• 제목/요약/키워드: cement-based materials

검색결과 584건 처리시간 0.024초

SWCNT 분산용액을 혼입한 시멘트 페이스트의 휨강도 및 미세구조 (Bending Strength and Microstructure of Cement Paste Containing SWCNT Dispersion Solution)

  • 최익제;김지현;이수용;정철우
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 추계 학술논문 발표대회
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    • pp.149-150
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    • 2017
  • It is known that physical and chemical changes of cement hydrates cause problems in the volume stability of concrete. In order to overcome these problems, there is a growing interest in research on mixing technology of cement-based materials and nanomaterials. Among the nanomaterials, carbon nanotubes (CNTs) are attracting attention due to their excellent mechanical properties. The CNTs are made of cylindrically shaped graphene sheets. According to the number of sheets, single-walled carbon nanotubes (SWCNTs) and multi-walled carbon nanotubes (MWCNTs) are classified. Although the SWCNT has superior mechanical properties, the research using MWCNT is vigorous due to the difficulty of marketability and manufacturing, but the research using SWCNT is insufficient. In this study, we investigate the effect of SWCNT on the formation of hydrate of cement paste by observing the microstructure of broken cement paste after measuring the flexural strength of cement paste with SWCNT dispersion.

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Theoretical prediction on thickness distribution of cement paste among neighboring aggregates in concrete

  • Chen, Huisu;Sluys, Lambertus Johannes;Stroeven, Piet;Sun, Wei
    • Computers and Concrete
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    • 제8권2호
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    • pp.163-176
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    • 2011
  • By virtue of chord-length density function from the field of statistical physics, this paper introduced a quantitative approach to estimate the distribution of cement paste thickness between aggregates in concrete. Dynamics mixing method based on molecular dynamics was employed to generate one model structure, then image analysis algorithm was used to obtain the distribution of thickness of cement paste in model structure for the purpose of verification. By comparison of probability density curves and cumulative probability curves of the cement paste thickness among neighboring aggregates, it is found that the theoretical results are consistent with the simulation. Furthermore, for the model mortar and concrete mixtures with practical volume fraction of Fuller-type aggregate, this analytical formula was employed to predict the influence of aggregate volume fraction and aggregate fineness. And evolution of its mean values were also investigated with the variation of volume fraction of aggregate as well as the fineness of aggregates in model mortars and concretes.

섬유혼입조건 및 팽창재 대체에 따른 변형 경화형 시멘트 복합체 내의 철근 겹침이음 성능 (Effects of Fiber Blending Condition and Expansive Admixture Replacement on Tensile Performance of Rebar Lap Splice in Strain-Hardening Cement-Based Composites (SHCCs))

  • 류승현;이영오;윤현도
    • 콘크리트학회논문집
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    • 제24권2호
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    • pp.111-120
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    • 2012
  • 이 연구는 섬유 보강 시멘트 복합체(SHCC) 내에 매립된 철근의 겹침이음 성능을 평가하고자 하였으며, 이에 따라 단조 및 반복 재하시의 겹침이음된 철근의 인장 실험을 실시하였다. 총 10개의 SHCC 및 콘크리트 배합이 계획되었으며, 실험체의 변수는 보강섬유 종류(폴리에틸렌 및 강섬유), 팽창재 대체율(0% 및 10%) 및 실험체의 설계강도(30 MPa 및 100 MPa)로 계획하였다. SHCC 및 콘크리트 배합에 매립된 철근의 겹침이음 길이는 각각 콘크리트 구조설계 기준에 의거하여 산정된 겹침이음 길이의 60% 및 100%를 적용하였다. 실험 결과 SHCC에 철근이 매립될 경우 철근의 겹침이 음 성능을 향상시키는 것으로 나타났으며, SHCC 배합에서 보강 섬유 종류(PE-SHCC 및 PESF-SHCC)에 관계없이 겹침 이음된 철근의 인장강도 및 부착강도 증진에 기여하는 것으로 나타났다. 또한 SHCC에 팽창재를 대체할 경우 SHCC에 매립된 철근 겹침이음부의 거동 특성을 개선하는 특징을 보였다. 한편 균열 특성에서는 배합조건 및 재료특성에 따라 PE-SHCC가 PESF-SHCC에 비해 보다 많은 미세균열 특성을 나타내었다. 전언한 바와 같이 이 연구는 SHCC의 변형경화 특성에 따라 매립된 철근과의 상호작용을 증진시킴에 따라, SHCC에 매립된 철근 겹침이음 길이를 감소할 경우에도 양호한 거동 특성을 보이는 것으로 판단된다.

