• Title/Summary/Keyword: ceramic nano coating

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The Synthesis and Optical Properties of Silica Coated CdSe/ZnS QDs (실리카가 코팅된 양자점의 코팅두께에 따른 광 특성 변화)

  • Lee, Ji-Hye;Shin, Hyun Ho;Lee, Jong-Heun;Hyun, Sang Il;Koo, Eunhae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.3
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    • pp.221-226
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    • 2013
  • The water soluble quantum dots (QDs) are synthesized by the phase transfer and silica coating reaction. The photoluminescence intensity of silica-coated QDs are mainly affected by the amount of phase transfer agent, SDS (sodium dodecyl sulfate), and the maximum value is obtained at the cmc (critical micell concentration) concentration of SDS in the phase transfer reaction. Based on fluorescence spectra and field emission transmission electron microscope (FETEM), the energy transfer rate by forster resonance energy transfer (FRET) is increasing with the thickness of the silica shell coated on CdSe/ZnS QDs.

Investigation of Dispersion Stability of Conductive Nano Ink Using 1-Octanethiol Coated Copper Nano Powders (1-Octanethiol이 코팅된 나노 구리 분말을 이용한 나노 잉크의 분산도에 대한 연구)

  • Cho, Danee;Baik, Jong-Hwan;Park, Joong-Hark;Lee, Caroline Sunyong
    • Journal of the Korean Ceramic Society
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    • v.49 no.5
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    • pp.417-422
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    • 2012
  • Copper nano particles have been considered as the materials for conductive ink due to its good thermal, electrical conductivity and low cost. However, copper nanoparticles oxidize easily, decreasing dispersion stability and electrical conductivity. Therefore, it is important to develop a method to minimize oxidation of copper nano particles to improve its dispersion stability property in copper nano ink. In this study, copper nano particles were coated with 1-Octanethiol VSAM(Vaporized Self Assembled Multilayers) to prevent oxidation and coated copper powders were dispersed in conductive ink successfully by studying its relationship of different chain length of solvents to 1-Octanethiol coating layer to fabricate nano ink. Various alcohol solvents, such as 1-Hexanol, 1-Octanol, and 1-Decanol were used. The coating layer was observed using FESEM and TEM. Furthermore, dispersion of copper nano particles in nano inks, was characterized using Turbiscan analyzer, viscometer, and contact angle measurement tool.

The properties and wear behavior of HVOF spray coating layer of Co-alloy powder

  • Cho, Tong-Yul;Yoon, Jae-Hong;Kim, Kil-Su;Youn, Suk-Jo;Back, Nam-Ki;Chun, Hui-Gon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.6
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    • pp.273-277
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    • 2006
  • High velocity of oxy-fuel (HVOF) thermal spray coating is progressively replacing the other classical hard coatings such as chrome plating and ceramic coating by the classical methods, since the very toxic $Cr^{6+}$ ion is well known as carcinogen causing lung cancer, and the ceramic coatings are brittle. Co-alloy T800 powder is coated on the Inconel 718 substrates by the HVOF coating procesess developed by this laboratory. For the study of the possibility of replacing of chrome plating, the wear properties of HVOF Co-alloy T800 coatings are investigated using the reciprocating sliding tester with a counter sliding SUS 304 ball both at room and at an elevated temperature of $1000^{\circ}F\;(538^{\circ}C)$. The possibility as durability improvement coating is studied for the application to the high speed spindles vulnerable to frictional heat and wear. Wear mechanisms at the reciprocating sliding wear test are studied far the application to the systems similar to the sliding test such as high speed spindles. Wear debris and frictional coefficients of T800 coatings both at room and at an elevated temperature of $538^{\circ}C$ are drastically reduced compared to those of non-coated surface of Inconel 718 substrates. Wear traces and friction coefficients of both coated and non-coated surfaces are drastically reduced at a high temperature of $538^{\circ}C$ compared with those at room temperature. These show that the coating is highly recommendable far the durability Improvement coating on the surfaces vulnerable to frictional heat and wear.

High-Transmittance Films Coated from Silica Colloidal Nano-Particles (II) (실리카 콜로이드 나노입자를 이용한 반사 방지막의 제조 (II))

  • Hwang, Yeon
    • Journal of the Korean Ceramic Society
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    • v.42 no.6 s.277
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    • pp.399-404
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    • 2005
  • Anti-reflection film was coated by using spherical silica nano colloidal particles and fumed silica particles. Silica colloid sol was reserved between two inclined slide glasses by capillary force, and particles were stacked to form a film onto the substrate as the upper glass was sliding. The deposition processes were studied to enhance the wavelength dependency of the light transmittance and to control the effective refractive index of the film. Both of the spherical and fumed silica particles showed an enhancement of $4.0-4.4\%$ in light transmittance by one step coating. The dependence of the transmittance on wavelength was largely improved at the longer wavelength by partial coating of fumed particles on the film of spherical particles. The effective refractive index of the film was controlled by removing latex particles that were co-deposited with silica particles. Using this process the light reflectance from one side of the glass substrate could be reduced from $4.2\%$ to $0.6\%$ although zero reflectance was not achieved due to the agglomeration of the latex particles.

