• 한국자동차공학회논문집
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• 제13권3호
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• pp.80-86
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• 2005

In this study, we investigated the characteristics of the conversion efficiency and the effect of ageing Diesel Oxidation Catalyst (DOC). The DOC was composed of Warm-up Catalytic Converter (WCC) and Underbody Catalytic Converter (UCC). As the result, the conversion efficiency of THC was 10$\~$50$\%$ on WCC and 30$\~$40$\%$ on UCC .The conversion efficiency of CO was 80$\~$90$\%$ on WCC and remained 10$\~$20$\%$ of CO was purified on UCC. The WCC shows high conversion efficiency on CO. After 20 hours aging process of engine bench, conversion efficiencies of THC and CO were improved a little, because it was activated catalyst surface by 20 hours aging. In case of 80 hours aging, the conversion efficiencies of THC and CO were decreased on WCC. However, the UCC was not affected by aging process .

• 공업화학
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• 제4권3호
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• pp.549-557
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• 1993

헤테로폴리산 촉매에 의한 에탄올 전환반응에서, 반응성, 반응 메카니즘, 반응물과 함께 주입된 유기염기의 효과 및 금속염 촉매의 산의 세기와 촉매활성과의 관계를 연구하였다. 에탄을 전환반응은 촉매의 의액상에서 일어났고, 이러한 성질 때문에 아주 높은 촉매활성을 보여 주었으며, $SiO_2$에 담지시켜 표면적을 증가시킨 촉매에서도 활성이 그다지 증가하지 않았다. 에틸렌과 에테르가 생성되는 반응 메카니즘은 서로 다른 것으로 관찰되었으며, 알루미늄 이온에 의해 부분적으로 이온교환된 여러 가지 12-텅스토인산염들은 서로 다른 촉매활성을 보여주었다.

• 한국환경과학회지
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• 제16권9호
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• pp.1077-1083
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• 2007

[ $V_2O_5/TiO_2$ ] catalyst impregnated ceramic candle filters are in principle, capable of performing shallow-bed dust filtration plus a catalytic reaction, promoted by a catalytic deposited in their inner structure. Pilot-scale $V_2O_5/TiO_2$ catalyst impregnated ceramic candle filters were prepared, characterized and tested for their activity towards the SCR reaction. The effect on NO conversion of operating temperature, gas hourly space velocity, amount of deposited catalyst, pressure drops and long-term experiment (life of catalytic filter) was determined. The following effects of $V_2O_5/TiO_2$ catalyst impregnated ceramic candle filters in SCR reaction are observed: (1) It increases the activity and widens the temperature window for SCR. (2) When the content of $V_2O_5$ catalyst increases further from 3 to 9wt.%, activity of NO increases. (3) NO conversion at first increases with temperature and then decreases at high temperatures (above $400^{\circ} over), possibly due to the occurrence of the ammonia oxidation reaction.

• 한국환경보건학회지
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• 제26권3호
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• pp.61-68
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• 2000

The use of photo-catalytic processes in pollution abatement and resource has a significant economic importance. Therefore, the applications of photochemical oxidation of secondary effluent driven by UV, TiO2, TiO2/UV, H2O2/UV and TiO2/H2O2/UV, have been investigated in order to treat the secondary effluent from municipal sewage. Various experimental parameters such as BOD, CODcr, Nurbidity, total P, and SPC were examined in each photo-catalytic reaction system. The results showed that the application of single oxidant such as UV, TiO2 only has a minor effect on parameters reduction (CODcr, BOD, etc) to treat the secondary effluent, whereas the combinations of oxidants increase the removal efficiency. The best removal efficiency in every parameters was achieved by the combination of TiO2, H2O2 and UV. It was also found that the optimum amount of TiO2 for the treatment was 1g/ι to achieve water reuse standard. From the results, the photocatalytic reaction system can be an alternative as a post-treatment to treat the secondary effluent from municipal sewage.

• 한국자동차공학회논문집
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• 제15권5호
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• pp.105-111
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• 2007

In this study, we investigated the conversion performance of de-NOx catalyst for lean-burn natural gas engine. As a de-NOx catalyst, NOx storage reduction catalyst was composed of Pt, Pd and Rh with washcoat including Ba and Ni, Ru-ZSM-5. Ni, Ru-ZSM-5, which was regarded as a NOx direct decomposition catalyst, was made up of ion exchanged ZSM-5 by 5wt.% Ni or Ru. The performance of de-NOx catalyst was evaluated by NOx storage capacity and catalytic reduction in air/fuel, $\lambda=1.6$. The catalytic reaction was also observed when the added fuel was supplied to fuel rich atmosphere by fuel spike period of 5 seconds. The NOx conversion of the catalysts with Ni-ZSM-5 or Ru-ZSM-5 was mainly caused by the effect of NOx adsorption of Ba rather than the catalytic reduction of Ni, Ru-ZSM-5. Ni, Ru-ZSM-5 catalysts can not use for the NSR catalyst because they have quick process in thermal deactivation.

