• Title/Summary/Keyword: cement matrix

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Loss of strength in asbestos-cement water pipes due to leaching

  • Gil, Lluis;Perez, Marco A.;Bernat, Ernest;Cruz, Juan J.
    • Structural Engineering and Mechanics
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    • v.40 no.5
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    • pp.655-663
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    • 2011
  • Asbestos-cement is a material with valuable strength and durability. It was extensively used for water distribution pipes across the world from the 1950s until the early 1980s. The network of pipes in this case study dates from the 1970s, and after more than 30 to 40 years of service, some pipes have been found to break under common service pressure with no apparent reason. A set of mechanical tests was performed including bending, compression, pressure and crushing tests. Microscopy analysis was also used to understand the material behaviour. Tests showed that there was a clear loss of strength in the pipes and that the safety factor was under the established threshold in most of the specimens. Microscopy results showed morphological damage to the pipes. The loss of strength was attributed to a leaching effect. Leaching damages the cement matrix and reduces the frictional interfacial shear stress.

Durability of Polymer-Modified Mortars Using Acrylic Latexes with Methyl Methacrylate (MMA계 아크릴 라텍스를 혼입한 폴리머시멘트 모르타르의 내구성)

  • Hyung Won-Gil;Kim Wan-Ki;Soh Yang-Seob
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.411-418
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    • 2005
  • Polymer-modified mortar and concrete are prepared by mixing either a polymer or monomer in a dispersed, or liquid form with fresh cement mortar and concrete mixtures, and subsequently curing, and if necessary, the monomer contained in the mortar or concrete is polymerized in situ. Although polymers and monomers in any form such as latexes, water-soluble polymers, liquid resins, and monomers are used in cement composites such as mortar and concrete, it is very important that both cement hydration and polymer phase formation proceed well the yield a monolithic matrix phase with a network structure in which the hydrated cement phase and polymer phase interpenetrate. In the polymer-modified mortar and concrete structures, aggregates are bound by such a co-matrix phase, resulting in the superior properties of polymer-modified mortar and concrete compared to conventional mortar and concrete. The purpose of this study is to obtain the necessary basic data to develope appropriate latexes as cement modifiers, and to clarify the effects of the monomer ratios and amount of emulsifier on the properties of the polymer-modified mortars using methyl methacrylate-butyl acrylate(MMA/BA) and methyl methacrylate-ethyl acrylate(MMA/EA) latexes. The results of this study are as follows, the water absorption, chloride ion penetration depth and carbonation depth of MMA/BA-modified mortar are lowest. However, they are greatly affected by the polymer-cement ratio rather than the bound MMA content and type of polymer.

Optimal Mixture Proportion for High Performance Concrete Incorporating Ground Granulated Blast furnace Slag

  • Choi Jae-Jin;Kim Eun-Kyum;Yoo Jung-Hoon
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.473-480
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    • 2005
  • In this study, a mix design for self compacting concrete was based on Okamura's method and concrete incorporated just a ground granulated blast furnace slag. Replacement ratio of slag is in the range of $20-80\%$ of cement matrix by volume. For the optimal self compactability in mixture incorporating ground granulated blast furnace slag, the paste and mortar tests were first completed. Then the slump flow, elapsed time of 500mm slump flow, V funnel time and filling height by U type box were conducted in concrete. The volume of coarse aggregate in self compacting concrete was in the range of $50-60\%$ to the solid volume percentage of coarse aggregate. Finally, the compressive and splitting tensile strengths were determined in the hardened self compacting concrete incorporating ground granulated blast furnace slag. From the test results, it is desirable for self compacting concrete that the replacement of ground granulated blast furnace slag is in the range of $40-60\%$ of cement matrix by volume and the volume of coarse aggregate to the solid volume percentage of coarse aggregate with a limit of $55\%$.