Synthesis of AlO(OH) Nano Colloids from γ-Al2O3 via Reversible Process (γ-Al2O3로부터 가역과정을 경유한 AlO(OH) 나노콜로이드의 합성)

  • Cho, Hyun-Ran;Kim, Sook-Hyun;Park, Byung-Ki
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.288-294
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    • 2009
  • The platelet AlO(OH) nano colloids were prepared by hydrothermal reaction of the $\gamma-Al_2O_3$ obtained with dehydration of $\gamma$-AlO(OH) and dilute $CH_3COOH$ solution. In hydrothermal reaction process, reversible reaction was accompanied between $\gamma-Al_2O_3$ and AlO(OH), and hydrothermal reaction temperature, hydrothermal reaction time and $CH_3COOH$ concentration had an effect on the crystal structure, surface chemical property, surface area, pore characteristics and crystal morphology of the AlO(OH) nano colloid particles. In this study, it was investigated to the hydrothermal reaction condition of the AlO(OH) nano colloid for using catalyst support, heat resisting agent, adsorbents, binder, polishing agent and coating agent. The crystal structure, surface area, pore volume and pore size of the platelet AlO(OH) nano colloids were investigated by XRD, TEM, TG/DTA, FT-IR and $N_2$ BET method in liquid nitrogen temperature.

Ceramic Coating by Electron Beam PVD for Nanos-Tructure Control (나노구조 제어를 위한 EB-PVD법에 의반 세라믹스 코팅)

  • Matsbara, Hideaki
    • Ceramist
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    • v.9 no.6
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    • pp.24-29
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    • 2006
  • Electron beam physical vapor deposition (EB-PVD) process has currently been applied to thermal barrier coatings (TBCs) for aircraft engines. Due to unique columnar structure, EB-PVD TBCs have advantages in resistances to thermal shock and thermal cycle for their applications, compared to films prepared by plasma spray By the EB-PVD equipment, we successfully obtained yttria-stabilized zirconia (YSZ) layer which has columnar and feather like structure including a large amount of nano size pores and gaps. The EB-PVD technique has been developed for coating functional perovskite type oxides such as (La, Sr)MnO3. Electrode properties have been improved by interface and structural control.

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Uniform Coating of Organic-Capped Ba-Ti-O Nanolayers on Spherical Ni Particles

  • Lee, Yong-Kyun;Choi, Jae-Young;Yoon, Seon-Mi;Lee, Jong-Heun
    • Korean Journal of Materials Research
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    • v.17 no.2
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    • pp.86-90
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    • 2007
  • The organic-capped Ba-Ti-O nanolayers were coated uniformly on spherical Ni particles for multilayer ceramic capacitor (MLCC) applications via the formation of Ti-hydroxide nano-coating layers and their subsequent reaction with Ba-stearate at $180^{\circ}C$. The capping of organic shell on oxide coating layer changed the hydrophilic surface structure into hydrophobic one, which significantly improved the dispersion behavior in hydrophobic solvents such as terpineol and butanol. In addition, the uniform coating of Ba-Ti-O layer was advantageous to prevent Ni oxidation. This method provides a useful chemical route to fabricate organic-soluble Ba-Ti-O coated Ni particles for a highly integrated passive component.

Tribological Behavior of Thermally Sprayed Nano Composite Chromium Carbide (크로뮴 카바이드 나노 분말을 이용한 용사코팅 층의 내마모 특성에 관한 연구)

  • 이정엽;신종한;임대순;안효석
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.06a
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    • pp.42-48
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    • 2001
  • Chromium carbides have the excellent wear properties as transition metal carbides. Their tribological applications were studied recently. The nano-sized ceramic could enhance the mechanical and electronical properties of materials. In this study, it was observed to test the wear of the coated surface of nano-sized chromium carbides. The nano-sized chromium carbides were produced by sol-gel processing. Coating surface of produced powders was obtained front plasma spraying. Wear test of coating surface was held increasing temperature. The friction coefficient and the wear loss were testified in dry environment. And the worn surfaces were analyzed by XRD and SEM.

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