• Journal of the Korean Ceramic Society
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• v.39 no.10
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• pp.988-993
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• 2002

Electrochemical cells for decomposing $NO_x$ were fabricated using a hydrothermally synthesized lanthanum stannate pyrochlore catalyst. Thick film of the catalyst on the YSZ electrolyte disk was produced by screen-printing a paste consisted of $La_2Sn_2O_7$ and YSZ powders. Direct current was applied to the electrochemical cell to promote an electrochemical catalytic decomposition of $NO_x$. $NO_x$ decomposition behavior of the rectant gas mixture ($NO_x$ 0.1%, $O_2$ 2%) was investigated at 700${\circ}C$ under atmosphere pressure using on-line gas chromatography and $NO_x$ analyzer. It was observed that microstructure of the catalyst layer significantly influences the electrocatalystic decomposition of $NO_x$.

• New & Renewable Energy
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• v.9 no.1
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• pp.51-59
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• 2013

Tantalum carbide crystallites which is to be used for $H_2$ fuel cell has been synthesized via a temperature-programmed reduction of $Ta_2O_5$ with pure $CH_4$. The resultant Ta carbide crystallites prepared using two different heating rates and space velocity exhibit the different surface areas. The $O_2$ uptake has a linear relation with surface area, corresponding to an oxygen capacity of $1.36{\times}10^{13}\;O\;cm^{-2}$. Tantalum carbide crystallites are very active for hydrogen production form ammonia decomposition reaction. Tantalum carbides are as much as two orders of magnitude more active than Pt/C catalyst (Engelhard). The highest activity has been observed at a ratio of $C_1/Ta^{{\delta}+}=0.85$, suggesting the presence of electron transfer between metals and carbon in metal carbides.

• Korean Membrane Journal
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• v.3 no.1
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• pp.69-74
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• 2001

Films of TiO$_2$/SiO$_2$ were deposited on the inner surface of the porous glass support tubes by decomposition of tetraisopropyl titanate (TIPT) and tetraethyl orthosilicate (TEOS) at atmospheric pressure. Dense and hydrogen -permselective membranes were formed at 400-600$\^{C}$. The permeation rates of H$_2$ through the membrane at 600$\^{C}$ were 0.2-0.4 ㎤(STP)/min-㎠ atm and H$_2$:N$_2$permeation ratios were above 1000. The permeation properties of the membranes were investigated at various deposition temperatures and TIPT/TEOS concentrations. Decomposition of TIPT alone at temperatures above 400$\^{C}$ produced porous crystalline TiO$_2$ films and they were not H7-selective. Decomposition of TEOS produced H$_2$-permeable SiO$_2$ films at 400-600$\^{C}$ but film deposition rate was very low. Addition of TIFT to the TEOS stream significantly accelerated the deposition rate and produced highly H$_2$-selective films. Increasing the TIPT/TEOS concentration ratio increased the deposition rate. The TiO$_2$/SiO$_2$ membranes formed at 600 $\^{C}$ have the permeation properties comparable to those of SiO$_2$ membranes produced from TEOS.

• Proceedings of the Korean Nuclear Society Conference
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• 2002.05a
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• pp.420.1-420
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• 2002

Thermal decomposition reaction of gas-phase UO2(hfacac)2. THF was investigated in a static cell. IR spectroscopic method was used to study the thermal decomptsition of gas phase uranyl complexes. The decomposition reaction products were separated by using thermal-gradient fractional sublimation method utilizing the differences in their volatility.

• The Journal of Korea Robotics Society
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• v.2 no.4
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• pp.304-309
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• 2007

This paper describes an efficient path generation method for area coverage. Its applications include robots for de-mining, cleaning, painting, and so on. Our method is basically based on a divide and conquer strategy. We developed a novel cell decomposition algorithm that divides a given area into several cells. Each cell is covered by a robot motion that requires minimum time to cover the cell. Using this method, completeness and time efficiency of coverage are easily achieved. For the completeness of coverage in dynamic environments, we also propose a path following method that makes the robot cover missed areas as a result of the presence of unknown obstacles. The effectiveness of the method is verified using computer simulations.

