• 콘크리트학회논문집
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• 제29권3호
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• pp.275-281
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• 2017

본 연구는 물-결합재비(water-to-binder ratio, W/B) 및 인산염-결합재비(phosphate-to-binder ratio, P/B)가 마그네시아-인산칼륨 시멘트(magnesium-potassium phosphate cement, MKPC) 모르타르의 플로, 응결시간, 압축강도발현 및 pH 변화에 미치는 영향성에 대한 평가이다. MKPC 모르타르의 P/B가 0.3 및 0.5일 때 W/B 범위 20~40%에 대하여 10 배합의 모르타르 실험을 실시하였으며, X-선 회절 분석(X-ray diffraction, XRD), 전자현미경(scanning electron microscope, SEM) 및 수은압입법(mercury intrusion porosimetry, MIP) 분석을 위해 MKPC의 반응생성물 및 미세공극분포를 평가하였다. 실험결과, MKPC 모르타르의 플로 및 응결시간은 P/B의 증가에 따라 감소하였으며, P/B가 0.3에서 0.5로 증가함에 따라 종결시간은 약 24% 감소하였다. MKPC 모르타르의 초기 압축강도 발현 기울기의 경우 콘크리트 구조기준에서 제시하는 시멘트 콘크리트 대비 높은 수준에 있었다. 재령 28일의 압축강도 30 MPa 이상 및 pH 9.0 이하를 만족하기 위해 MKPC 모르타르의 P/B 및 W/B는 각각 0.5이상 및 30% 이하가 추천된다. MKPC의 반응생성물인 스트루바이트(struvite)-K의 결정은 MKPC의 P/B 및 W/B가 높을수록 증가하였는데, 이로 인해 거대 모세관 공극은 감소하였다.

• 한국건축시공학회지
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• 제4권3호
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• pp.93-100
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• 2004

In recent years, it has widely been studied on the light-weight composites for the purpose of the large space and thermal insulation of building structures. The purpose of this study is to evaluate the properties of light-weight composites made by binders as cement, resin and polymer cement slurry. The concrete composites are prepared with various conditions such as polymer-cement ratio, void-filling ratio, type of resin, filler content and light-weight aggregate content, tested for thermal conductivity. From the test results, the thermal conductivity of concrete composites with the binder of cement tends to decrease with increasing polymer-cement ratio, and to increase with increasing void-filling ratio. The thermal conductivity of concrete composites with the binder of resin are markedly affected by the light-weight aggregate content, type of resin and filler content. The composites made by polymer-modified concrete and polymer cement slurry have a good thermal insulation property. From the this study, we can recommend the proper mix proportions for thermal insulation Panel or concrete. Expecially. the thermal conductivity of concrete composites made by polyurethane resin is almost the same as that of the conventional expanded polystyrene resin.

• KCI Concrete Journal
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• 제13권1호
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• pp.35-41
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• 2001

This paper investigated rheological properties of binder pastes for self-compacting high performance concrete. Six mixtures of self-compacting concrete were initially prepared and tested to estimate self-compacting property. Then, the binder pastes used in self-compacting concrete were tested for rheological properties using a rotary type rheometer. Binder pastes with different water-binder ratios arid flow values were also examined to evaluate their rheological characteristics. The binders were composed of ordinary Portland cement, fly ash, two types of pulverized blast-furnace slag, and limestone powder. The flow curves of binder pastes were obtained by a rotary type rheometer with shear rate control. Slump flow, O-funnel time, box, and L-flow teats were carried out to estimate self-compacting property of concrete. The flow curves of binder pastes for self-compacting concrete had negligible yield stresses and showed an approximately linear behavior at higher shear rates beyond a certain limit. Test results also indicated that the binders incorporating fly ash are more appropriate than the other types of binders in quality control of self-compacting concrete.

• 한국건축시공학회지
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• 제18권4호
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• pp.329-335
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• 2018

본 연구의 목적은 기존 콘크리트 건물의 단면확대 내진보강 기술에서 필요한 고유동 고접착성의 보강 모르타르 배합의 개발이다. 보강 모르타르의 목표성능(플로우 220mm 이상, 압축강도 30MPa, 접착강도 1MPa 이상)을 위해 물-결합재비, 잔골재-결합재비, 폴리머-결합재비, 증점제 사용 및 초속경시멘트의 혼입 등을 변수로 단계적으로 배합실험을 수행하였다. 모르타르의 접착강도는 기존 콘크리트의 다양한 면 처리 상태에 따라 평가하였다. 실험결과로부터 단면증설용 보강 모르타르의 배합을 위해 폴리머-결합재비는 10%, 초속경시멘트의 치환율은 5%가 추천될 수 있었는데, 이 배합은 초기 플로우 220 mm, 높은 초기강도 발현, 압축강도 35 MPa 그리고 접착강도 1.2 MPa 이상의 성능을 보였다.

