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Effect of Surface Treatment on Hydrogen Production of Cadmium Sulfide Particulate Film Electrodes (수소제조용 CdS 입자막 전극의 표면처리 효과)

  • Jang, Jum-Suk;Chang, Hye-Young;So, Won-Wook;Rhee, Young-Woo;Moon, Sang-Jin
    • Journal of Hydrogen and New Energy
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    • v.11 no.3
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    • pp.119-125
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    • 2000
  • To improve the photochemical energy conversion efficiency and the stability of CdS particulate film electrode which is used to produce hydrogen from the aqueous $H_2S$ solution photoelectrochemically, surface treatment of this film was carried out using $TiCl_4$ solution. CdS particles for preparation of the films were synthesized by precipitation reaction of $Cd({NO_3})_2{\cdot}9H_2O$ and $Na_2S{\cdot}4H_2O$. Then, the CdS sol was hydrothermally treated for 12hr in an autoclave with the variation of treatment temperature to control the crystalline phase of particles. CdS film electrode was thus prepared by annealing at $400^{\circ}C$ for 12hr of the wet-film cast at room temperature, and subsequently surface treated with $TiCl_4$ solution. The electrodes were characterized using XRD, SEM, and the photocurrent meter. The photocurrents of Cds film electrodes prepared with surface treatment were up to two times higher than the electrodes without surface treatment, indicating about $4.0mA/cm^2$. Hydrogen production rate in a continuous flow system using photoelectrochemical or photochemical cells prepared with surface treatment also increased in proportion to the increase of photocurrents.

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THE INFLUENCE OF THE DIE HARDENER ON GYPSUM DIE (석고 다이에 대한 다이 강화제의 영향)

  • Kim, Young-Rim;Park, Ju-Mi;Song, Kwang-Yeob
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.4
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    • pp.546-554
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    • 2007
  • Statement of problem: Die materials require abrasion resistance, dimensional stability with time, and high surface wettability for adequate material properties. Wear of gypsum materials is a significant problem in the fabrication of accurately fitting cast prosthetic devices. So It has been recommended that the use of die hardener before carving or burnishing of the wax pattern. Purpose: The purpose of this study was to compare the abrasion resistance and surface microhardness(Knoop) with 3 commonly used gypsum die materials(MG Crystal Rock, Super plumstone, GC $FUJIROCK^{(R)}$ EP) with and without the application of 2 die hardeners. Material and methods: Three die materials were evaluated for abrasion resistance and surface microhardness after application of 2 die hardeners(Die hardener and Stone die & plaster hardener). Thirty specimens of each gypsum material were fabricated using an impression of resin die(Pattern resin; GC Corporation, Japan) with 1-mm high ridges, sloped 90 degrees. Gypsum materials were mixed according to manufacturer's recommendations and allowed to set 24 hours before coating. Specimens were arbitrary assigned to 1 of 3 treatment subgroups (n=10/subgroup): no treatment(control), coated with Die hardener, and coated with Stone die & plaster hardener. Abrasion resistance(measured by weight loss) was evaluated using device in 50g mass perpendicular to the ridges. Knoop hardness was determined by loading each specimen face 5 times for 15 seconds with a force of 50g. A scanning electron microscope was used to evaluate the surface of specimens in each treatment subgroup. Conclusions: The obtained results were as follows: 1. 3 types of die stone evaluated in this study did not show significant differences in surface hardness and abrasive resistance(P<.05). 2. In the abrasive resistance test, there were no significant differences between GC $FUJIROCK^{(R)}$ EP and MG Crystal Rock with or without 2 die hardener(P<.05). 3. Super plumstone treated with Stone die & plaster hardener showed increased wear loss(P<.05) 4. Die hardener coatings used in this study decreased the surface hardness of the gypsum material(P<.05).