• Journal of Institute of Control, Robotics and Systems
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• v.16 no.1
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• pp.48-52
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• 2010

In this paper, we introduce a new path planning algorithm which combines the merits of a visibility graph algorithm and an adaptive cell decomposition. We quantize a given map with empty cells, blocked cells, and mixed cells, then find the optimal path on the quantized map using a visibility graph algorithm. For reducing the number of the quantized cells we use the quad-tree technique which is used in an adaptive cell decomposition, and for improving the performance of the visibility checking in making a visibility graph we propose a new visibility checking method which uses the property of the quad-tree instead of the well-known rotational sweep-line algorithm. For the more efficient visibility checking, we propose two additional improvements for our suggested method. Both of them are used for reducing the visited cells in the quad-tree. The experiments for a performance comparison of our algorithm with other well-known algorithms show that our proposed method is superior to others.

• Elastomers and Composites
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• v.50 no.4
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• pp.297-303
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• 2015

Ammonium polyphosphate-polyurethane foam composite (APP-PUF) was prepared from poly(adipate)diol/ammonium polyphosphate composite (f = 2), polyether polyol (f = 4.6), and PMDI (f = 2.5). As a blowing agent, $H_2O$ was used at various concentrations. The thermal decomposition behavior, morphology, closed-cell content, and density of APP-PUF were characterized. At the $H_2O$ concentrations lower than 3.5 php, the cell size of pure polyurethane foams (PUF) and APP-PUFs were close each other. As the $H_2O$ concentration became greater than 5.0 php, the cell size of the PUFs greatly increased compared to that of APP-PUFs. Addition of 1.5~1.9 wt% ammonium polyphosphate to the PUFs greatly enhanced the thermal stability of the PUFs, so 50 wt% residual temperature of APP-PUFs increased to $380{\sim}488^{\circ}C$, which were $30{\sim}70^{\circ}C$ higher than those of the PUFs. Thermal stability of the PUFs and APP-PUFs increased with $H_2O$ content and then decreased once $H_2O$ content exceeded 5 php.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.6
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• pp.514-523
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• 2021

This study investigated the effect of anode fuel composition on the performance of direct borohydride/hydrogen peroxide fuel cells (DBHPFCs). The effect of sodium borohydride (NaBH₄) and sodium hydroxide (NaOH) concentrations on fuel cell performance was determined through fuel cell tests. Fuel cell performance increased with an increase in the NaBH₄ concentration, whereas it decreased with an increase in the NaOH concentration. The anode fuel composition was selected as 10 wt% NaBH₄+10 wt% NaOH+80 wt% H₂O based on the fuel viscosity, electrochemical reaction rate, and decomposition reaction rate. DBHPFCs were also tested to analyze the effect of operating temperature and operation time on fuel cell performance. The present results can be used as a reference basis to determine operating conditions of DBHPFCs.

• 한국방재학회:학술대회논문집
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• 2007.02a
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• pp.71-74
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• 2007

Thin-walled multicell box girders subjected to an eccentric load can be produced the three global behaviors of flexure, torsion, and distortion. But it is very difficult to evaluate each influences of major behaviors numerically. If we can decompose an eccentric load P into flexural, torsional, and distortional forces, we can execute quantitative analysis each influences of major behaviors. Decomposition of Applied Load for Thin-walled Rectangular multi-cell box girders is researched by Park, Nam-Hoi(Development of a multicell Box Beam Element Including Distortional Degrees of Freedom, 2003). But researches about thin-walled trapezoidal multi-cell section is insufficient. So, this paper deals with decomposition process and independent analysis method of multi-cell box girders include trapezoidal section.

• Journal of the Korean Society for Precision Engineering
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• v.26 no.7
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• pp.73-80
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• 2009

This paper describes a path planning algorithm, which is the minimal turning path based on the shape and size of the cell to clean up the whole area with two cleaning robots. Our method divides the whole cleaning area with each cell by cellular decomposition, and then provides some path plans among of the robots to reduce the rate of energy consumption and cleaning time of it. In addition we suggest how to plan between the robots especially when they are cleaning in the same cell. Finally simulation results demonstrate the effectiveness of the algorithm in an unknown area with multiple robots. And then we compare the performance index of two algorithms such as total of turn, total of time.