• Geomechanics and Engineering
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• v.16 no.4
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• pp.375-384
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• 2018

Unconfined compressive strength (UCS) of high plasticity clayey soil mixed with 5 and 10 % of Portland cement and four chemical agents such as sodium hexametaphosphate, aluminum sulfate, sodium carbonate, and sodium silicate with 0, 5, 10, and 20% concentrations was comparatively evaluated. The individual and combined effects of the cement and chemical agents on the UCS of the soil mixture were investigated. The strength of the soil-cement mixture generally increases with increasing the cement content. However, if the chemical agent is added to the mixture, the strength of the cement-chemical agent-soil mixture tends to vary depending on the type and the amount of the chemical agent. At low concentrations of 5% of aluminum sulfate and 5% and 10% of sodium carbonate, the average UCS of the cement-chemical agent-soil mixture slightly increased compared to pure clay due to increasing the flocculation of the clay in the mixture. However, at high concentrations (20%) of all chemical agents, the UCS significantly decreased compared to the pure clay and clay-cement mixtures. In the case of high cement content, the rate of UCS reduction is the highest among all cement-chemical agent-soil mixtures, which is more than three times higher in comparison to the soil-chemical agent mixtures without cement. Therefore, in the mixture with high cement (> 10%), the reduction of the USC is very sensitive when the chemical agent is added.

• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.1
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• pp.8-16
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• 2024

Limestone (CaCO₃, calcium carbonate), which is used as a raw material in the portland cement and steel industry, emits CO₂ through decarbonation by high temperatures in the manufacturing process. To reduce CO₂ emissions by the use of raw materials like limestone, it has been proposed to replace limestone with various industrial by-products that contain CaO but less or none of the carbonated minerals, that cause CO₂ emissions. Loss of Ignition (LOI), Thermogravimetric analysis (TG), and Infrared Spectroscopy (IR) are used to quantitative the amount of CO₂ emission by using these industrial by-products, but CO₂ emissions can be either over or underestimated depending on the characteristics of by-product materials. In this study, we estimated CO₂ contents by LOI, TG, IR and DTG(Differential Thermogravimetric analysis) of calcite(CaCO₃) and samples that contain CO₂ in the form of carbonate and whose weight increases by oxidation at high temperatures. The test results showed for CaCO₃ samples, all test methods have a sufficient level of reliability. On the other hand, for the CO₂ content of the sample whose weight increases at high temperature, LOI and TG did not properly estimate the CO₂ content of the sample, and IR tended to overestimate compared to the predicted value, but the estimated result by DTG was close to the predicted valu e. From these resu lts, in the case of samples that contain less than a few percent of CO₂ and whose weight increases during the temperature that carbonate minerals decompose, estimating the CO₂ content using DTG is a more reasonable way than LOI, TG, and IR.

• Journal of the Korea Safety Management & Science
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• v.2 no.4
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• pp.177-186
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• 2000

The molten carbonate fuel cell has conspicuous features and high potential in being used as an energy converter of various fuels to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at $650^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti has been done in (62+38)mol % (Li+K) $CO_3$ melt at 923K by using. steady state polarization and electrochemical impedance spectroscopy method. It found that the corrosion current of these Febased alloys decreased with increasing Ti content, and this attribute to the formation of $LiCrO_2$ layer at the surface.

• Electrical & Electronic Materials
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• v.9 no.8
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• pp.831-835
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• 1996

The molten carbonate fuel cell has conspicuous features and high potential in being used as an energy converter of various fuels to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650[.deg. C] have many problem. Systematic investigation on corrosion behavior of Fe-based Cr has been done in ($62{\times}38$)mol % (Li+K)$CO_3$ melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. It was found that the corrosion current of these Fe-based alloys decreased with increasing Cr content, and this was attributed to the formation of $LiCrO_2$ layer at the surface .

• Proceedings of the Korea Concrete Institute Conference
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• 1993.10a
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• pp.65-70
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• 1993

The effect of particle size of Al powder, water repellent agent and finishing agent on frost resistance, absorption ratio and structure of micropore was examined to improve the physical properties and durability of ALC. According as the amount added of water repellent agent was increased, frost resistance was improved and absorption ratio was decreased. From one side freezing /thaw test, finishing agent which has a low vapor permeation located the crack at close indoor point of ALC specimen. ALC produced from fine Al powder has a low volume reduction by scalling and a sound appearance after freezing/thawing test and top surface freezing test, The crystal of tobermorite in ALC matrix was converted to calcium carbonate by carbonation which was accelerated with the decreasing of water content. Since the micropore of ALC was filled up by calcium carbonate, void ratio was reduced and crack was detected after complete carbonation.

• Magazine of the Korean Society of Agricultural Engineers
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• v.44 no.6
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• pp.115-123
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• 2002

This study was performed to provide basic data for development and construction of reinforced soil wall that mixed with reinforcements such as calcium carbonate, monofilament fiber. In order to determine proper moisture content and mixing ratio by weight of reinforcement, Poisson's ratio and compressive strength tests for sandy soil had been conducted. Model tests for long-term behavior of reinforced soil wall were carried out to investigate the effect of reinforcement during loads and under static loads. The results of creep and model tests for sandy soil compared with clayey soil. Reinforced sandy soil mixed with calcium carbonate and cement showed brittle rupture by shear but that of mixed with monofilament fiber showed ductile rupture due to the tension force of fiber. It was shown that when age increased, creep strain of reinforced soil under sustained load approached constant values.

• Journal of the Korean Society of Safety
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• v.5 no.3
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• pp.63-68
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• 1990

The effects of various brominated flame retardants were investigated in PC/ABS blend system. The compatibilities between polymers and flame retardants were expected with the solubility parameter using group contribution theory. Tetrabromobisphenol A carbonate oligomer, among the flame retardants in this experiment, has been shown good miscibility for PC and ABS, respectively. But polydibromophenylene oxide and octabromodiphenyl oxide has immiscibility. The flame retardant PC/ABS blends containning tetrabromobisphenol A carbonate oligomer have been exhibited higher mechanical properties, tensile strengths and notch Izod impact strengths, at varlous content of flame retardants, than containning other flame retardants. It could be seen that the trends of mechanical properties for the flame retardant PC/ABS blends have a good concidence with the expectation of compatibility.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.11a
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• pp.67-70
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• 2000

This study was performed to investigate the material behavior of hybrid thermoplastic composites contained glass fiber and calcium carbonate. The composite was prepared with each combination ratio of calcium carbonate, and the content of glass fiber was fixed with 10% by weight. In order to investigate the material behavior for various combination ratio, tension test, flexural test, and impact test were performed. Microscopic observation were conducted to examine the fractured surface of specimen for tension test. And the material behavior of the hybrid thermoplastic composite immersed in salt water with definite time was investigated.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11a
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• pp.157-159
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• 2001

The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650$^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)CO$_3$ melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way, Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a result, the performance of Ni-YSZ anode(47vo1%) was bettor excellent than the others.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.927-933
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• 2000

The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650$^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)CO3 melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way , Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a results, the performance of Ni-YSZ anode(40vo1%) was better excellent than the others.