• Clean Technology
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• v.14 no.4
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• pp.248-255
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• 2008

The volume expansion of three ionic liquids (ILs) in the presence of supercritical carbon dioxide has been measured at pressures up to 32 MPa and at temperatures from 313.15 to 333.15 K in a high-pressure view cell. The imidazolium-derivative ionic liquids 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][$PF_6$]), 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][$BF_4$]), and 1-octyl-3-methylimidazolium tetrafluoroborate ([omim][$BF_4$]) were employed in this research. The effects of pressure, temperature, nature of anion and cation as well as the water content on the volume expansion of ILs by absorbing $CO_2$ were investigated experimentally. The volume expansion was higher for the ILs with longer cationic alkyl group and for the ILs with lower anion polarity. The lower the water content, the lower the temperature, or the higher the pressure, the higher was the expansion of IL phase.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.456-461
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• 2003

A fuel cell is an electrochemical device in which the energy of a chemical reaction is converted directly into electricity. By combining hydrogen fuel with oxygen from air, electricity is formed, without combustion of any form. Water and heat are the only by-products when hydrogen is used as the fuel source. Fuel cell stack consists of multi-layered unit cells. A unit cell consists of MEA and bipolar plates. The end plate of fuel cell stack should give a uniform distributed pressure to multi unit cell layers so as to reduce the contact resistance and to prevent the leakage of reactant gases and the damage of multi layer components. The current end plate is redundantly large and heavy. It makes the power per unit volume reduced. Topology optimization of end plate is conducted for mass reduction and enhancement of bending rigidity. The evaluation of the current design and the recommendation for the future design is remarked.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.31 no.3 s.258
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• pp.380-387
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• 2007

We carried out an image analysis of living cells forming their contacts at the bottom of the cell culturing substrate. In order to visualize the contact area selectively, we adopted total-internal-reflection-fluorescence (TIRF) method, which can illuminate the specimen volume within only several hundred nano-meters above the substrate. From the fluorescent intensity of the TRF image, we could calculate the distance of the cell surface from the substrate. As a result, we visualized the origin of cell contacts, their movements, and the change of cell-contact type from the close-contact into focal-contact with information of its vertical displacement representing the temporal evolution process of the three-dimensional cell-surface-profile near the contact area during this metamorphosis.

• Journal of Korea Water Resources Association
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• v.50 no.5
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• pp.289-302
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• 2017

DFB (Divergence Form for Bed slope source term) was rigorously derived and the error of mDFB using mean water depth at the cell face in DFB was clearly demonstrated. In addition, DFB technique turned out to be an exact method to the bed slope source term. The existing volume/free-surface relationship to the PSC (Partially Submerged Cell) has been corrected. It was discussed that treatment for the partially submerged edge is required to satisfy the C-property in PSC. It is expected that this study will provides a more accurate means in analyzing the shallow water equations with the approximate Riemann solver.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.35 no.8
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• pp.677-684
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• 2007

In the Present Study, a 3-D viscous flow solver, based on unstructured hybrid meshses containing tetrahedra, prisms and pyramids, has been developed. A finite-volume discretization scheme is used for solving the compressible Navier-Stokes equations. A cell-vertex median dual volume is used for spatial discretization. The one-equation Spalart-Allmaras turbulence model has been adopted to evaluate the eddy viscosity. Validation were made by computing laminar and turbulent flows around a 3-D wing for steady flows and turbulent flows around an oscillating 3-D wing in harmonic motion for unsteady flows.

• Journal of the Korean Wood Science and Technology
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• v.45 no.2
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• pp.232-242
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• 2017

The objective of this study was to examine changes in the porosity and internal structure of wood as it goes through the process of saccharification (extraction of fermentable sugars). This study also examined the use of different drying methods to prepare samples for characterization of internal pores, with particular emphasis on the partially disrupted cell wall. Aspen wood flour samples after dilute acid pretreatment followed by enzymatic hydrolysis were examined for nitrogen adsorption. The resulting isotherms were analyzed for surface area, pore size distribution, and total pore volume. Results showed that freeze drying (with sample pre-freezing) maintains the cell wall structure, allowing for examination of saccharification effects. Acid pretreatment (hemicellulose removal) doubled the surface area and tripled the total volume of pores, which were mostly 10-20 nm wide. Subsequent enzymatic hydrolysis (cellulose removal) caused a 5-fold increase in the surface area and a ~ 11-fold increase in the total volume of pores, which ranged from 5 to 100 nm in width. These results indicate that nitrogen adsorption analysis is a feasible technique to examine the internal pore structure of lignocellulosic residues after saccharification. The information on the pore structure will be useful when considering value-adding options for utilizing the solid waste for biofuel production.

• Korea Trade Review
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• v.47 no.1
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• pp.1-12
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• 2022

This study analyzes FCEV among measures to respond to climate change policies. In particular, it proposes alternatives to solve this problem in the trade industry, which relies on transportation sectors with high greenhouse gas emissions such as exports and imports of goods. Therefore, when FCEV is introduced in the transportation sector, changes in CO2 emissions, a greenhouse gas, and changes in logistics costs for changes in CO2 emissions are set through scenarios to evaluate the impact on product trade, such as imports and exports. As a result, the increase in logistics costs due to carbon dioxide emissions affected the import and export volume of goods, and when FCEV was introduced, the export volume would increase by up to 5.6%, and the import volume by up to 30%. In addition, CO2 emissions decreased to about 60% in 2050. Therefore, the introduction of FCEV in the transportation sector will greatly contribute to increasing sales in the trading industry and will be able to solve environmental problems such as greenhouse gas reduction.

• 한국전산유체공학회:학술대회논문집
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• 2005.10a
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• pp.131-134
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• 2005

Conventional high order interpolation schemes are limitative in several aspects mainly because they need data of neighboring cells at the reconstruction step. However, discontinuous Galerkin method and spectral volume method, two high order flux schemes which will be analyzed and compared in this paper, have an important benefit that they are not necessary to determine the flow gradients from data of neighboring cells or elements. These two schemes construct polynomial of variables within a cell so that even near wall or discontinuity, the high order does not deteriorate.

• Journal of the Korean Society of Combustion
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• v.6 no.2
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• pp.15-22
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• 2001

A pressure-based, unstructured finite volume method has been applied to couple the chemical kinetics and fluid dynamics and to capture effectively and accurately the steep gradient flame field. The pressure-velocity coupling is handled by two methodologies including the pressure-correction algorithm and the projection scheme. A stiff, operator-split projection scheme for the detailed nonequilibrium chemistry has been employed to treat the stiff reaction source terms. The conservative form of the governing equations are integrated over a cell-centered control volume with collocated storage for all transport variables. Computations using detailed chemistry and variable transport properties were performed for two laminar reacting flows: a counterflow hydrogen-air diffusion flame and a lifted methane-air triple flame. Numerical results favorably agree with measurements in terms of the detailed flame structure.

• Journal of computational fluids engineering
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• v.14 no.1
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• pp.35-44
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• 2009

To adequately analyze flows in pipe or duct network system, traditional node-based junction coupling methods require the junction loss which is specified by empirical or analytic correlations. In this paper, a new finite volume junction coupling method using a ghost junction cell is developed by considering the interchange of linear momentum as well as the important wall-effect at junction without requiring any correlation on the junction loss. Also, boundary treatment is modified to preserve the stagnation enthalpy across boundaries, such as pipe-end and the interface between junction and branch. Also, the computational accuracy and efficiency of the Godunov-type finite volume schemes are investigated by tracing the total mechanical energy of rapid transients due to sudden closure of valve at downstream end.