsorption/desorption appeared as was smallest. When concentration of $CH_3$COOH was in range of 5~15%, new C-H functional groups were formed. Mechanical strength of pellets was highest by 1.35 MPa when $CH_3$COOH concentration was 2.5%.

Preparation of Fe2O3 Supported γ-alumina Catalyst by Hydrothermal Method (수열법에 의한 Fe2O3 담지 감마알루미나 촉매제조)

  • 박병기;이정민;서동수
    • Journal of the Korean Ceramic Society
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    • v.40 no.7
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    • pp.683-689
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    • 2003
  • The cylindrical ${\gamma}$-alumina pellets were prepared using amorphous alumina and pore generating agent. Its were immersed in aqueous solution of the mixture of Fe(NO$_3$)$_3$.9$H_2O$ and $CH_3$COOH, Fe(NO$_3$)$_3$.9$H_2O$ and $CH_3$COOH and HNO$_3$, and Fe(NO$_3$)$_3$.9$H_2O$ and HNO$_3$. The pellets thus were hydrothermally treated at 20$0^{\circ}C$ for 3 h in autoclave, and were investigated morphologies and changes of crystal pore characteristics, $N_2$ adsorption and desorption isotherms, active sites and mechanical strength etc. According to the preparation method, acicular platelet pseudo-boehmite crystals of 0.1~0.3 ${\mu}{\textrm}{m}$ size were transformed into acicular pseudo-boehmite cristals of 0.5~2 ${\mu}{\textrm}{m}$ size having the same crystal structure. When ${\gamma}$-alumina pellets were immersed in aqueous solution of the mixture of Fe(NO$_3$)$_3$.9$H_2O$ and $CH_3$COOH and then were hydrothermally treated, pore volume between 100 $\AA$ and 1000 $\AA$ was increased from 0.34 ㏄/g to 0.86 ㏄/g, and the gap of $N_2$ adsorption and desorption hysteresis loop was decreased due to increasement of pore size. New active site that could adsorb the C-H functional group was created on the catalist. Also, mechanical strength of catalyst was increased from 1.06 ㎫ to 1.36 ㎫.

Fabrication of Porous Ceramics for Microorganism Carrier by Hydrothermal Reaction (수열반응을 이용한 미생물 담체용 다공성 세라믹스의 제조)

  • 양성구;정승화;강종봉
    • Journal of the Korean Ceramic Society
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    • v.40 no.12
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    • pp.1213-1219
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    • 2003
  • Porous ceramics for microoganism carriers were prepared with amorphous alumina and pore formers by hydrothermal reaction, burn-out and wash-out method. Activated carbon with average size of 67,222, and 405 $\mu\textrm{m}$, organic polymer and inorganic salt were used as pore formers. Specimens were hydrothermally treated at 200$^{\circ}C$ for 24 h, heat-treated at 650$^{\circ}C$ for 5 h, and washed out at 80$^{\circ}C$ for 48 h. The formation of crystalline phase, porosity, pore size distribution and compressive strength were measured. The specimen with activated carbon was transformed to boehmite phase, but organic polymer and inorganic salt inhibited the aquohydroxoy complex gel and crystalline formation. The porous ceramics for microoganism carriers using activated carbon as a pore formers was successfully prepared, which is composed of ${\gamma}$-alumina phase with porosity of above 70 vol% and the compressive strength of 40 kgf/$\textrm{cm}^2$.

Effect of In2O3 Doping on the Properties of ZnO Films as a Transparent Conducting Oxide (투명전도성 ZnO 박막의 특성에 미치는 In2O3 첨가에 따른 영향)

  • Lee, Choon-Ho;Kim, Sun-Il
    • Journal of the Korean Ceramic Society
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    • v.41 no.1
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    • pp.57-61
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    • 2004
  • Zinc Oxide (ZnO) have the crystal structure of wurtzite which is semiconducting oxide with band gap energy of 3.3eV. $In_2O_3$-doped ZnO films were fabricated by electron beam evaporation at $400^{\circ}C$ and their characteristics were investigated. The content of $In_2O_3$ in ZnO films had a marked effect on the electrical properties of the films. As $In_2O_3$ content decreased. $In_2O_3$-doped ZnO films was converted amorphous into crystallized films and showed a better characteristics generally as a transparent conducting oxide. As $In_2O_3$-doped ZnO films were prepared by $In_2O_3$-doped ZnO pellet with 0.2at% of $In_2O_3$ content, the value of resistivity was about $6.0 {\times} 10^{-3} {\Omega}cm$. The transmittance was higher than 85% throughout the visible range.

Effects of High Energy Ball Milling on the Piezoelectric Properties of Lead-free (K0.44Na0.52)(Nb0.86Ta0.10)-0.04LiSbO3 Ceramics (고에너지 볼 밀링을 이용한 (K0.44Na0.52)(Nb0.86Ta0.10)-0.04LiSbO3 무연 압전 세라믹스의 특성)

  • Kim, Young-Hyeok;Heo, Dae-Young;Tai, Weon-Pil;Lee, Jae-Shin
    • Journal of the Korean Ceramic Society
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    • v.45 no.6
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    • pp.363-367
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    • 2008
  • Lead-free $(K_{0.44}Na_{0.52})(Nb_{0.86}Ta_{0.10})-0.04LiSbO_3$ piezoelectric ceramics have been synthesized by conventional sintering process and then investigated on the sintering and piezoelectric properties by high energy ball milling (HEBM) treatment. The powders milled for different time are characterized by XRD, FE-SEM. The powders are pressed into a pellet and sintered. It is found that the piezoelectric properties of sintered specimens are strongly dependent on the milling time. The piezoelectric properties are enhanced by high energy ball milling treatment. The planer electromechanical coupling factor ($k_p$) and piezoelectric constant ($d_{33}$) of a specimen sintered at $1050^{\circ}C$ are 0.44 and 267 pC/N, respectively.