• Advances in nano research
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• 제5권3호
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• pp.231-244
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• 2017

Graphene oxide (GO) was prepared by modified Hummer's method to produce reduced graphene oxide (RGO) following standard thermal and chemical reduction processes. Prepared RGO colloids were utilized to fabricate RGO films over glass and FTO coated glass substrates through drop-coating. A systematic study was performed to evaluate the effect of reduction degree on the optical and electrical properties of the RGO film. We demonstrate that both the reduction process (thermal and chemical) produce RGO films of similar optical and electrical behaviors. However, the RGO films fabricated using chemically reduced GO colloid render better performance in dye sensitized solar cells (DSSCs), when they are used as counter electrodes (CEs). It has been demonstrated that RGO films of optimum thicknesses fabricated using RGO colloids prepared using lower concentration of hydrazine reducer have better catalytic performance in DSSCs due to a better catalytic interaction with redox couple. The better catalytic performance of the RGO films fabricated at optimal hydrazine concentration is associated to their higher available surface area and lower grain boundaries.

• Bulletin of the Korean Chemical Society
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• 제29권1호
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• pp.57-60
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• 2008

Catalytic oligomerization of isobutene to produce triisobutenes has been performed over a cation-exchange resin (Amberlyst-35) by using commercial C4 feeds. The catalytic activity in the oligomerization was retained without deactivation up to 90 h of reaction in a simulated reaction feed without butadiene, but its activity was significantly affected by the presence of butadiene in commercial C4 feeds. The isobutene conversion with time-on-stream was significantly decreased in the presence of butadiene, indicating the catalyst deactivation by butadiene. However, the stable activity for trimerization was accomplished when the oligomerization was carried out after eliminating butadiene by hydrogenation of the feeds. This work demonstrates that butadiene plays a role as a catalyst poison on the solid acid catalyst, so that its removal in the reactant feed is essential for practical application of trimerization.

• 대한화학회지
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• 제12권3호
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• pp.121-127
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• 1968

In the oligomerization of p-aminophenol under the catalytic action of the metallic complexes, the effects of the ligands are studied. When the initial velocity of $O_2$ uptake at pH 8 using Fe(Ⅲ) as the central metal and N-hydroxylethylethylenediaminetriacetic acid (HEDTA), ethylenediaminetetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), 1,2-cyclohexanediaminetetraacetic acid(CyDTA) as the ligands respectively are compared, the velocities are as the following order: HEDTA > EDTA > DTPA > CyDTA. Further when the effect of the ligands, nitrilotriacetic acid (NTA), HEDTA, EDTA, and DTPA, on the yields of oligomers are compared, the result shows as the following order: NTA > HEDTA > EDTA > DTPA. These are nearly reverse order of the stability constants of the complexes. In order to determine the composition of the mixed complexes at the initial step, the method of continuous variation is used, and it is found that the composition ratio of Fe-EDTA complex to monomer in the mixed complexes is one at pH 5-8 range. It is also found that at pH 9 or in the more alkaline range, side reactions occur to form water soluble dimer of quinone type and the catalytic action of the metallic complex markedly decreases on account of the hydrolysis of the central metal by the $OH^-$ ion.

• 대한기계학회논문집A
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• 제37권3호
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• pp.419-427
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• 2013

자동차 배기계의 앞쪽에 배치된 촉매변환기는 배기가스 중 유해한 성분을 무해한 것으로 변환하는 제품이다. 담체를 매트에 두르고 캔에 넣는 캐닝공정을 통하여 제작된다. 매트의 압력이 너무 높으면 담체가 파손되기 쉽고, 너무 작으면 담체가 미끄러지기 쉽다. 담체, 매트와 캔에 대한 통계학적인 오차분포를 반영하여 공정능력수준을 예측하고 담체의 파손이나 미끄러짐도 예측하는 프로그램을 EXCEL로 개발하였다. 상용 프로그램 결과와 비교하여 공정능력평가와 유한요소해석의 타당성을 입증하였다. 기존에 독립적으로 수행하던 유한요소 해석과 공정능력분석을 통합하였다.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 2003년도 춘계 학술발표회 논문집
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• pp.579-587
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• 2003

에나멜 도장장치의 건조 과정에서는 유해한 VU가 다량 배출된다. 이 VOC 가스는 촉매연소를 통해 완전 소각될 수 있으며, 소각되는 과정에서 발생된 열은 공정에 다시 사용할 수 있다. 본 연구에서는 이러한 기술적 특성을 이용하여 환경개선과 에너지 절감 효과가 뛰어난 에나멜 도장장치를 개발하였다. 이를 위한 기초 연구로서 촉매의 VOC 가스에 대한 연소 특성 및 성능 평가와 수치해석이 수행되었다. 연구 결과에 의하면, 고온에서 VOC에 대한 금속 촉매 폼의 성능은 우수한 것으로 나타났으며, 건조 과정이 효율적으로 진행되기 위해서는 재 순환 가스 공급량 및 건조 가스 흡입량의 정밀한 조절이 가능한 구조로 설계되어져야 함을 보여 주었다.