Cementing Efficiency of Fly-ash in Mortar Matrix According to Binder-Water Ratio and Fly-ash Replacement Ratio

  • Cho, Hong-Bum;Jee, Nam-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.2
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    • pp.194-202
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    • 2012
  • This paper predicts the cementing efficiency of fly-ash(FA) based on mortar test considering binder-water ratio and FA replacement ratio as experimental variables. The cementing efficiency prediction model proposed by statistical analysis enables us to estimate the value according to the binder-water ratio and FA replacement ratio of matrix. When FA replacement ratio is the same, the lower the binder-water ratio, the higher the estimated cementing efficiency. There are significant differences in the values according to binder-water ratio at FA replacement ratios of 15% or less, but there are almost no differences when FA replacement ratio is more than 15%. As the binder-water ratio increases, the variations in the values according to FA replacement ratio are great at FA replacement ratios of 15% or less. As the FA replacement ratios increase, the values increase for FA replacement ratios of 15% or less, but decrease for more than 15%. The values range from -0.71 to 1.24 at binder-water ratio of 1.67-2.86 and FA replacement ratio of 0-70%. The RMSE of the 28-day compressive strength predicted by modified water-cement ratio is 2.2 MPa. The values can be trusted, as there is good agreement between predicted strength and experimental strength.

Cleaner Production Management using Evaluation Method of Environmental Impact of ISO14001 (ISO14001 환경영향평가방법을 이용한 청정공정관리 - Tourah Portland Cement회사를 중심으로 -)

  • Park, Young G.
    • Clean Technology
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    • v.5 no.2
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    • pp.13-23
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    • 1999
  • The unique method for evaluating the environmental impact, which is restricted to use in BS7750, was performed to determine the priority for reducing environmental loads in the cement process. Mass balance in the unit process was achieved, it was utilized to introduce the matrix method which are composed of two different evaluation's criteria by occurrence possibility and by occurrence results. The purpose of this paper is first to explain the matrix method in the practical plant and secondly to show the successful examples of enviromental improvement. Conclusively, the seriousness of environmental impact could be quantified in several different unit processes and suggested some progressive results obtained after process improvement.

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Density and Strength Properties of according to the Gypsum replacement of Lightweight Matrix based on Blast Furnace Slag (고로슬래그 기반 석고를 사용한 경량 경화체의 밀도 및 강도 특성)

  • Kim, Weon-Jeong;Lee, Seung-Ho;Park, Sun-Gyu;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.169-170
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    • 2015
  • This study is the experiment for manufacturing the Lightweight non-cement matrix based on the blast furnace slag, paper ash. Materials like cement and blowing agent in foamed concrete is replaced by by-products fro blast furnace slag and paper ash. Further, the experiment was performed by replacing alkali with nature gypsum and α type gypsum by (0, 5, 10, 15, 20) of weight of alkali (wt.%) in order to reduce the amount of expensive alkali-activator. Consequently, in the case of the density, plain showed the lowest density and it seems that specimen adding nature gypsum 5% has the best compressive strength and flexural strength. It is detemined that the strength is lowered in accordance with the α type gypsum replacement ratio is higher. The research that it can supplement the further intensity seems to be needed.

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Compressive Strength Properties Surface Coating Lightweight Aggregate ITZ using Inorganic Materials (무기 재료를 이용한 표면코팅 경량골재 계면 압축강도 특성)

  • Kim, Ho-Jin;Jeong, Su-Mi;Pyeon, Myeong-Jang;Kim, Ju-Sung;Park, Sun-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.109-110
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    • 2022
  • Recently, it tend to increase the high-rise and large-scale of buildings and the developtment of construction technology can to be applied reinforced concrete structures to high-rise buildings. However, when a high-rise buildings is constructed with reinforced concrete, it has a disadvantage that buildings weight increases. In order to resolve the weight of reinforced concrete structures, various types of lightweight aggregates become development and research. Although lightweight aggregates can be reduced the weight of concrete, the strength of ITZ(Interfacial Transition Zone) is lowered due to its less strength than natural aggregates. In this study, an experimental study was conducted to coat the surface of lightweight aggregates with GGBFS(ground granulated blast furnace slag) to improve the strength of cement matrix mixed with lightweight aggregates. Result of this experimental study shows that the compressive strnegth of the surface coating lightweight aggregates was higher than general lightweight aggregates. Also, it was considered that this is because the pore at the ITZ of the surface-coated lightweight aggregates mixed cement matrix are filled with GGBFS fine particle.

