• Title/Summary/Keyword: cell degradation

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Study of Light-induced Degradation in Thin Film Silicon Solar Cells: Hydrogenated Amorphous Silicon Solar Cell and Nano-quantum Dot Silicon Thin Film Solar Cell (박막 실리콘 태양전지의 광열화현상 연구: 비정질 실리콘 태양전지 및 나노양자점 실리콘 박막 태양전지)

  • Kim, Ka-Hyun
    • Journal of the Korean Solar Energy Society
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    • v.39 no.1
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    • pp.1-9
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    • 2019
  • Light induced degradation is one of the major research challenges of hydrogenated amorphous silicon related thin film silicon solar cells. Amorphous silicon shows creation of metastable defect states, originating from elevated concentration of dangling bonds during light exposure. The metastable defect states work as recombination centers, and mostly affects quality of intrinsic layer in solar cells. In this paper we present results of light induced degradation in thin film silicon solar cells and discussion on physical origin, mechanism and practical solutions of light induced degradation in thin film silicon solar cells. In-situ light-soaking IV measurement techniques are presented. We also present thin film silicon material with silicon nano-quantum dots embedded within amorphous matrix, which shows superior stability during light-soaking. Our results suggest that solar cell using silicon nano-quantum dots in abosrber layer shows superior stability under light soaking, compared to the conventional amorphous silicon solar cell.

Accelerated Degradation Test of Electrolyte Membrane in PEMFC Stack (고분자 전해질 연료전지 스택에서 전해질막의 열화 가속시험)

  • Jeong, Jaejin;Lee, Sehoon;Lee, Hyeri;Kim, Saehoon;Ahn, Byungki;Ko, Jaijoon;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.6-10
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    • 2016
  • Until a recent day, degradation of PEMFC (Proton Exchange Membrane Fuel Cells) has been mainly studied in unit cell. But operation and degradation of real PEMFC going along in stack instead of unit cell. Therefore in this work, ADT (Accelerated Degradation Test) of PEMFC was done in stack and the result from stack's test was compared with that of unit cell. The polymer electrolyte membrane was degraded by repeated electrochemical and mechanical degradation method among several ADT methods. Current densities of MEA at 0.6V decreased in stack and unit cell, 28.4% and 27.8% respectively after ADT for 312 hours. Hydrogen crossover current densities of membrane increased in stack and unit cell, 16.8% and 15.2% respectively after ADT for 312 hours. The result of ADT in stack was similar that of ADT in unit cell, which showed that ADT method of unit cell was available to the stack.

ATM cell transmission performance evaluation for co-channel interference in the next generation satellite B-ISDN/ATM networks (차세대 위성 B-ISDN/ATM 망에서 공동채널간섭에 대한 ATM 셀 전송 성능평가)

  • 김병균;김신재;최형진
    • Journal of the Korean Institute of Telematics and Electronics S
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    • v.35S no.3
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    • pp.9-18
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    • 1998
  • For constructionof the next generation satellite B-ISDN/ATM networks considering integration with terrestrial information infrastructure networks, various high speed and wideband satellites with be launched and they will make used of frequency reue techniques for efficient management of limited frequency resource. Therefore, CCI(Co-Channel Interference) inherent in frequency reuse will be a dominant factor in performance degradation of satellite networks. This paper alanyzes the ATM cell transmission performance degradation caused by CCI. The satellite link, including up-link and down-link thermal noise, CCI, and nonlinear satellite transponder, is modeled and interleaving technique is used for compensating the ATM cell transmission performance degradation caused by burst error of satellite link. First, each satellite link subsystem is analyzed in detail and then end-to-end ATM cell transmission performance is evaluated with BER and CLR. Specifically, ATMcell transmission performance degradation caused by CCI is evaluated in detail.

