• 제목/요약/키워드: catalytic effect

검색결과 826건 처리시간 0.024초

5 kW급 고온형 연료전지 촉매 연소기 유동 균일화 장치가 연소 특성에 미치는 영향 (Effect of Flow Uniformity Device on the Catalytic Combustor for 5 kW High Temperature Fuel Cell System)

  • 이상민;우현탁;안국영
    • 한국수소및신에너지학회논문집
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    • 제22권6호
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    • pp.878-883
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    • 2011
  • Effect of flow uniformity on the reaction characteristics of a catalytic combustor for high temperature fuel cell system has been experimentally investigated in the present study. One of the most important factor in designing catalytic combustion is to avoid hot spot in catalysts. In this regard, it is very important to secure flow uniformity of combustor inlet. A couple of perforated plates were applied at the front of catalyst region as flow uniformity device with minimal pressure drop. Results show that the velocity and temperature profile became more uniform when applying the flow uniformity device. CO and $CH_4$ emissions at the combustor exit were decreased and the average exit temperature was slightly increased with the flow uniformity device.

Facile Preparation of Ag2S-CNT Nanocomposites with Enhanced Photo-catalytic Activity

  • Meng, Ze-Da;Sarkar, Sourav;Zhu, Lei;Ullah, Kefayat;Ye, Shu;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제51권1호
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    • pp.1-6
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    • 2014
  • Here we report improved photo-catalytic effect of $Ag_2S$ under visible light using carbon nano-tubes (CNT) modified with $Ag_2S$ nanoparticles. The optical properties, structural properties and compositional analysis, as well as the photo-electrochemical properties of the prepared composites were investigated. It was found that the photocurrent density, and the photo-catalytic effect, was increased by modification of CNT in this way. Compared with the separate effects of $Ag_2S$ and CNT nanoparticles, the photocatalytic effect of CNT-modified-with-$Ag_2S$ composites, increased significantly due to a synergistic effect between the CNT and the $Ag_2S$ nanoparticles.

크기에 따른 스위스 롤 형태 연소기의 성능 변화 (Effects of Size on the Performance of Heat-Recirculating Swiss-roll Combustors)

  • 오화영;김연호;허환일
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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    • pp.46-49
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    • 2006
  • Extinction limits and combustion temperatures in heat-recirculating excess enthalpy reactors employing both gas-phase and catalytic reaction have been examined previously, with and emphasis Reynolds number (Re) effects and possible application to microscale combustion devices. However, Re is not the only parameter needed to characterize reactor operation. In particular, the use of a fixed reactor size implies that residence time and Re cannot be adjusted independently. To remedy this situation, in this work geometrically similar reactors of different physical sizes were tested with the aim of independently determining the effects of Re and Da. It is found that the difference between catalytic and non-catalytic combustion limits narrow as scale decreases. Moreover, to assess the importance of wall thermal conductivity, reactors of varying wall thickness were studied. From these results the effect of scale on microscale reactor performance and implications for practical microcombustion devices are discussed.

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세라믹 가스 터빈용 촉매연소기의 연소특성 (Combustion Characterisitics of a Catalytic Combustorfor an Automotive Ceramic Gas Turbine)

  • 김영일
    • 한국산업융합학회 논문집
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    • 제1권2호
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    • pp.49-54
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    • 1998
  • In the catalytic combustor, combustion characteristic and deterioration of catalysts were affected by non-uniformity of pre-mixed gas, Therefore, formation of uniform pre-mixed gas is one of important subjects. In this study, the effect of uniformity and non-uniformity of pre-mixed gas supplied to the catalyst was examined to clarify reaction acceleration and combustion characteristic of the catalytic combustion. It was clarified that static mixer or vaporizer tube length of about 150mm and weak swirl to a combustion air were effictive expedient to make uniform pre-mixed gas. And catalystic inlet temperature needs more than $600^{\circ}C$ with rich pre-mixed gas to active reaction.

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무전해 Co-Cu-P 도금속도에 미치는 도금 조건과 표면상태의 영향 (Effect of Plating Condition and Surface on Electroless Co-Cu-P Alloy Plating Rate)

  • 오이식
    • 동력기계공학회지
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    • 제4권2호
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    • pp.31-39
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    • 2000
  • Relationships between the plating condition and the plating rate of the deposition film for the electroless plating of Co-Cu-P alloy were discussed in this report. The result obtained from this experiment were summarized as follow ; The optimum bath composition was consisted of 0.8 ppm thiourea as a stabilizing agent. Composition of the deposit was found to be uniform after two hours of electroless plating. Plating rates of nickel-catalytic surface and zincate-catalytic surface were found to be very closely equal, but the plating time of nickel-catalytic surface took longer than that of the zincated-catalytic surface.

