• Journal of the Korea Concrete Institute
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• v.23 no.4
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• pp.441-448
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• 2011

In this study, experimental tests of chemical and autogenous shrinkage were performed to evaluate the early age shrinkage behaviors of ultra high performance cementitious composites (UHPCC) with various replacement ratios of silica fume (SF), shrinkage reducing agent (SRA), expansive admixture (EA), and superplasticizer (SP). Starting time of self-desiccation, was analyzed by comparing the setting times and the deviated point of chemical and autogenous shrinkage strains. The test results indicated that both SF and SRA augment the early age chemical shrinkage, whereas SP delays the hydration reaction between cement particles and water, and reduces chemical shrinkage. About 49% of autogenous shrinkage was depleted by synergetic effect of SRA and EA. The hardening of UHPCC was catalyzed by containing EA. Self-desiccation of UHPCC occurred prior to the initial setting due to the high volume fraction of fibers and low water-binder ratio (W/B).

• Journal of the Korea Concrete Institute
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• v.23 no.4
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• pp.431-440
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• 2011

Concrete structures exposed to fire produce changes in their internal structure, resulting in their service life reduction due to the deterioration of its strength and performance capacity. The deterioration level are dependent on the temperature, exposure time, concrete mix proportions, aggregate property, and material properties. This study was performed to evaluate the thermal behavior of ultra-high strength concrete for the parameters of water to cement ratio (compressive strength), fine to total aggregate ratio, and maximum coarse aggregate size. At room temperature and $500^{\circ}C$, tests of ultrasonic pulse velocity, resonance frequency, static modulus of elasticity, and compressive strength are performed using ${\varnothing}100{\times}200\;mm$ cylindrical concrete specimens. The results showed that the residual mechanical properties of ultra-high strength concrete heated to $500^{\circ}C$ is influenced by variation of a water to binder ratio, fine to total aggregate ratio, and maximum coarse aggregate size.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.3
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• pp.94-101
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• 2011

In this study, in order to develop organic-inorganic hybrid packaging materials(PM) of bike paths using blast furnace slag(BS) as industrial by-products, fundamental properties of organic-inorganic hybrid packaging materials were performed. Test result, the increase of Acryl emulsion polymer(AEP)/binder(B) ratios tends to delay the setting time, to increase the table flow, to decrease the strength by material segregation and to increase the length change. The optimal mix proportion of AEP decides on 40%(AEP/B) due to workability and high strength. The increase of BS replacement ratios also tends to delay the setting time, to separate AEP from B and to decrease the strength by material segregation. When BS replacement ratios were lower than 40%, they are satisfied with goal properties.

• Korean Journal of Materials Research
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• v.26 no.8
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• pp.449-453
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• 2016

$HA(hydroxyapatite)/{\beta}-TCP$ (tricalcium phosphate) biomaterial (BCP; biphasic calcium phosphate) is widely used as bone cement or scaffolds material due to its superior biocompatibility. Furthermore, $NH_4HCO_3$ as a space holder (SH) has been used to evaluate feasibility assessment of porous structured BCP as bone scaffolds. In this study, using a spark plasma sintering (SPS) process at 393K and 1373K under 20MPa load, porous $HA/{\beta}-TCP$ biomaterials were successfully fabricated using $HA/{\beta}-TCP$ powders with 10~30 wt% SH, TiH2 as a foaming agent, and MgO powder as a binder. The effect of SH content on the pore size and distribution of the BCP biomaterial was observed by scanning electron microscopy (SEM) and a microfocus X-ray computer tomography system (SMX-225CT). The microstructure observations revealed that the volume fraction of the pores increased with increasing SH content and that rough pores were successfully fabricated by adding SH. Accordingly, the cell viabilities of BCP biomaterials were improved with increasing SH content. And, good biological properties were shown after assessment using Hanks balanced salt solution (HBSS).

• Journal of the Korea Concrete Institute
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• v.24 no.1
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• pp.87-95
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• 2012

This study investigated the compressive strength, flexural strength, setting time, and rebound when blast furnace slag and anhydrite, which are widely used mineral admixtures for concrete, are applied to shotcrete. When Ordinary Portland Cement (OPC) was replaced at a rate of 10% with blast furnace slag and anhydrite, the initial and final setting time requirements were all satisfied. However, when OPC was replaced at a rate of 20%, final setting was delayed, revealing that this mixture was not suitable for shotcrete. Compressive strength test results showed that the mixture with 10% OPC replacement rate met the target strength at 1 day and 28 days for permanent tunnel support usage. Particularly, the mixture designed with OPC replacement by blast furnace slag and anhydrite at rates of 5% showed the highest compressive strength. Rebound measurements revealed that this mixture exhibited excellent performance with 23% reduction in the rebound compared to the shotcrete that was produced with only OPC binder.