A study on the Policy Formation Process of Multi-Functions of Social Welfare Facilities (사회복지시설 다기능화 정책 형성과정에 관한 연구)

  • Kim, Jin Woo
    • Korean Journal of Social Welfare
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    • v.69 no.1
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    • pp.125-145
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    • 2017
  • The Purpose of this research is to draw implications of Multi-Functions of social welfare facilities on non-public social welfare delivery system especially in the rural area where there is not enough welfare infrastructure. The policy formation process of social welfare facilities was reviewed with 'Modified Policy Streams Framework" which combined Kingdon's Model with Mucciaroni's Model. Multi-Functions Policy of Social Welfare Facilities was led by the government with background of powerful President's initial stage of taking the power and finally legislated by amending Social Welfare Service Act in line with efficiency of non-public social welfare delivery system. However, the process did not represent the summation of needs originated from social work practice. The government just play the role of collecting some evidence underpinning the necessity of multi-functions of social welfare facilities and rearanging how to deploy the multi-functions policy. As the result the multi-functions policy is not activated and is not able to be the key criteria in expanding social welfare infrastructure. However, in spite of these limitation, the issue of multi-functions of social welfare facilities can cast the light on expanding infrastructure in the rural area where the gross size of area in larger in comparison to the district in the metropolitan city whereas residents are scattered because more number of social welfare facilities can not be the solution due to the limitation of finance and logic of efficiency.

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An Experimental Study on Flexural Behavior of Steel Fiber Reinforced Ultra High Performance Concrete Prestressed Girders (강섬유 보강 초고성능 콘크리트 프리스트레스트 거더의 휨거동 실험 연구)

  • Yang, In-Hwan;Joh, Chang-Bin;Kim, Byung-Suk
    • Journal of the Korea Concrete Institute
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    • v.22 no.6
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    • pp.777-786
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    • 2010
  • This paper examines the flexural behavior of full-scale prestressed concrete girders that were constructed of steel fiber reinforced ultra high performance concrete (UHPC). This study is designed to provide more information about the bending characteristics of UHPC girders in order to establish a reasonable prediction model for flexural resistance and deflection for future structural design codes. Short steel fibers have been introduced into prestressed concrete T-girders in order to study their effects under flexural loads. Round straight high strength steel fibers were used at volume fraction of 2%. The girders were cast using 150~190 MPa steel fiber reinforced UHPC and were designed to assess the ability of steel fiber reinforced UHPC to carry flexural loads in prestressed girders. The experimental results show that steel fiber reinforced UHPC enhances the cracking behavior and ductility of beams. Moreover, when ultimate failure did occur, the failure of girders composed of steel fiber reinforced UHPC was observed to be precipitated by the pullout of steel fibers that were bridging tension cracks in the concrete. Flexural failure of girders occurred when the UHPC at a particular cross section began to lose tensile capacity due to steel fiber pullout. In addition, it was determined that the level of prestressing force influenced the ultimate load capacity.

THE FRACTURE CHARACTERISTICS OF GLASS FIBER POST AND CORE ON USING DIFFERENT TYPES OF CORE RESIN MATERIALS

  • Shim Dong-Wook;Shim June-Sung;Lee Seok-Hyung;Lee Keun-Woo
    • The Journal of Korean Academy of Prosthodontics
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    • v.42 no.3
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    • pp.280-293
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    • 2004
  • Statement of problem. Glass fiber post is one of recent developments to accommodate esthetic restoration for endodontically treated teeth. This has many advantages over conventional post system in physical properties, esthetic factor, risk of root and restoration fracture, adhesion to core, radiopacity, removal and retrievabilty, biocompatibility and chemical stability. Purpose. This in vitro study was to evaluate the most suitable type of resin core for the glass fiber post through surveying the fracture modes and the maximum load that fractures the tooth. Material and methods. 50 sound maxillary premolars restored with glass fiber posts($ParaPost^{(R)}$ Fiber White) and different types of resin cores(ParaCore, $Z100^{TM}$, $Rebilda^{(R)}$ and $Admira^{(R)}$) were prepared and loaded to faiure in a universal test machine. The maximum fracture load and fracture mode were investigated in the specimens that were restored with resin and those of metal cast and core. With the data, Wilcoxon rank sum test was used to validate the significance between the test groups, and Tukey' s studentized range test was used to check if there is any significant statistical difference between each test group. Every analysis was approved with 95% reliance. Results. On measuring the maximum fracture load of teeth specimens, there was a significant difference between the maximum fracture loads of the tooth specimens. ParaCore showed the highest mean maximum fracture load followed by $Z100^{TM}$. And, the distribution of fracture mode of tooth specimens showed generally Type D, the three parted fracture of the core around the post was mostly seen(62.5%), and specifically, ParaCore showed 90% and $Z100^{TM}$ showed 100% Type D fracture. Conclusion. Referring to the values of maximum fracture load and mean compressive fracture load, ParaCore and $Z100^{TM}$ had high values and are recommended as tooth colored resin core material for glass fiber post. CLINICAL IMPLICATIONS. This study was carried out intending to be of aid in selecting the appropriate resin core for the glass fiber post. The dual cure type composite resin ParaCore and light cure type composite resin $Z100^{TM}$ have good properties and are recommended as tooth colored resin core material for glass fiber post.