• Computers and Concrete
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• 제24권2호
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• pp.151-158
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• 2019

The sustainable development principle of replacing natural resources with renewable material is an important research topic. In this study, waste LCD (liquid crystal display) glass powder was used to replace cement (0%, 10%, 20% and 30%) through a volumetric method using three water-binder ratios (0.47, 0.59, and 0.71) to make cement mortar. The compressive strength was tested at the ages of 7, 28, 56 and 91 days. The test results show that the compressive strength increases with age but decreases as the water-binder ratio increases. The compressive strength slightly decreases with an increase in the replacement of LCD glass powder at a curing age of 7 days. However, at a curing age of 91 days, the compressive strength is slightly greater than that for the control group (glass powder is 0%). When the water-binder ratios are 0.47, 0.59 and 0.71, the compressive strength of the various replacements increases by 1.38-1.61 times, 1.56-1.80 times and 1.45-2.20 times, respectively, during the aging process from day 7 to day 91. Furthermore, a prediction model of the compressive strength of a cement mortar with waste LCD glass powder was deduced in this study. According to the comparison between the prediction analysis values and test results, the MAPE (mean absolute percentage error) values of the compressive strength are between 2.79% and 5.29%, and less than 10%. Thus, the analytical model established in this study has a good forecasting accuracy. Therefore, the proposed model can be used as a reliable tool for assessing the design strength of cement mortar from early age test results.

• 한국건축시공학회지
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• 제16권1호
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• pp.45-52
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• 2016

본 연구에서는 무시멘트 결합재(NCB)를 사용한 지반 그라우팅용 약액주입재의 B액 결합재의 종류, 결합재의 W/B 및 A액과 B액의 부피비에 따른 겔타임 및 호모겔강도의 변화 특성을 검토함으로써 무시멘트 결합재의 지반 그라우팅용 결합재로서의 적용 가능성을 검토하고자 하였다. 무시멘트 무기결합재는 당사에서 공동연구를 통해 개발된 시멘트를 대체할 수 있는 고로슬래그 기반의 친환경 무기결합재로서 화학조성비가 다른 NCB-1, 2, 3을 사용하여 실험을 진행하였다. 실험 및 현장 적용성 분석 결과, 겔타임 및 호모겔강도의 요구성능을 확보할 수 있는 결합재 종류별 W/B 및 A액과 B액의 부피비가 도출되었으며, W/B가 100~140%, A : B가 50 : 50~30 : 70인 조건에서 급결구간 및 중결구간의 경우 NCB가 OPC 대비 동일한 겔타임 수준에서 호모겔강도의 확보가 유리한 것으로 평가되어 NCB의 지반 그라우팅용 결합재로서의 적용이 가능할 것으로 판단된다.

• Corrosion Science and Technology
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• 제8권2호
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• pp.74-80
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• 2009

The high alkaline property in the concrete pore solution protects the embedded steel in concrete from corrosion due to aggressive ions attack. However, a continuous supply of those ions, in particular, chlorides altogether with a pH fall in electrochemical reaction on the steel surface eventually depassivate the steel to corrode. To mitigate chloride-induced corrosion in concrete structures, finely grained mineral admixtures, for example, pulverized fuel ash (PFA), ground granulated blast furnace slag (GGBS) and silica fume (SF) have been often advised to replace ordinary Portland cement (OPC) partially as binder. A consistent assessment of those partial replacements has been rarely performed with respect to the resistance of each binder to corrosion, although the studies for each binder were extensively looked into in a way of measuring the corrosion rate, influence of microstructure or chemistry of chlorides ions with cement hydrations. The paper studies the behavior of steel corrosion, chloride transport, pore structure and buffering capacity of those cementitious binders. The corrosion rate of steel in mortars of OPC, 30% PFA, 60% GGBS and 10% SF respectively, with chloride in cast ranging from 0.0 to 3.0% by weight of binder was measured at 7, 28 and 150 days to determine the chloride threshold level and the rate of corrosion propagation, using the anodic polarization technique. Mercury intrusion porosimetry was also applied to cement pastes of each binder at 7 and 28 days to ensure the development of pore structure. Finally, the release rate of bound chlorides (i.e. buffering capacity) was measured at 150 days. The chloride threshold level was determined assuming that the corrosion rate is beyond 1-2 mA/$m^3$ at corrosion and the order of the level was OPC > 10% SF > 60% GGBS > 30% PFA. Mercury intrusion porosimetry showed that 10% SF paste produced the most dense pore structure, followed by 60% GGBS, 30% PFA and OPC pastes, respectively. It was found that OPC itself is beneficial in resisting to corrosion initiation, but use of pozzolanic materials as binders shows more resistance to chloride transport into concrete, thus delay the onset of corrosion.

