• Title/Summary/Keyword: cation distribution

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A Study On The Characteristics Of The Medium Voltage Power Distribution Line Channel By Wideband Channel Impulse Response Measurement Using PN Sequence (PN 시퀀스 방식의 광대역 임펄스 응답 측정을 통한 고압 배전선로 채널 특성 연구)

  • Oh, Hui-Myoung;Choi, Sung-Soo;Lee, Jae-Jo;Kim, Kwan-Ho;Whang, Keum-Chan
    • Proceedings of the KIEE Conference
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    • 2004.07d
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    • pp.2646-2648
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    • 2004
  • 전력선 통신(Power-Line Communi-cation)에 있어서 전력선은 유선 매체임에도 불구하고 수많은 분기 및 부하접속, 그리고 상호간의 임피던스 부정합에 의해 무선 통신 채널 환경과 같은 다중 경로 페이딩 특성을 갖게 된다. 따라서 채널의 다중경로 해석이 상당히 중요하며, 실제 전력선 통신 채널 연구 분야에서 신호 송수신단 사이의 임펄스 응답 측정을 바탕으로 다중경로를 분석하는 방안이 적용되고 있다. PN 시퀀스를 이용한 광대역 임펄스 응답 측정 방식은 무선 채널 환경에 대해 개발되었으나, 현재는 무선 채널은 물론 전력선 채널과 같은 유선 채널에서도 적용되고 있다. 게다가 고압 배전선로와 같이 다중 경로를 포함하는 장거리 통신채널은 PN 시퀀스 방식이 여러 가지 면에서 효율적이다[1]. 본 논문에서는 PN 시퀀스 방식의 광대역 임펄스응답 측정 방법을 통해 고압 배전선로 채널의 다중경로 특성을 측정, 검토하고 이를 제시하였다.

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A Study on the Development and Application of Slow Releasing Fertilizer using Korean Natural Clay Minerals-I. Characterization of Korean Natural Clay (점토광물을 이용한 완효성비료의 개발 및 응용에 관한 연구-I. 점토광물의 특성)

  • Park, Jung-Chul;Choy, Jin-Ho;Park, Kuen-Woo
    • Korean Journal of Environmental Agriculture
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    • v.3 no.2
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    • pp.50-54
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    • 1984
  • For the development of slow releasing K-fertilizer, K-ion exchanged montmorillonite was evaluated and characterized by layer charge determination with n-alkylammonium method. By this method it was possible to discern inhomogenous charge distribution within the crystals and to estimate the upper and lower limit of the layer charge(layer charge limit for Young-il bentonite in Korea: ${\xi}=0.39-0.28$ $e/(SiAl)_4O_{10}$, ${\xi}=0.34$) and the mean value of interlayer cation exchange capacity of 0.915meq/100g.

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Isospecific Propylene Polymerization Behavior of Lewis Base Functionalized Unbridged Zirconocences under Bulk Conditions

  • Yoon, Seung Woong;Kim, Hwa Kyu;Kim, Seong Kyun;Kim, Taewon;Lee, Min Hyung;Do, Youngkyu
    • Bulletin of the Korean Chemical Society
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    • v.35 no.1
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    • pp.236-242
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    • 2014
  • Isospecific propylene polymerization behavior of meta- and para-Lewis base (E) functionalized unbridged zirconocenes ($[1-(E_n-Ph)-3,4-Me_2C_5H_2]_2ZrCl_2$, E = $NMe_2$, OMe; n = 1 or 2) was investigated under bulk conditions. Catalytic activity of the zirconocenes, and molecular weight and isotacticity of polypropylenes are found to be dependent on the position and number of the Lewis base functional groups in the zirconocenes. All the crude polypropylenes possess a broad molecular weight distribution and multi-melting transitions, indicating an involvement of multi-catalytic active species in the polymerization. The highest [mmmm] value of an isotactic portion of the polypropylenes reached 89%, which is higher than that (85%) from the well-known $C_2$-symmetric EBIZr (rac-$Et(Ind)_2ZrCl_2$) catalyst. These results support that the in situ generated, rigid rac-like cation-anion pair through the Lewis acid-base interactions between the functional groups of zirconocenes and methylaluminoxane anion is effective in the formation of isotactic polypropylene under bulk propylene polymerization conditions.