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Electrochemical Degradation of Benzoquinone in a Flow through Cell with Carbon Fibers

  • Yoon, Jang-Hee;Yang, Jee-Eun;Shim, Yoon-Bo;Won, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.28 no.3
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    • pp.403-407
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    • 2007
  • The anodic degradation of benzoquinone(BQ), a model compound for wastewater treatment was carried out using a home-made flow-through electrochemical cell with carbon fibers. To optimize the controlled current electrolysis condition of an aqueous BQ solution, the experimental variables affecting the degradation of BQ, such as the applying current, pH, reaction time, and flow rate of the BQ solution were examined. The degradation products of the oxidation reaction were identified by High Performance Liquid Chromatography and Inductively Coupled Plasma Atomic Emission Spectrometer. Low molecular weight aliphatic acids, and CO2 were the major products in this experiment. The removal efficiency of BQ from the solution increased with the applying current and time. 99.23% of 1.0 × 10-2 M BQ was degraded to aliphatic acids and CO2 when the applying current is 175 mA in a 12 hr electrolysis.

Effects of Shut-down Process on Degradation of Polymer Electrolyte Membrane Fuel Cells I. Effects of Hydrogen Removal on the Degradation (운전 정지 시 보관방법이 고분자 전해질 연료전지의 열화에 미치는 영향 I. 잔류 수소 제거 방법의 영향)

  • Lim, Sang-Jin;Cho, Eun-Ae;Lee, Sang-Yeop;Kim, Hyoung-Juhn;Lim, Tae-Hoon;Lee, Kwan-Young
    • Journal of the Korean Electrochemical Society
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    • v.9 no.3
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    • pp.118-123
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    • 2006
  • Degradation of polymer electrolyte membrane fuel cell (PEMFC) that is facilitated by on/off cycles is one of the most important issues for commercialization of fuel cell vehicles. When a PEMFC stack is shut down, residual hydrogen and induce high voltage equivalent to open circuit voltage to the cathode side that might cause sintering of Pt catalyst and facilitate formation of hydrogen peroxide at the anode side that might decompose $Nafionc\'{A}$ membrane. In this study, degradation of PEMFC exposed to repetitive on/off cycles was investigated by measuring i-V characteristics, ac impedance, cyclic voltammograms, gas leak, cross-sectional SEM images, and TEM images. To prevent degradation of PEMFC caused by the residual gases, hydrogen was removed from anode gas channel by gas-purging and by using a dummy resistance, that were found to be a very effective method.

Study of Light-induced Effect on Silicon Solar Cell from Wafer to Cell: A Review (광조사에 의한 실리콘 태양전지 열화 연구)

  • MyeongSeob Sim;Dongjin Choi;Myeongji Woo;Ji Woo Sohn;Youngho Choe;Donghwan Kim
    • Current Photovoltaic Research
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    • v.12 no.1
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    • pp.6-16
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    • 2024
  • The efficiency of silicon solar cells is approaching a theoretical limit referred to as 'the state of the art'. Consequently, maintaining efficiency is more productive than pursuing improvements the last room for limiting efficiency. One of the primary considerations in silicon module conservation is the occurrence of failures and degradation. Degradation can be mitigated during the cell manufacturing stage, unlike physical and spontaneous failure. It is mostly because the chemical reaction is triggered by the carrier generation of thermal and light injection, an inherent aspect of the solar cell environment. Therefore, numerous researchers and cell manufacturers are engaged in implementing mitigation strategies based on the physical degradation mechanism.

Mitigation of Potential-Induced Degradation (PID) for PERC Solar Cells Using SiO2 Structure of ARC Layer (반사방지막(ARC)의 SiO2 구조에 따른 PERC 태양전지 PID 열화 완화 상관관계 연구)

  • Oh, Kyoung Suk;Park, Ji Won;Chan, Sung Il
    • Current Photovoltaic Research
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    • v.8 no.4
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    • pp.114-119
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    • 2020
  • In this study, Mitigation of Potential-induced degradation (PID) for PERC solar cells using SiO2 Structure of ARC layer. The conventional PID test was conducted with a cell-level test based on the IEC-62804 test standard, but a copper PID test device was manufactured to increase the PID detection rate. The accelerated aging test was conducted by maintaining 96 hours with a potential difference of 1000 V at a temperature of 60℃. As a result, the PERC solar cell of SiO2-Free ARC structure decreased 22.11% compared to the initial efficiency, and the PERC solar cell of the Upper-SiO2 ARC structure decreased 30.78% of the initial efficiency and the PID reliability was not good. However, the PERC solar cell with the lower-SiO2 ARC structure reduced only 2.44%, effectively mitigating the degradation of PID. Na+ ions in the cover glass generate PID on the surface of the PERC solar cell. In order to prevent PID, the structure of SiNx and SiO2 thin films of the ARC layer is important. SiO2 thin film must be deposited on bottom of ARC layer and the surface of the PERC solar cell N-type emitter to prevent surface recombination and stacking fault defects of the PERC solar cell and mitigated PID degradation.

