• Title/Summary/Keyword: cement-based materials

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Effect of Curing Period on Photocatalytic Effect of TiO2 Nanotubes-reinforced Cement Paste (양생기간이 TiO2 나노튜브 보강 시멘트 페이스트의 광촉매 효과에 미치는 영향)

  • Liu, Jun-Xing;Jin, Da-hyung;Bae, Sung-chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.172-173
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    • 2021
  • With the development of nano-reinforcement technology and the increasing concern for environmental issues, TiO2 nanomaterials have received wide attention as an additive besides carbon nanomaterials that can be used to enhance the mechanical properties of cement-based materials. Also, TiO2-based materials can allow cement-baned materials with photocatalytic capability, providing a potentially effective approach to reduce environmental problems. In this work, compressive strength, splitting tensile strength, and degradation of methylene blue solution were used as target to assess the effect of TiO2 nanotubes on the mechanical strength and photocatalytic effect of hardened cement paste at different curing time. According to the strength results, the optimum amount of TiO2 was identified as 0.5% of the weight of cement. Meanwhile, the TiO2 nanotubes-reinforced specimen exhibited better photocatalytic effect in the early stage of curing.

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Predicting Compressive Strength of Fly Ash Mortar Considering Fly Ash Fineness (플라이 애시 미세도를 고려한 플라이 애시 모르타르의 압축 강도 예측)

  • Sun, Yang;Lee, Han-seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.90-91
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    • 2020
  • Utilization of upgraded fine fly ash in cement-based materials has been proved by many researchers as an effective method to improve compressive strength of cement based materials at early ages. The addition of fine fly ash has introduced dilution effect, enhanced pozzolanic reaction effect, nucleation effect and physical filling effect into cement-fly ash system. In this study, an integrated reaction model is adpoted to quantify the contributions from cement hydration and pozzolanic reaction to compressive strength. A modified model related to the physical filling effect is utilized to calculate the compressive strength increment considering the gradual dissolution of fly ash particles. Via combination of these two parts, a numerical model has been proposed to predict the compressive strength development of fine fly ash mortar considering fly ash fineness. The reliability of the model is validated through good agreement with the experimental results from previous articles.

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Thermal Insulation and Flame Retardant Properties of Cement Based Super Light-weight Inorganic Thermal Insulation using 100㎛ Grade Glass Bubble (100㎛급 글라스 버블 혼입 시멘트계 초경량 무기 단열재의 단열 및 난연특성)

  • Son, Bae-Geun;Song, Hun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.642-649
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    • 2021
  • Energy saving standard for buildings are strengthened, the application of exterior insulation finishing system and thickness of insulation materials are increasing. Most buildings with exterior insulation finishing system is applied organic insulating material. Organic insulating material have workability, economic feasibility, reduction in construction cost, and excellent thermal insulation performance. However, Organic insulating material is very vulnerable to heat, so when a fire occurs, rapid fire spread and toxic gas are generated, causing many casualties. Inorganic insulating material can be non-combustible performance, but it is heavy and has low thermal insulation performance. Mineral wool has higher thermal insulation performance than other types of inorganic insulating material, but mineral wool is disadvantageous to workability and vulnerable to moisture. Glass bubble are highly resistant to water and chemically stable substances. In addition, the density of the glass bubble is very low and the particles are spherical, fluidity is improved by the ball bearing effect. Glass bubbles can be used with cement-based ino rganic insulating material to impro ve the weight and thermal insulatio n perfo rmance o f cement-based inorganic insulation. This study produced a inorganic insulating materials were manufactured using cement-based materials and glass bubble. In order to evaluate the insulation performance and flame retardant performance of cement-based super light-weight inorganic insulating materials using with glass bubble, insulation performance or flame retardant and non-combustible performance were evaluated after manufacturing insulating materials using micro cement and two types of glass bubbles. From the test result, Increasing the mixing ratio of glass bubbles improved the insulation performance of cement-based super light-weight inorganic insulating materials, and when the mixing ratio of glass bubbles was 10%, it sho wed sufficient flame retardant and no n-co mbustible perfo rmance.