Semantic Network Analysis of Presidential Debates in 2007 Election in Korea (제17대 대통령 후보 합동 토론 언어네트워크 분석 - 북한 관련 이슈를 중심으로)

  • Park, Sung-Hee
    • Korean journal of communication and information
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    • v.45
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    • pp.220-254
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    • 2009
  • Presidential TV debates serve as an important instrument for the general viewers to evaluate the candidates’ character, to examine their policy, and finally to make an important political decisions to cast ballots. Every words candidates utter in the course of entire election campaign exert influence of a certain significance by delivering their ideas and by creating clashes with their respective opponents. This study focuses on the conceptual venue, coined as ‘stasis’ by ancient rhetoricians, in which the clashes take place, and examines the words selection made by each candidates, the manners in which they form stasis, call for evidence, educate the public, and finally create a legitimate form of political argumentation. The study applied computer based content analysis using KrKwic and UCINET software to analyze semantic networks among the candidates. The results showed three major candidates, namely Lee Myung Bak, Jung Dong Young, and Lee Hoi Chang, displayed separate patterns in their use of language, by selecting the words that are often neglected by their opponents. Apparently, the absence of stasis and the lack of speaking mutual language significantly undermined the effects of debates. Central questions regarding issues of North Korea failed to meet basic requirements, and the respondents failed to engage in effective argumentation process.

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Some Evidences for Glacial Landforms on the Baekdusan and Its Implications to Quaternary Volcanic Eruptions (백두산 빙하지형의 존재 가능성과 제4기 화산활동과의 관계)

  • Lee, Sung-Ee;Seong, Yeong-Bae;Kang, Hee-Cheol;Choi, Kwang-Hee
    • Journal of the Korean Geographical Society
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    • v.47 no.2
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    • pp.159-178
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    • 2012
  • Since the suggestions on the paleo-glacial landforms in and around the northern high mountains of Korean Peninsula by some western and Japanese scientists in the early 1900s, the likelihood of the glacier existence in the Baekdusan over the Quaternary glacial period has been had in common among most of the Korean geomorphologists. In the other meaning, some have cast doubt on the likelihood the paleo-glacier in the Baekdusan because there has been no unequivocal evidences for the glacier such as striation, moraines, except morphologic characteristic landforms possibly related to glacier. Here we show some evidences for the existence of the glacier in the Baekdusan and their cosmogenic $^{36}Cl$ exposure ages over the late Quaternary and would put forward a model on the Quaternary landscape evolution of the Baekdusan, with a focus on the relationship of 1000 AD explosive eruption and the glacial landforms. The exposure ages constrained by cosmogenic $^{36}Cl$ abundances of the col surface of the western slope located below the glacier yield 46~26 ka, which is inphase with the last glacial period. Given all the evidences above, we can draw a conclusion that the glacier existed on the Baekdusan over the late Quaternary and the style of glaciation changed from extensive ice cap through valley glacier to restricted cirque.

