• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 1998년도 가을 학술발표회 논문집(I)
• /
• pp.203-206
• /
• 1998

In reinforced concrete carbonation of concrete leads to depassivation of the reinforcement, and hence to initiation of corrosion. As a result of carbonation accelerating experiment with using effect of wet-dry cycle and 15% concentration of CO ₂, the carbonation rate shows very distinct difference according to W/C ratio. OPC-40 estimated no carbonation depth, whereas OPC-60 estimated rapidly the carbonation rate. The comparative analysis of the carbonation rate accelerating depends on different kinds of cement shows fastest FAC-20. Also, highly W/C ratio's concrete shows low half-cell potential value and fast corrosion rate. During period for 14 weeks. corrosion rate was not severe. So, it can be concluded that only carbonation attack on concrete doesn't severly deteriorated except very poor qualitified concrete.

• Computers and Concrete
• /
• 제8권2호
• /
• pp.177-192
• /
• 2011

This research paper aims at computer based modeling of carbonation induced corrosion under extreme conditions and its experimental verification by incorporating enhanced electrochemical and mass balance equations based on thermo-hygro physics with strong coupling of mass transport and equilibrium in micro-pore structure of carbonated concrete for which the previous research data is limited. In this paper the carbonation induced electrochemical corrosion model is developed and coupled with carbon dioxide transport computational model by the use of a concrete durability computer based model DuCOM developed by our research group at concrete laboratory in the University of Tokyo and its reliability is checked in the light of experiment results of carbonation induced corrosion mass loss obtained in this research. The comparison of model analysis and experiment results shows a fair agreement. The carbonation induced corrosion model computation reasonably predicts the quantitative behavior of corrosion rate for normal air dry relative humidity conditions. The computational model developed also shows fair qualitative corrosion rate simulation and analysis for various pH levels and coupled environmental actions of chloride and carbonation. Detailed verification of the model for the quantitative carbonation induced corrosion rate computation under varying relative conditions, different pH levels and combined effects of carbonation and chloride attack remain as scope for future research.

• 한국세라믹학회지
• /
• 제55권2호
• /
• pp.160-165
• /
• 2018

This paper investigates the reaction rate of $CO_2$ storing carbonation hybrid reaction by comparing the behavior of carbonation between $Ca(OH)_2$ and fly ash with that of CFBC (Circulating Fluidized Bed Combustion) containing plenty of Free-CaO. Because fly ash with CFBC contains a lot of unreacted CaO, it cannot be used as a raw material for concrete admixtures and its usages are limited. To reuse such material, we stabilized unreacted CaO by carbonation and investigated the carbonation rate. We used a pH meter and a thermometer to check the rate of the carbonization. Also, we set the contents of fly ash with CFBC, $Ca(OH)_2$, flow and fluid of $CO_2$, respectively, to 100 g, 50 g, 100 ~ 1000 cc/min and 400 g based on the content of Free-CaO. We used carbonated water instead of water, and added an alkaline activator to promote the carbonation rate. As a result, the addition of the alkaline activator and carbonated water promoted the rate of carbonation via a hybrid reaction.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
• /
• pp.655-660
• /
• 2002

Major deterioration in concrete structures are salt attack and carbonation. Especially severe problems due to carbonation occur in tile concrete structures of city, tunnel, underground structures. Cracks in concrete during service life including early age due to hydration heat and/or shrinkage accelerate the diffusion of concrete so that the deterioration is also accelerated. In this study, carbonation depths of both non-cracked concrete and cracked concrete are evaluated and weight change test and TGA are carried out. Through the tests, a relation between water-cement ratio and carbonation depth is derived and also carbonation increase rate is derived in the function of crack width.

• 한국산업융합학회 논문집
• /
• 제23권6_2호
• /
• pp.1111-1117
• /
• 2020

In this study, the carbonation characteristics of concrete according to the mixture of OLED waste glass were evaluated. Replacement capacities of OLED waste glass were 0%, 10%, 20%, and 30% of cement, and they were named OG 0, OG 10, OG 20, and OG 30. As a result of the compressive strength test, OG 0 without replacing OLED waste glass showed high intensity until the 14th. However, the higher the replacement rate of OLED waste glass, the higher the compressive strength of 28 days. In addition, the speed of carbonation was faster with the higher the replacement rate of OLED waste glass, and the accelerated carbonation experiment was about three times faster than the natural carbonation test. In conclusion, the carbonation characteristics of OLED concrete are expected to be positive in terms of atmospheric CO2 absorption.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2019년도 춘계 학술논문 발표대회
• /
• pp.30-31
• /
• 2019