• 한국건축시공학회지
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• 제8권6호
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• pp.131-137
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• 2008

In recent years, the light-weight aggregate has widely been used to reduce the weight of construction structures, and to achieve the thermal insulation of building structures. The purpose of this study is to evaluate the heat resistance of polymer concrete composites with light-weight aggregate made by binders as resin and cement with polymer dispersion. The light-weight polymer concrete composites are prepared with various conditions such as binder content, filler content, void-filling ratio, light-weight aggregate content and polymer-cement ratio, and tested for heat resistant test, and measured the weight reducing ratio, strengths and exhaustion content of gas such as CO, NO and $SO_2$. From the test results, the weight reducing ratio of light weight polymer concrete using UP binder after heat resistance test increase with an increase in the UP content irrespective of the filler content. The weight reducing ratio of polymer cement concrete is considerably smaller than that of UP concrete. In general, the strengths after heat resistance of polymer concrete composites are reduced about 40 to 65% compared with those before test. The exhausted quantity of CO, NO and $SO_2$ gases in polymer concrete composites is less than EPS(Expanded poly styrene). From the this study, it is confirmed that the many types gases discharge according to binder type of polymer concrete composites, its amount is controlled by selection of the binder type and mix proportions.

• 한국지하수토양환경학회지:지하수토양환경
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• 제21권6호
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• pp.135-145
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• 2016

MgO recently has been regarded as the alternative material for replacement of cement. The aim of this study is to investigate the effects of accelerated carbonation on the strength development of MgO-based binder which is binary mixtures of magnesium oxide (MgO) with portland cement (PC) or ground granulated blast furnace slag (GGBS) or fly ash (FA). The compressive strengths of all binders were higher in the 20% $CO_2$ condition and for longer curing time. The strength were generally higher as the following order: MgO/PC > MgO/GGBS > MgO/FA system. The binder composed of 20% MgO and 80% PC showed highest compressive strength (38.0MPa) which was higher than PC. The correlation analysis of the porosity and compressive strength showed that compressive strength was higher when porosity was lower. The hydration and carbonation products of MgO including brucite ($Ca(OH)_2$), magnesite ($MgCO_3$) and nesquehonite ($MgCO_3{\cdot}3H_2O$) presumably filled the pores and contributed to strength development. Thermogravimetric analyses elucidated that 0.34 kg of $CO_2$ could be stored the 50% MgO/50% PC binder which performed the maximum $CO_2$ uptake at 20% $CO_2$ condition.

• 한국농공학회논문집
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• 제52권3호
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• pp.9-17
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• 2010

This study aims to evaluate a porous concrete using hwang-toh, blast furnace slag and blast furnace slag (BFS) cement instead of type I cement. The tests that were carried out to analysis the properties of porous hwang-toh BFS cement concrete included compressive strength, continuous void ratio, absorption rate, and pH value, repeated freezing and thawing test were conducted. Test results indicated that the performance in porous hwang-toh concrete are effective on the kaoline based binder materials. The pH value were shown in about 9.5 ~ 8.5. The compressive strength was increased and void ratio was decreased with increasing the kaoline based binder materials, respectively. The void ratio and compressive strength were in the range of about 21 ~ 30 %, 8 ~ 13 MPa, respectively. The increased in void ratio of more than 25 % is showed to reduce the resistance of repeated freezing and thawing. Also, the resistance of repeated freezing of thawing and the compressive strength of porous hwang-toh BFS cement concrete are independent with hwang-toh content and BFS cement amount. But, the void ratio was decreased with increasing the high volume hwang-toh contents (more than 15 %).