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Anchorage Strength of Headed Bars in Steel Fiber-Reinforced UHPC of 120 and 180 MPa (120, 180 MPa 강섬유 보강 초고성능 콘크리트에 정착된 확대머리철근의 정착강도)

  • Sim, Hye-Jung;Chun, Sung-Chul;Choi, Sokhwan
    • Journal of the Korea Concrete Institute
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    • v.28 no.3
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    • pp.365-373
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    • 2016
  • Ultra-High-Performance Steel Fiber-Reinforced Concrete (SUPER Concrete) exhibits improved compressive and tensile strengths far superior to those of conventional concrete. These characteristics can significantly reduce the cross sectional area of the member and the anchorage strength of a headed bar is expected to be improved. In this study, the anchorage strengths of headed bars with $4d_b$ or $6d_b$ embedment length were evaluated by simulated exterior beam-column joint tests where the headed bars were used as beam bars and the joints were cast of 120 or 180 MPa SUPER Concrete. In all specimens, the actual yield strengths of the headed bars over 600 MPa were developed. Some headed bars were fractured due to the high anchorage capacity in SUPER Concrete. Therefore, the headed bar with only $4d_b$ embedment length in 120 MPa SUPER Concrete can develop a yield strength of 600 MPa which is the highest design yield strength permitted by the KCI design code. The previous model derived from tests with normal concrete and the current design code underestimate the anchorage capacity of the headed bar anchored in SUPER Concrete. Because the previous model and the current design code do not consider the effects of the high tensile strength of SUPER Concrete. From a regression analysis assuming that the anchorage strength is proportional to $(f_{ck})^{\alpha}$, the model for predicting anchorage strength of headed bars in SUPER Concrete is developed. The average and coefficient of variation of the test-to-prediction values are 1.01 and 5%, respectively.

Shear Capacity of Precast Concrete Triple Ribs Slab (프리캐스트 콘크리트 트리플 리브 슬래브의 전단성능)

  • Hwang, Seung-Bum;Seo, Soo-Yeon;Lee, Kang-Cheol;Lee, Seok-Hyun
    • Journal of the Korea Concrete Institute
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    • v.28 no.4
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    • pp.489-496
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    • 2016
  • Recently, a concern about hollow core precast concrete (PC) slab has been increased as a method to improve the construction ability by reducing the self weight of structures during the construction. Hollow core slab which is known as a typical PC slab in domestic construction of PC building has a problem to put shear reinforcements in the web of element during the production of element in the factory. With regard to this point, recently, tripple ribs slab (TRS) which can be said as a new type of half PC slab system was developed. In TRS, it is possible to place shear reinforcements in PC element during the production of the element in the factory. This paper presents the shear test result of TRS which was done by one point loading test under simple support condition. Test parameters are the presence of cast-in-place (CIP) concrete and the contribution of lattice bars. From the test, it was found that the TRS has sufficient shear capacity to resist the design load and its strength can be predicted by the code equations for general beam. It is recommended to ignore the strength of lattice bar in the calculation of shear strength during the construction since its contribution is too low to be considered when CIP is not casted.

Screening method of varietal resistance to planthoppers labeled with radioisotope $^{32}P$ ( I ) (방사성동위원소 $^{32}P$를 이용한 멸구 류에 대한 품종저항성 검정방법에 관한 연구(I))

  • Lee J. O.;Kim Y. H.;Park J. S.;Seok S. J.;Goh H. G.
    • Korean journal of applied entomology
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    • v.20 no.2 s.47
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    • pp.117-121
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    • 1981
  • The screening method of varietal resistance on the plant hoppers has generally been evaluated as a reaction of plant after infesting insects. However, feeding amount of insects to the varieties was investigated in this experiment. The new method using isotope $^{32}P$ for rice varietal resistance to plant hoppers was carried out through the following method. Insects tested were caged for a few hours on the plants which had absorbed $^{32}P$ solution in small vials for $24\~48\;hours$. After feeding, insects were killed in the refrigerator with formalin solution, and then were measured by the feeding amount as a count per minute (CPM) with the G.M. Counter. The results obtained were summarized as follows; 1. The apparatus of Type D(Fig. 2) was most effective and the safest among four others. 2. The optimum amount of $H_3PO_4$ solution was found to be $2\~3m1$. 3. Radioactivity of $0.7\mu\;Ci.\;^{32}P$ was sufficient to check varietal difference of feeding amount by the brown planthopper. 4. Radioisotope was found from the body of insects but not in the cuticular layer nymphs cast off.

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