DEGRADATION OF NUCLEIC ACIDS BY CELL-FREE EXTRACT OF MIXED RUMEN PROTOZOA OF BUFFALO RUMEN

  • Sinha, P.R.;Dutta, S.M..
    • Asian-Australasian Journal of Animal Sciences
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    • v.1 no.4
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    • pp.219-222
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    • 1988
  • Degradation of deoxyribonucleic acid(DNA) and ribonucleic acid(RNA) by cell-free extract of mixed rumen protozoa of buffalo rumen was investigated. DNA was observed to be degraded rapidly during an initial incubation period of 2 hr with simultaneous appearance of degradation products. RNA on the other hand recorded a rapid degradation during an initial incubation period of 1 hr. RNA degradation products appeared upto an incubation period of 2 hr. DNA was observed to degrade into oligo- and mononucleotides. pyrimidine nucleosides, purine nucleoside adenosine and bases xanthine, hypoxanthine and thymine. Degradation products of RNA comprised of pyrimidine nucleosides, purine nucleoside, adenosine and bases xanthine, hypoxanthine and uracil besides oligo- and mononucleotides.

Design of flow path with 2 inlet and outlets to improve cell performance and prevent cell degradation in Solid Oxide Fuel Cell (SOFC 셀 성능 향상 및 수명 저하 방지를 위한 입구와 출구 2개의 유로 설계)

  • Kim, Dongwoo;Yeom, Eunseop
    • Journal of the Korean Society of Visualization
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    • v.19 no.2
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    • pp.56-62
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    • 2021
  • Solid oxide fuel cells (SOFCs) is the high efficiency fuel cell operating at high temperatures ranging from 700-1000℃. Design of the flow paths of the fuel and air in SOFCs is important to improve cell performance and prevent cell degradation. However, the uneven distribution of current density in the traditional type having one inlet and outlet causes cell degradation. In this regard, the parallel flow path with two inlet and outlets was designed and compared to the traditional type based on computational fluid dynamics (CFD) simulation. To check the cell performance, hydrogen distribution, velocity distribution and current density distribution were monitored. The results validated that the parallel designs with two inlets and outlets have a higher cell performance compared to the traditional design with one inlet and outlet due to a larger reaction area. In case of uniform-type paths, more uniform current density distribution was observed with less cross-sectional variation in flow paths. In case of contracted and expanded inflow paths, significant improvement of performance and uniform current density was not observed compared to uniform parallel path. Considering SOFC cell with uniform current density can prevent cell degradation, more suitable design of SOFC cell with less cross-sectional variation in the flow path should be developed. This work can be helpful to understand the role of flow distribution in the SOFC performance.

Long-term Testing and Analysis of a ScSZ/LaSrCuFe Cell

  • Wackerl, Jurgen;Peck, Dong-Hyun;Markus, Torsten
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.788-795
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    • 2008
  • An electrolyte supported SOFC cell was tested at $800^{\circ}C$ in air for 3600 h with an applied current density of $200\;mA/cm^2$ to examine possible cathode degradation issues. A scandium- stabilized zirconia (ScSZ) with additional manganese doping (ScSZ: Mn) was used as electrolyte. A strontium and copper-doped lanthanum ferrite (LaSrCuFe) and platinum were used as cathode and quasi-anode material, respectively. The DC resistance was logged over the complete testing period. Additionally, impedance spectroscopy was used from time to time to track changes of the cell in-situ. Post-test analysis of the cell using methods like scanning electron microscopy imaging and other electrochemical testing methods allow the identification of different degradation sources. The results indicate a promising combination of electrolyte and cathode material in terms of chemical compatibility and electrical performance.