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LDPE 반회분식 촉매열분해에서 조업조건이 반응 특성에 미치는 영향 (Effects of Reaction Conditions on the Performance of Catalytic Pyrolysis of LDPE in a Semi-Batch Reactor)

  • 나정걸;임철현;최휘경;정수현
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.79-82
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    • 2006
  • Fueled by ballooning oil prices, waste plastics are now regarded as being cheap and abundant renewable sources, removing their stigma of dirty wastes Catalytic pryolysis of plastics in liquid phase allows recovery of light fuel oil as well as green treatment of polymerics wastes, and therefore significant efforts have been devoted to this research field. In this study, catalytic Pyrolysis of LDPE was carl ied out in semi-batch reactor which equipped a unit of separation and recirculation. The effect of react ion conditions were examined by analyzing liquid oil yield and carbon number distribution of products

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적외선 열화성 온도 측정법을 이용하여 살펴본 서브밀리미터 스케일 촉매 연소기에서의 수소-공기 예혼합 가스의 촉매 연소 특성 (An Investigation on Combustion Characteristics of Hydrogen-Air Premixture in a Sub-millimeter Scale Catalytic Combustor using Infrared Thermography)

  • 최원영;권세진
    • 한국연소학회지
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    • 제10권3호
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    • pp.17-24
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    • 2005
  • A sub-millimeter scale catalytic combustor with a simple plate-shaped combustion chamber was fabricated. A porous ceramics support coated with platinum catalyst was placed in the chamber. The combustor has a gallium arsenide window on the top that is transparent to infrared ray. The temperature distribution in the combustion chamber was measured using infrared thermal imager while hydrogen-air premixture is steadily supplied to the combustor. The area where the catalytic reaction took place broaden for higher flow rate and lower equivalence ratio made activated area in the combustion chamber broaden. The amount of coated platinum catalyst did not affect the reaction. Stop of reaction, which is similar to flame quenching of conventional combustion, was investigated. Large content of heat generation and broad activated area are essential criteria to prevent stop of reaction that has a bad effect on the combustor performance.

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촉매연소를 이용한 무 산소 가스 생성에 관한 연구 (A Study on the Generation of Oxygen-Free Gas Using Catalytic Combustion for Industrial Applications)

  • 정남조;강성규;송광섭;조성준;유상필;유인수
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2001년도 제22회 KOSCI SYMPOSIUM 논문집
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    • pp.46-52
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    • 2001
  • In this study, the generation of oxygen-free gas using catalytic combustion for industrial applications is explained ; heat treatment and copper annealing. For the experiment, Pd catalysts were determined by testing their catalytic activities over LPG in a micro-reactor. Combustion characteristics for the generation of oxygen-free atmospheric gas and the effect of flue gas upon surface oxidation were estimated form this experiment. As a result of the experimental investigation, we can state that the catalytic combustion could generate oxygen-free atmospheric gas suitable for industrial applications, but vapor produced by combustion process must be carefully considered as a new factor of surface oxidation.

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다꾸치 방법을 이용한 디젤엔진용 후처리시스템의 입구부 형상 최적화 (The Inlet Shape Optimization of Aftertreatment System for Diesel Engine with Taguchi Method)

  • 정종화;김종학;김상호
    • 한국자동차공학회논문집
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    • 제20권5호
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    • pp.145-151
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    • 2012
  • New design of catalytic converter is proposed by optimization of DFSS (Design For Six Sigma) and DOE (Design Of Experiment) method which is based on taguchi matrix. As a result of the optimization of design of catalytic converter, this paper classifies Exhaust-downpipe shapes with 3 parameters to increase flow velocity uniformity of front catalytic substrate face from CFD results. after finishing with L9 Taguchi test matrix, it can be found the main effect of each design parameter of concept model, and optimal design level. in conclusion, it can be increase flow uniformity from 0.60 upto 0.80 with optimal diffuser shape for Turbo-charger.

스크린 프린팅법을 이용하여 제조된 고분자 전해질 연료전지에서 MEA(조합 막 전극)의 특성 (Characteristics of Fabricated MEA(Membrane Electrode Assembly) on Polymer Electrolyte Membrane Fuel Cell Made by the Screen Printing Method)

  • 임재욱;최대규;류호진
    • 반도체디스플레이기술학회지
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    • 제2권4호
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    • pp.27-30
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    • 2003
  • The effect of fabrication method of catalytic layer on electrode performance has been investigated. Brush, spray gun and screen printer were used as fabrication tool and catalytic layers were formed by several methods in screen printing. Direct screen printing on polymer membrane, screen printing on carbon paper, and their combined method were applied. In the electrode fabricated by the screen printing method, Pt loading of Pt/C catalysts could be cut down to 50%, compared with results by the brushing and spraying methods. The best result of electrode was obtained as 0.6 V, at 1 A/$\textrm{cm}^2$ when catalytic layer was formed by the combined way.

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