Crystallographic and Magnetic Properties of Li0.7Co0.2Ti0.2V0.2Fe1.7O4 Ferrite

  • Chae, Kwang-Pyo;Kwon, Woo-Hyun;Lee, Jae-Gwang
    • Journal of Magnetics
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    • v.15 no.1
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    • pp.25-28
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    • 2010
  • This study examined the crystallographic and magnetic properties of vanadium-substituted lithium cobalt titanium ferrite, $Li_{0.7}Co_{0.2}Ti_{0.2}V_{0.2}Fe_{1.7}O_4$. Ferrite was synthesized using a conventional ceramic method. The samples annealed below $1040^{\circ}C$ showed X-ray diffraction peaks for spinel and other phases. However, the sample annealed above $1040^{\circ}C$ showed a single spinel phase. The lattice constant of the sample was $8.351\;{\AA}$, which was relatively unaffected by vanadium-substitution. The average grain size after vanadium-substitution was $13.90\;{\mu}m$, as determined by scanning electron microscopy. The M$\ddot{o}$ssbauer spectrum could be fitted to two Zeeman sextets, which is the typical spinel ferrite spectra of $Fe^{3+}$ with A and B sites, and one doublet. From the absorption area ratio of the M$\ddot{o}$ssbauer spectrum, the cation distribution was found to be ($Co_{0.2}V_{0.2}Fe_{0.6})[Li_{0.7}Ti_{0.2}Fe_{1.1}]O_4$. Vibrating sample magnetometry revealed a saturation magnetization and coercivity of 36.9 emu/g and 88.6 Oe, respectively, which were decreased by vanadium-substitution.

Characterization of the Brain Transport and Brain-to-Blood Efflux of Nitrone Based Antioxidant, PBN (Nitrone계 항산화제 (PBN)의 뇌에서 혈액으로의 배출과 뇌 수송 특성)

  • 이나영;강영숙
    • YAKHAK HOEJI
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    • v.47 no.4
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    • pp.224-229
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    • 2003
  • We have investigated the transport characteristics of synthetic antioxidant and free radical scavenger, $\alpha$-phenyl-n-tert-butyl nitrone (PBN) at the blood-brain barrier (BBB) by in vitro uptake study in conditionally immortalized rat brain capillary endothelial cell line (TR-BBB). Also, the efflux of PBN from brain to blood is estimated using the brain efflux index (BEI) method. Choline is a charged organic cation, including nitrogen-methyl group and shows the carrier-mediated distribution to the brain. [$^3$H]Choline uptake by TR-BBB cells was significantly inhibited by PBN with $IC_{50}$/ of 1.2 mM, which appears to be due to similar structures between choline and PBN. And, PBN was microinjected into Par2 of the rat brain by BEI method, and was eliminated from the brain with an apparent elimination half-life of about 2 min. Also, [$^3$H]choline efflux was significantly inhibited by PBN using BEI method. In conclusion, the efflux transport of PBN takes place across the BBB and PBN may be transported into the brain and eliminated from the brain by BBB choline transporter.

Crystallographic Effects of Larger Indium Ion Substitution in NiFe2-xInxO4 (x = 0, 0.2, 0.5, and 1.0) System

  • Yoon, Sung-Hyun;Yoon, Chang-Sun;Kim, Byung-Ho
    • Journal of Magnetics
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    • v.10 no.1
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    • pp.23-27
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    • 2005
  • The crystallographic and magnetic properties of a series of substitutions in nickel ferrite where the Fe3+ is replaced with In3+ have been investigated using X-ray diffraction (XRD) and Mössbauer spectroscopy. Information on the exact crystalline structure, lattice parameters, bond lengths and bond angles were obtained by refining their XRD profiles by a Rietveld method. All the crystal structures were found to be cubic with the space group Fd/3m. The lattice constants increased with In3+ concentration. The expansion of the tetrahedron was outstanding, indicative of the tetrahedral (A) site preference of larger indium ion. The Mossbauer spectra showed two sets of sextuplet originating from ferric ions occupying the tetrahedral sites and the octahedral (B) sites under the Neel temperature TN. Regardless of the composition x, the electric quadrupole splitting was zero within the experimental error. At x = 0.2, the magnetic hyperfine fields increased slightly, which meant that the nonmagnetic indium ions occupied preferentially the A-site. At the same time, the intensity of the B-site sub-spectra decreased markedly at the elevated temperature, indicating that the occupation of the A site by indium induced a considerable perturbation on the B site.

Effects of Polyelectrolytes on the Charge Transfer Complexing between Indole derivatives and Methylviologen: Hydrophobic and Electrostatic Interactions

  • Park, Joon-Woo;Hwang, Book-Kee
    • Bulletin of the Korean Chemical Society
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    • v.6 no.3
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    • pp.145-148
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    • 1985
  • The effect of anionic polyelectrolytes, poly(styrenesulfonate) (PSS) and poly(vinylsulfonate) (PVS), on the charge transfer complexing between indole derivatives and methyl viologen($MV^{++}$) cation was investigated. The results were compared with effect of NaCl and an anionic surfactant, sodium dodecylsulfate (SDS). Both PSS and PVS enhanced the complex formation of neutral species (indole and indole acetate at low pH), zwitter ionic tryptophan, and positively charged tryptamine and tryptophan at low pH with $MV^{++}$. This result was attributed to the contribution of hydrophobic interaction, in addition to electrostatic interaction. The enhancing effect of PSS was much higher than that of PVS reflecting the higher hydrophobicity of PSS. The interaction between indole acetate anion and $MV^{++}$ was greatly reduced by addition of PVS and PSS. The higher charge density of PVS was appeared as greater reducing effect indicating the importance of electrostatic force in this case. In all cases, the effect of polyelectrolytes showed maxima, and further addition of PVS and PSS decreased the effect. This behavior was explained in terms of distribution of indole derivatives and $MV^{++}$ in domain of polyanions. The complex formation constants and molar absorptivities of complexes were determined, and the values were compared with those in water and SDS solutions.