• KIEAE Journal
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• v.10 no.3
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• pp.89-96
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• 2010

In comparison with ordinary or heavy-weight concrete, light-weight air void concrete has the good aspects in optimizing super tall structure systems for the process of design considering wind load and seismic load by lightening total dead load of buildings and reducing natural resources used. Light-weight air void concrete has excellent properties of heat and sound insulating due to its high amount porosity of air voids. So, it has been used as partition walls and the floor of Ondol which is the traditional Korean floor heating system. Under the condition of which the supply of light-weight aggregates are limited, the development of light-weight concrete using air voids is highly required in the aspects of reduced manufacturing prices and mass production. In this study, we investigated the physical properties and thermal behaviors of specimens that applied different mixing ratios of foaming agent to evaluate the possibility of use in the structural elements. We proposed the estimating equation for compressive strength of each mix having different ratio of foaming agent. We also confirmed that the density of cement matrix is decreased as the mixing amount of foaming agent increase up to 0.6% of foaming agent mixing ratio which was observed by SEM. Based on porosity and compressive strength of control mortar without foaming agent, we built the estimating equations of compressive strength for mortars with foaming agent. The upper limit of use in foaming agent is about 0.6% of the binder amount. Each air void is independent, and size of voids range from 50 to $100{\mu}m$.

• Magazine of the Korea Concrete Institute
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• v.7 no.4
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• pp.109-118
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• 1995

The permeability of concrete is closely related to the durability and the latter may be expressed by measuring permeability of concrete. According to the results, the permeability of fly ash concrete was lower than that of OPC(PC1) concrete and decreased with increasing fly ash levels(l5%, 30% and 45%). The permeability values of concrete cured in water is significantly lower than those of concrete cured in air, but the differences were reduced with increasing fly ash level. In comparison with OPC(PC1) concrete and high fly ash concrete containing enhanced early strength cements, the latter also had a lower permeability than the former. The permeability of concrete cured in water was decreased with curing time(28 and 180 days) irrespectwe of cement types. However, the trend of results cured in air was opposite to that cured in water due to the rnicrocrackinp: of concrete. It was found that the properties of strength and permeability of concrete were related each other. However, the permeability of concrete was more dependant upon the type of binder used in concrete.

• Journal of the Korea Concrete Institute
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• v.14 no.2
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• pp.249-256
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• 2002

High performance concrete is prone to large autogenous shrinkage due to its low water to binder ratio (W/B). The autogenous shrinkage of concrete is caused by self-desiccation as a result of water consumption by the hydration of cement. In this study, the autogenous shrinkage of high performance concrete with and without fly ash was Investigated. The properties of fresh concrete, slump loss, air content, and flowability as well as the mechanical properties, compressive strength and modulus of elasticity, were also measured. Test results was shown that the autogenous shrinkage of concrete increased as the W/B decreased. For the same W/B, the autogenous shrinkage of high strength concrete with fly ash was considerably reduced although the development of its compressive strength was delayed at early ages. Furthermore, the autogenous shrinkage and compressive strength of high strength concrete were more rapidly developed than those of normal strength concrete. It was concluded that fly ash could improve the quality of high strength concrete with respect to the workability and autogenous shrinkage.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.389-394
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• 2017

The aim of the research is providing the application method of recycled materials to manufacture the low costed eco-friend block at currently operated concrete block plant. In this research, based on the previous research results on three types of slag cement with illite, desulfurized gypsum, and wasted refractory products, the actual block product was manufactured by the currently operated plant facility and evaluated their properties to suggest the optimal proportions. As an experimental results, in aspect of compressive strength, absorption ratio, freezing resistance, and pH, type III slag incorporating 5% desulfurized gypsum with 1% replaced illite as an aggregate could be suggested as am optimal proportion. In additionally, considering the high cost of the illite, it can be considered as an optimal proportion that type III slag incorporating 5% desulfurized gypsum for binder.

• Magazine of the Korea Concrete Institute
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• v.11 no.1
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• pp.141-148
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• 1999

Recently, high performance concrete developed has a good quality at fresh and hardened state, but high binder contents results in spending much money on manufacturing and many cracks by drying and autogenous shrinkage, Therefore, in this paper, not only prevention of cracks caused by drying and autogenous shrinkage, but improvement of quality and accomplishment of economy by applying F.A(fly ash), S.F(silica fume) and CSA(calcium sulfa aluminate) expansive additives as an inorganic admixtures in W/B 35% are discussed. According to the experimental results, when 5% of CSA expansive additives and 15:5(F.A:S.F)are replaced at unit cement content, high performance concrete with both good fluidity at fresh state and high compressive strength, compensation of drying and autogenous shrinkage at hardened state are accomplished.