Carbonation of the root concrete reduces the durability of the reinforced concrete, and it is important to check the carbonation resistance of the concrete to ensure the durability of the reinforced concrete structure. In this study, a basic study on the prediction of carbonation progress was conducted by considering the mixing conditions of concrete using deep learning algorithm during the theory of artificial neural network theory. The data used in the experiment used values that converted the carbonation velocity coefficient obtained from the mixing conditions of concrete and the accelerated carbonation experiment into the actual environment. The analysis shows that the error rate of the deep learning model according to the Hidden Layer is the best for the model using five layers, and based on the five Hidden layers, we want to verify the predicted performance of the carbonation speed coefficient of the carbonation test specimen in which the exposure experiment took place in the real environment.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
• /
• pp.1193-1198
• /
• 2001

The glass of Ground Granulated Blast Furnace Slag(GGBFS) was released by the hydroxyl ions during the hydration of the Portland cement. That results in relatively less $Ca(OH)_{2}$ in the concrete replaced with GGBFS than in ordinary portland cement concrete(OPCC). As the quantity of $Ca(OH)_{2}$ is decreased, the rate of carbonation in the concrete replaced GGBFS is faster than OPCC. Therefore, it has been misunderstood that the concrete replaced GGBFS has negative effect on the corrosion of steel by carbonation. Therefore, this study aimed at the relation between carbonation and rebar corrsion in the concrete with GGBFS, measuring air.water permeability, half cell, and corrosion rate by the depth of carbonation.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2022년도 가을 학술논문 발표대회
• /
• pp.187-188
• /
• 2022

In this study, the compressive strength and carbonation properties of geopolymer paste according to the amount of alkali admixture added were evaluated for the development of geopolymer concrete that recycles industrial waste. A geopolymer paste specimen was prepared using Ca(OH)2 as an admixture, and the prepared specimen was standard cured for 28 days. After curing, the compressive strength of the specimen was measured. As the amount of alkali admixture increased, the compressive strength increased. After curing, carbonation was carried out for 7 days in a CO2 5% environment. As a result of comparative evaluation of the amount of CaCO3 produced according to carbonation, the amount of CaCO3 produced increased as the amount of Ca(OH)2 added increased. However, when the amount of admixture added exceeds 5%, the increase rate decreases, so the optimum addition rate is considered to be 5%.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2019년도 추계 학술논문 발표대회
• /
• pp.60-61
• /
• 2019

Concrete carbonation is one of the factors that reduce the durability of concrete. In modern times, due to industrialization, the carbon dioxide concentration in the atmosphere is increasing, and the impact of carbonation is increasing. So, it is important to understand the carbonation resistance according to the concrete compounding to secure the concrete durability life. In this study, we want to predict the concrete carbonation velocity coefficient, which is an indicator of the carbonation resistance of concrete, through the deep learning algorithm, and to find the activation function suitable for the prediction of carbonation rate coefficient as a process to determine the learning accuracy through the deep learning algorithm. In the scope of this study, using the ReLU function showed better accuracy than using other activation functions.

• 자원환경지질
• /
• 제50권1호
• /
• pp.27-34
• /
• 2017

제강 환원슬래그(steelmaking reduction slag)를 출발물질로 사용하여 다양한 농도의 $H_2SO_4$, $NH_4NO_3$(0.3, 0.5, 0.7, 1 M) 용액, 반응온도 $100^{\circ}C$와 $150^{\circ}C$의 조건에서 Ca 용출 및 탄산화 실험을 실시하였다. 양이온 용출과 탄산화 반응시간은 각각 2시간 및 1시간이었으며 탄산화 효율 증대를 위해 pH는 약 12로 조절하였고 $CO_2$의 부분압은 10 bar이었다. TG 분석결과로부터 탄산화율을 계산한 결과, $H_2SO_4$ 0.5 M과 반응온도 $150^{\circ}C$의 실험 조건에서 약 86%의 고정화율이 관찰되었으나 이 이상의 농도에서는 탄산화율은 급격히 감소하였다. 그러나 $NH_4NO_3$용액을 사용한 결과, 산의 농도가 증가함에 따라 탄산화율도 비례적으로 증가하여 1 M 농도에서 약 93%의 탄산화율이 관찰되었다. 따라서 제강 환원슬래그를 사용한 탄산화반응은 $H_2SO_4$보다는 $NH_4NO_3$용액을 사용할 경우 유리한 것으로 분석되었다. SEM 분석결과, 합성된 아라고나이트는 나무토막 형태(wood piece shape), 둥근형태(round shape), 꽃모양(flower shape)으로 관찰되었으며, 방해석은 결정면이 잘 발달된 능면체형(rhombohedral shape)의 전형적인 형태로 확인되었다.