Characterizations of High Early-Strength Type Shrinkage Reducing Cement and Calcium Sulfo-aluminate by Using Industrial Wastes

  • Lee, Keon-Ho;Nam, Seong-Young;Min, Seung-Eui;Lee, Hyoung-Woo;Han, Choon;Ahn, Ji-Whan
    • 한국세라믹학회지
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    • 제53권2호
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    • pp.215-221
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    • 2016
  • In this study, the utilization of the by-products of various industries was examined using raw materials of CSA high-functional cement such as coal bottom ash, red mud, phosphate gypsum, etc. Technology to improve energy efficiency and reduce $CO_2$ was developed as part of the manufacturing process; this technology included lower temperature sintering ($150{\sim}200^{\circ}C$) than is used in the OPC cement manufacturing process, replacement of CSA cement with the main raw material bauxite, and a determination of the optimum mix condition. In order to develop CSA cement, a manufacturing system was established in the Danyang plant of the HANIL Cement Co. Ltd., in Korea. About 4,200 tons of low purity expansion agent CSA cement (about 16%) and about 850 tons of the lime-based expansion agent dead burned lime (about 8%) were produced at a rate of 60 tons per hour at the HANIL Cement rotary kiln. To improve the OPC cement properties, samples of 10%, 13%, and 16% of CSA cement were mixed with the OPC cement and the compressive strength and length variation rate of the green cement were examined. When green cement was mixed with each ratio of CSA cement and OPC cement, the compressive strength was improved by about 30% and the expansibility of the green cement was also improved. When green cement was mixed with 16% of CSA cement, the compressive strength was excellent compared with that of OPC cement. Therefore, this study indicates the possibility of a practical use of low-cost CSA cement employing industrial wastes only.

Mechanical properties of blended cements at elevated temperatures predicted using a fuzzy logic model

  • Beycioglu, Ahmet;Gultekin, Adil;Aruntas, Huseyin Yilmaz;Gencel, Osman;Dobiszewska, Magdalena;Brostow, Witold
    • Computers and Concrete
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    • 제20권2호
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    • pp.247-255
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    • 2017
  • This study aimed to develop a Rule Based Mamdani Type Fuzzy Logic (RBMFL) model to predict the flexural strengths and compressive strengths of blended cements under elevated temperatures. Clinoptilolite was used as cement substitution material in the experimental stage. Substitution ratios in the cement mortar mix designs were selected as 0% (reference), 5%, 10%, 15% and 20%. The data used in the modeling process were obtained experimentally, after mortar specimens having reached the age of 90 days and exposed to $300^{\circ}C$, $400^{\circ}C$, $500^{\circ}C$ temperatures for 3 hours. In the RBMFL model, temperature ($C^{\circ}$) and substitution ratio of clinoptilolite (%) were inputs while the compressive strengths and flexural strengths of mortars were outputs. Results were compared by using some statistical methods. Statistical comparison results showed that rule based Mamdani type fuzzy logic can be an alternative approach for the evaluation of the mechanical properties of concrete under elevated temperature.