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In vivo wear determination of novel CAD/CAM ceramic crowns by using 3D alignment

  • Aladag, Akin;Oguz, Didem;Comlekoglu, Muharrem Erhan;Akan, Ender
    • The Journal of Advanced Prosthodontics
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    • v.11 no.2
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    • pp.120-127
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    • 2019
  • PURPOSE. To determine wear amount of single molar crowns, made from four different restoratives, and opposing natural teeth through computerized fabrication techniques using 3D image alignment. MATERIALS AND METHODS. A total of 24 single crowns (N = 24 patients, age range: 18 - 50) were made from lithium disilicate (IPS E-max CAD), lithium silicate and zirconia based (Vita Suprinity CAD), resin matrix ceramic material (Cerasmart, GC), and dual matrix (Vita Enamic CAD) blocks. After digital impressions (Cerec 3D Bluecam, DentsplySirona), the crowns were designed and manufactured (Cerec 3, DentsplySirona). A dualcuring resin cement was used for cementation (Variolink Esthetic DC, Ivoclar). Then, measurement and recording of crowns and the opposing enamel surfaces with the intraoral scanner were made as well as at the third and sixth month follow-ups. All measurements were superimposed with a software (David-Laserscanner, V3.10.4). Volume loss due to wear was calculated from baseline to follow-up periods with Siemens Unigraphics NX 10 software. Statistical analysis was accomplished by Repeated Measures for ANOVA (SPSS 21) at = .05 significance level. RESULTS. After 6 months, insignificant differences of the glass matrix and resin matrix materials for restoration/enamel wear were observed (P>.05). While there were no significant differences between the glass matrix groups (P>.05), significant differences between the resin matrix group materials (P<.05) were obtained. Although Cerasmart and Enamic were both resin matrix based, they exhibited different wear characteristics. CONCLUSION. Glass matrix materials showed less wear both on their own and opposing enamel surfaces than resin matrix ceramic materials.

Binding of the Hexavalent Chromium Ions in the Process of Cement Hydration (시멘트 수화에 따른 6가 크롬의 고정화 특성)

  • Jung, Min-Sun;Hwang, Jun-Pil;Hong, Sung-In;Ann, Ki-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.6
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    • pp.88-94
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    • 2013
  • The hexavalent chromium (Cr(VI)) is well known as a hazardous ion, presumably inducing dermatic diseases and if serious cancer. The present study concerns the binding capacity of Cr(VI) ions in the cement powder and matrix for a quantitative technique of Cr(VI) ions in cement to influence human health. Both the water-soluble and acid-soluble Cr(VI) ions present in 3 types of ordinary Portland cement (OPC), pulverised fuel ash (PFA), ground granulated blast furnace slag (GGBS), and silica fume (SF) were measured using the spectrophotometer. As a result, it was found that the concentration of water-soluble Cr(VI) ion in cement ranged from 10.5 to 18.9mg/kg-cement, and in the additional materials a very low value of Cr(VI) ion was measured. Acid-soluble Cr(VI) ion was even higher than water-soluble Cr(VI) ion, ranging from 172.4 to 318.2mg/kg-cement. Nevertheless, the concentration of acid-soluble Cr(VI) ion is not proportional to addition of acid. It depends rather the variable pH of solvent involving cement paste. As enough cement hydration occurs, the binding capacity of Cr(VI) ion increases, inhibiting this ions from leaching out in the presence of hydration products such as ettringite or tri-calcium aluminate which bind Cr(VI) ion by ion-exchange.

Application of ASTM C 1260 for Cement Matrix Mixed with FlyAsh and Lithium Nitrate (플라이애시와 질산리튬을 사용한 시멘트 경화체의 ASTM C 1260 적용성 검토)

  • Kim, Seong-Kwon;Yun, Kyong-Ku;Hong, Seung-Ho;Kang, Moon-Sik
    • International Journal of Highway Engineering
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    • v.14 no.3
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    • pp.1-7
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    • 2012
  • The purpose of this study was to review application of ASTM C 1260 for cement matrix with flyash and lithium nitrate using reactive aggregate. The experimental program included the accelerated mortar bar test (AMBT: ASTM C 1260) for the slate which was evaluated as reactive aggregate by ASTM C 1260 at the previous study. The cement, which was substituted by 10, 20, 30% flyash containing less than 10% CaO, could control ASR expansion. From the experiment applying lithium nitrate to control ASR, the mortar bar containing lithium nitrate showed more than 0.1% expansion at 14 days. This is probably due to dissolution of lithium nitrate in NaOH solution during test periods. Thus, it is necessary to adopt another test method to verify the control effect of lithium nitrate against alkali-silica reaction.