Physical Properties Variation of Grout Materials Based on the Water to Cement Ratio and the Mixing Speed (물시멘트비 및 혼합속도에 따른 주입재의 물성변화 연구)

  • Chun, Byung-Sik;Kim, Jin-Chun;Jang, Bui-Woong;Lee, Jun-Woo
    • Journal of the Korean GEO-environmental Society
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    • v.1 no.1
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    • pp.87-96
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    • 2000
  • Generally, OPC(ordinary portland cement) is used for grouting in Korea, and bentonite has usually been added to prevent the deposition of cement particles. The dispersion of CB(cement bentonite) grout is influenced by variable factors i.e. water to cement ratio, particle size of cement, kind of bentonite, adding volume, method of adding, viscosity of CB grout materials and curdling time. Among variable factors, the viscosity of CB grout materials is influenced by the dispersion, and dispersion is improved as the speed of grout mixer increase. In this paper, the specification of construction was derived by estimating physical characteristics of CB grout materials and confirming the sate of dispersion. The results show that the engineering characteristics of CB grout materials vary with the water to cement ratio and the mixing speed.

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Manufacturing Properties and Hardening Characteristic of CO2 Reactive Hardening Cement (이산화탄소 반응경화 시멘트 제조 및 경화특성 연구)

  • Ki-Yeon Moon;Byung-Ryeol Kim;Seung-Han Lee;Moon-Kwan Choi;Kye-Hong Cho;Jin-Sang Cho
    • Resources Recycling
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    • v.31 no.6
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    • pp.52-59
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    • 2022
  • Calcium silicate based cement (CSC) is a low-carbon cement that emits less CO2 by up to 70% compared to ordinary Portland cement during its manufacture. Most developed countries have commercialized CSC, whereas Korea is still investigating the manufacturing characteristics and basic properties of CSC. This paper provides a review of methods for manufacturing CSC using domestic raw materials and discusses the possibility of CSC localization based on an evaluation of the basic physical properties of manufactured CSC. The experimental results of this study indicate that the primary mineral components of CSC were CS, C3S2 C2S, and unreacted SiO2. This suggests the possibility of manufacturing CSC using domestic raw materials that exhibit mineral compositions similar to that of theoretical CSC. The compressive strength of CSC mortar is less than 1MPa at the age of 7 d under wet curing. This implies that hydration does not affect the property development of CSC mortar. Meanwhile, during carbonation curing, the compressive strength is 56 MPa or higher after 7 d, which indicates excellent early strength development. Furthermore, results of Thermogravimetric Analysis Differential scanning calorimetry (TG/DSC) show that a significant amount of CaCO3 is formed, which is consistent with the results of previous studies. This implies that carbonation is associated significantly with the properties of CSC.

Mechanical Properties of Hydrated Cement Paste: Development of Structure-property Relationships

  • Ghebrab, Tewodros T.;Soroushian, Parviz
    • International Journal of Concrete Structures and Materials
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    • v.4 no.1
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    • pp.37-43
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    • 2010
  • Theoretical models based on modern interpretations of the morphology and interactions of cement hydration products are developed for prediction of the mechanical properties of hydrated cement paste (hcp). The models are based on the emerging nanostructural vision of calcium silicate hydrate (C-S-H) morphology, and account for the intermolecular interactions between nano-scale calcium C-S-H particles. The models also incorporate the effects of capillary porosity and microcracking within hydrated cement paste. The intrinsic modulus of elasticity and tensile strength of hydrated cement paste are determined based on intermolecular interactions between C-S-H nano-particles. Modeling of fracture toughness indicates that frictional pull-out of the micro-scale calcium hydroxide (CH) platelets makes major contributions to the fracture energy of hcp. A tensile strength model was developed for hcp based on the linear elastic fracture mechanics theories. The predicted theoretical models are in reasonable agreements with empirical models developed based on the experimental performance of hcp.