Effect of cement type, luting protocol, and ceramic abutment material on the shade of cemented titanium-based lithium disilicate crowns and surrounding peri-implant soft tissue: a spectrophotometric analysis

  • Peter Gehrke;Maria Julia Pietruska;Johannes Ladewig;Carsten Fischer;Robert Sader;Paul Weigl
    • The Journal of Advanced Prosthodontics
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    • 제16권4호
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    • pp.231-243
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    • 2024
  • PURPOSE. The objective of the study was to analyze the impact of cement, bonding pretreatment, and ceramic abutment material on the overall color results of CAD-CAM ceramic crowns bonded to titanium-based hybrid abutments. MATERIALS AND METHODS. For single implant restoration of a maxillary lateral incisor a total of 51 CAD-CAM-fabricated monolithic lithium disilicate crowns were fabricated and subsequently bonded onto 24 lithium disilicate Ti-base abutments, 24 zirconia Ti-base abutments and 3 resin abutment replicas as a control group. The 48 copings were cemented with three definitive and one provisional cement on both grit-blasted and non-blasted Ti-bases. The color of each restoration and surrounding artificial gingiva was measured spectrophotometrically at predefined measuring points and the CIELAB (ΔEab) color scale values were recorded. RESULTS. The color outcome of ceramic crowns bonded to hybrid abutments and soft tissues was affected differently by cements of different brands. Grit-blasting of Ti-bases prior to cementing CAD-CAM copings affected the color results of allceramic crowns. There was a significant difference (P = .038) for the median ΔE value between blasted and non-blasted reconstructions at the cervical aspect of the crown. Full-ceramic crowns on zirconia Ti-base abutments exhibited significantly lower ΔE values below the threshold of visibility (ΔE 1.8). In all subcategories tested, the use of a highly opaque temporary cement demonstrated the lowest median ΔE for both the crown and the artificial gingiva. CONCLUSION. Various cements, core ceramic materials and airborne particle abrasion prior to bonding can adversely affect the color of Ti-base supported ceramic crowns and peri-implant soft tissue. However, zirconia CAD-CAM copings and an opaque cement can effectively mask this darkening.

폐목질을 사용한 시멘트보드의 기초적 특성에 관한 실험적 연구 (An Experimental Study on the Basic Properties of Cement Boards of Waste Wood)

  • 황병준;김광기;박희곤;강태경;백민수;정상진
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2004년도 학술.기술논문발표회
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    • pp.57-60
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    • 2004
  • Recently. as the alternatives to preserve environment such as effective usage of wastes or unusable resources are drawing attentions, researches and measures for the two tasks, which are reuse of waste wood and development of eco-friendly materials, are being examined and established in various fields. However, they are still insufficient. Therefore, in this study, for the efficient application of waste woods and eco-friendly effects, mortar was produced using sawdust af the waste wood and mineral material cement for combination, in order to produce inorganic boards using waste woods, which were made when sawing. The present study purposed to analyze the physical and dynamic characteristics of woody cement boards, which were made by modifying water-cement ratio for each wood inclusion rate based on a hardening-accelerator inclusion rate set in previous studies and, based on the findings. to provide basic data about the physical properties of inorganic boards made of waste wood, in order to Produce woody cement boards using waste wood, which has problems in being used in the manufacturing of woody cement boards.

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콘크리트 포장의 급속 보수를 위한 산화마그네슘계열 단면복구재의 성능에 대한 실험적 연구 (Experimental Study on Performance of MgO-based Patching Materials for Rapid Repair of Concrete Pavement)