Synthesis and Magnetic Properties of Nano-sized Mn Ferrite Powder and Film

  • Kwon, Woo-Hyun;Lee, Jae-Gwang;Lee, Young-Bae;Chae, Kwang-Pyo
    • Journal of Magnetics
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    • v.16 no.1
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    • pp.27-30
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    • 2011
  • Nano-sized manganese ferrite powders and films, $MnFe_2O_4$, were fabricated by the sol-gel method, and the effects of annealing temperature on the crystallographic and magnetic properties were studied by using X-ray diffractometry, field emission scanning electron microscopy, M$\"{o}$ssbauer spectroscopy, and vibrating sample magnetometry. X-ray diffraction spectroscopy of powder samples annealed above 523 K indicated the presence of spinel structure, and the film samples annealed above 773 K also had spinel structure. The particle size increased with the annealing temperature. For the powder samples, the Mossbauer spectra annealed above 573 K could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and octahedral sites of $Fe^{3+}$ ions. Using the M$\"{o}$ssbauer subspectrum area ratio the cation distribution could be written as ($Mn_{0.52}Fe_{0.48}$) $[Mn_{0.48}Fe_{1.52}]$ $O_4$. However the spectrum annealed at 523 K only showed as a doublet due to a superparamagnetic phase. As the annealing temperature was increased, the saturation magnetization and the corecivity of the powder samples increased, as did the coercivity of film samples.

The Effect of Long-term Organic Matter Addition on the Physicochemical Properties of Paddy Soil (답토양(沓土壤)에서 퇴비연용(堆肥連用)이 토양(土壤)의 이화학적성질(理化學的性質)에 미치는 영향(影響))

  • Shin, Jae Sung;Shin, Yong Hwa
    • Korean Journal of Soil Science and Fertilizer
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    • v.8 no.1
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    • pp.19-23
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    • 1975
  • In order to find out the effect of long-term annual additions of organic matter on the physico-chemical properties of paddy soil, the soil with and without compost application has been analysed. 1. There was no significant difference in the particle size distribution between compost and uncompost treatment, however, hydraulic conductivity, sedimention volume were remarkedly increased in compost. 2. Bulk density and soil strength were decreased in organic matter additions, but porosity increased. 3. Relative to Atterberg Limits, liquid limit, plastic limit, and elastic index were increased in compost. 4. Aggregate size distribution was slightly increased in additions of organic matter. 5. Regarding to chemical properties, pH, organic matter content, C.E.C. and extractable cation were increased in organic matter additions.

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Significance of Urease Distribution across Helicobacter pylori Membrane

  • Gang, Jin-Gu;Yun, Soon-Kyu;Choi, Kyung-Min;Lim, Wang-Jin;Park, Jeong-Kyu;Hwang, Se-Young
    • Journal of Microbiology and Biotechnology
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    • v.11 no.2
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    • pp.317-325
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    • 2001
  • For heuristic purposes, the relative ratio of urease contents inside and outside cells was surveyed using nine ureB+ strains of Helicobacter pylori. the ratio of the enzyme specific activity appeared to vary greatly between the various H. pylori strains, ranging from 0.5 to 2.5. Besides the above compartment, urease was also richly found in the membrane fraction, especially in either peripheral or integral form. The urease distribution across the H. pylori membrane was significantly influenced by the ambient pH; the specific activity of external urease was highest at pH 5.5 with a narrow plateau, whereas the internal specific activity was highest within a pH range of 4.5 to 6.5 with a broad plateau. These finding strongly suggest that H. pylori urease is secretory and responded to the external pH. However, at pH 4.0 or below, no urease activity was detected in either the internal or external compartment, although an increase in the color development with 2,4,6-trinitrobenzene sulfonate (TNBS) was observed. Sodium dodecyl sulfate polyacrylamide gel electrophoresis (SDS-PAGE) demonstrated that these phenomena may be related to a specific proteolysis in certain proteins, including urease or ${\gamma}$-glutamyl transpeptidase. Interestingly, the effect of ammonium ions n alleviating the enzyme inactivation inside the H. pylori cells was remarkably similar to that of D-glucose. In addition, it would appear that the cation acted as a surrogate of not only $Na^+$ but also $K^+$ thereby increasing the H. pylori P-type ATPase activity. This is of great interest, as it implies that the urease action in H. pylori is indispensible at any locus.

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