Experimental study on nano silica modified cement base grouting reinforcement materials

  • Zhou, Fei;Sun, Wenbin;Shao, Jianli;Kong, Lingjun;Geng, Xueyu
    • Geomechanics and Engineering
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    • v.20 no.1
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    • pp.67-73
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    • 2020
  • With the increasing number of underground projects, the problem of rock-water coupling catastrophe has increasingly become the focus of safety. Grouting reinforcement is gradually applied in subway, tunnel, bridge reinforcement, coal mine floor and other construction projects. At present, cement-based grouting materials are easy to shrink and have low strength after solidification. In order to overcome the special problems of high water pressure and high in-situ stress in deep part and improve the reinforcement effect. In view of the mining conditions of deep surrounding rock, a new type of cement-based reinforcement material was developed. We analyses the principle and main indexes of floor strengthening, and tests and optimizes the indexes and proportions of the two materials through laboratory tests. Then, observes and compares the microstructures of the optimized floor strengthening materials with those of the traditional strengthening materials through scanning electron microscopy. The test results show that 42.5 Portland cement-based grouting reinforcement material has the advantages of slight expansion, anti-dry-shrinkage, high compressive strength and high density when the water-cement ratio is 0.4, the content of bentonite is 4%, and the content of Nano Silica is 2.5%. The reinforcement effect is better than other traditional grouting reinforcement materials.

Characterization of Shrinkage Reducing Type Cement Carbon Dioxide-reducible CSA Synthesis (이산화탄소 저감형 CSA합성을 통한 수축저감형 시멘트의 특성 평가)

  • Cho, Yong-Kwang;Nam, Seong-Young;Kim, Chun-Sik;Cho, Sung-Hyun;Lee, Hyoung-Woo;Ahn, Ji-Whan
    • Journal of Energy Engineering
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    • v.28 no.1
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    • pp.17-21
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    • 2019
  • Calcium sulfaluminate (CSA) was synthesized to improve the shrinkage of OPC. In this study, the setting time, the compressive strength and the length change ratio were confirmed by replacing the synthesized CSA with OPC by 10% and 13% by 16%. In the case of shrinkage-reducing type cement, formation of Ca-Al-$H_2$-based hydrate was activated. Therefore, the setting time was shortened. The compressive strength of the shrinkage - reducing type cement is comparable to that of OPC after 7 days' strength. However, shrinkage reducing type cement showed improved initial strength compared to OPC. The length change ratio was found to be improved by drying shrinkage from -0.075% to -0.047% on the 28th day.

An Experimental Study on the Gloss of Cement Matrix by Formwork Materials (거푸집 재료에 따른 시멘트경화체의 광택도에 관한 실험적 연구)

  • Kim, Hyeon-Sung;Jung, Yoong-Hoon;Park, Sun-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.118-119
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    • 2019
  • The exterior finish not only has a relationship to the functionality of building, but also the spatial aesthetics and visual perception. Common exterior finishes are wood, stone or acrylic based and etc. However, these finishes have different attributes which can alter the quality of the architecture, such as durability, moisture and fire resistance. To make up for the short-comings of these materials, we have used iron based resources for optimization. However, iron materials are expensive, so they have limitations in general use. In this study, we have experimented with various forms of exterior finishes using cement, which is the most efficient and widely used building material with several economic advantages. We experimented with different materials to use as the formwork for the gloss of the cement matrix. As a result, the gloss show that order of urethane, steel, and wood material.

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Numerical analysis of crack propagation in cement PMMA: application of SED approach

  • Ali, Benouis;Abdelkader, Boulenouar;Noureddine, Benseddiq;Boualem, Serier
    • Structural Engineering and Mechanics
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    • v.55 no.1
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    • pp.93-109
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    • 2015
  • Finite element analysis (FEA) combined with the concepts of linear elastic fracture mechanics (LEFM) provides a practical and convenient means to study the fracture and crack growth of materials. In this paper, a numerical modeling of crack propagation in the cement mantle of the reconstructed acetabulum is presented. This work is based on the implementation of the displacement extrapolation method (DEM) and the strain energy density (SED) theory in a finite element code. At each crack increment length, the kinking angle is evaluated as a function of stress intensity factors (SIFs). In this paper, we analyzed the mechanical behavior of cracks initiated in the cement mantle by evaluating the SIFs. The effect of the defect on the crack propagation path was highlighted.