  • 이현기;안기용;심종성
    • 한국도로학회논문집
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    • 제18권1호
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    • pp.43-55
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    • 2016
  • PURPOSES : This study aims to develop a repair material that can enhance pavement performance, inducing rapid traffic opening through early strength development and fast setting time by utilizing MgO-based patching materials for repairing road pavements. METHODS : To consider the applicability of MgO-based patching materials for repairing domestic road pavements, first, strength development and setting time of the materials were evaluated, based on MgO to $KH_2PO_4$ ratio, water to binder ratio, and addition ratio of retarder (Borax), by which the optimal mixture ratio of the developed material was obtained. To validate the performance of the developed material as a repair material, the strength(compressive strength and bonding strength) and durability (freezing, thawing, and chloride ion penetration resistance) was checked through testing, and its applicability was evaluated. RESULTS : The results showed that when an MgO-based patching material was used, the condensation time was reduced by 80%, and the compressive strength was enhanced by approximately 300%, as compared to existing cement-based repair materials. In addition, it was observed that the strength (compressive strength and bonding strength) and durability (freezing and thawing, and chloride ion penetration resistance) showed an excellent performance that satisfied the regulations. CONCLUSIONS : The results imply that an emergent repair/restoration could be covered by a rapid-hardening cement to meet the traffic limitation (i.e. the traffic restriction is only several hours for repair treatment). Furthermore, MgO-based patching materials can improve bonding strength and durability compared to existing repair materials.

시멘트계 주입재의 주입특성에 관한 연구 (A Study on the Properties of Grout Materials Based on Cement Type)

  • 천병식;최중근
    • 한국지반공학회논문집
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    • 제18권5호
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    • pp.229-236
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    • 2002
  • 본 논문은 실용화된 지반개량용 마이크로시멘트 및 보통포틀랜드시멘트의 주입특성에 관한 연구로서 기초물성, 고결율, 침투성과 같이 실험적으로 주입재의 입도와 다짐정도를 조정하고, 주입대상 토사지반의 투수계수를 3종류로 변화시컥 약액주입의 주요 특성을 검토한 것이다. 주입재의 적용성을 평가하기 위하여 고결성 시험 및 침투성 시험을 실시한 결과, 모형토사지반의 상대밀도에 따른 투수계수를 $10^{-4}$~$10^{-2}$cm/sec로 변화시킨 경우, 마이크로시멘트는 투수 계수 $10^{-4}$cm/sec에서 유효고결율 75%, 침투주입율 86%로서 침투성 및 고결성이 우수한 결과를 나타낸 반면, OPC는 $10^{-2}$cm/sec에서 유효고결율 및 침투주입율이 50% 미만으로서 원활한 침투주입이 될 수 없음을 알 수 있었다. 댐 기초 지반 및 연약지반의 보강을 위해 주입재의 침투성이 요구되는 경우에는 마이크로시멘트가 적용성이 매우 우수한 것으로 판단된다. 동수지중 모형시험 결과 유속이 상대적으로 느린 경우 주입압이 높을수록, 완결형 주입재가 고결효과가 우수한 반면, 유속이 빠른 경우에는 완결형의 경우 주입재의 대부분이 외부로 유출되는 등 유효고결율이 매우 낮아 고결효과가 불량함을 알 수 있었다.

도금공장 유해폐기물의 고형화에 관한 연구 (Solidification of Hazardous Wastes from Electroplating Industry)

  • 신항식;허남룡;구자공
    • 대한토목학회논문집
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    • 제8권2호
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    • pp.89-98
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    • 1988
  • 본 연구는 도금공장에서 생산된 슬러지를 시멘트 고형화방법을 이용하여 처리할 때 고형화에 영향을 미치는 인자들 중에 모래/시멘트 비, 물시멘트 비, 젖은 슬러지의 양, 그리고 중금속 용출방지제를 네가지의 인자로 하여 압축강도와 용출량의 변화를 살펴 보았다. 모래/시멘트 비는 Cr(VI) 용출에 가장 큰 영향을 미치는 인자이며, 물/시멘트 비는 Zn와 압축강도에 가장 큰 영향을 미치는 인자였다. Cr(VI)는 Zn보다 시멘트 고형화에서 leachability가 더 적었다. 현장에서의 Cr(VI)과 Zn 그리고 압축강도를 예측하기 위한 모델을 계발하였으며, 고체화의 3급 Brick으로의 이용을 위해 혼합조건을 제시하였다. 그리고 30g의 건조슬러지를 고형화할 때 최적조건은 모래/시멘트 비, 물/시멘트 비, 그리고 중금속 용출방지제의 양은 각각 1, 1.5, 1.075g이었다.

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