• Korean Journal of Materials Research
• /
• v.33 no.2
• /
• pp.29-46
• /
• 2023

The electrochemical reduction of carbon dioxide (CO₂) to value-added products is a remarkable approach for mitigating CO₂ emissions caused by the excessive consumption of fossil fuels. However, achieving the electrocatalytic reduction of CO₂ still faces some bottlenecks, including the large overpotential, undesirable selectivity, and slow electron transfer kinetics. Various electrocatalysts including metals, metals oxides, alloys, and single-atom catalysts have been widely researched to suppress HER performance, reduce overpotential and enhance the selectivity of CO₂RR over the last few decades. Among them, single-atom catalysts (SACs) have attracted a great deal of interest because of their advantages over traditional electrocatalysts such as maximized atomic utilization, tunable coordination environments and unique electronic structures. Herein, we discuss the mechanisms involved in the electroreduction of CO₂ to carbon monoxide (CO) and the fundamental concepts related to electrocatalysis. Then, we present an overview of recent advances in the design of high-performance noble and non-noble singleatom catalysts for the CO₂ reduction reaction.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2022.11a
• /
• pp.127-128
• /
• 2022

In order to realize carbon neutrality in the international society, research on supplementary cementitious materials(SCMs) has been actively conducted as a way to reduce carbon dioxide emissions in the cement industry. However, the use of SCMs causes problems of initial hydration delay and strength reduction due to the reduction of tricalcium silicate(C3S) in the cement clinker. Therefore, in this study, the initial hydration and basic characteristics of cement mortar were confirmed by adding a C-S-H based hardening acceleration to blended cement mixed with Portland cement, blast furnace slag, fly ash, and limestone power. As a result of the heat of hydration and compressive strength test, it was confirmed that when hardening acceleration was added, the initial reactivity was high, so the heat of hydration was promoted, and the initial strength was increased. It is considered to be due to C-S-H seeding effect. Therefore, it is judged that the use of C-S-H based hardening acceleration can supplement the problem of initial hydration delay of blended cement in Korea.

• Korean Journal of Soil Science and Fertilizer
• /
• v.47 no.5
• /
• pp.374-380
• /
• 2014

To estimate greenhouse gas (GHG) emission, the inventory of rice cultivation at the farming without agricultural chemicals was established from farmers in Gunsan, Jeonbuk province in 2011~2012. The objectives of this study were to calculate carbon footprint and analyse the major factor of GHGs. To do this, we carried out a sensitivity analysis using the analyzed main factors of GHGs and estimated the mitigation potential of GHGs. Also we suggested agricultural methods to reduce GHGs that can be appled by farmers at this region. At the farming system without agricultural chemicals, carbon footprint of rice production unit of 1 kg was 2.15 kg $CO_2.-eq.kg^{-1}$. Although the amount of carbon dioxide ($CO_2$) emission was the largest among GHGs, methane ($CH_4$) emission had the highest contribution to carbon footprint on rice production system when it was converted to carbon dioxide equivalent ($CO_2-eq.$) multiplied by the global warming potential (GWP). Main source of $CO_2$ emission in the rice farming system without agricultural chemicals was combustion of fossil fuels used by agricultural machinery. Most of the $CH_4$ was emitted during rice cultivation practice and its major emission factor was flooded paddy field in anaerobic condition. Also, most of the $N_2O$ was emitted from rice cultivation process. Major sources of the $N_2O$ emission was application of fertilizer such as compound fertilizer. As a result of sensitivity analysis in energy consumption, diesel had the highest sensitivity among the energy inputs. With the reduction of diesel consumption by 10%, it was estimated that $CO_2$ potential reduction was about 2.0%. With reducing application rate of compound fertilizer by 10%, the potential reduction was calculated that $CO_2$ and $N_2O$ could be reduced by 0.5% and 0.9%, respectively. At the condition of 10% reduction of silicate and compost, $CO_2$ and $CH_4$ could be reduced by 1.5% and 1.6%, respectively. With 8 days more drainage than the ordinary practice, $CH_4$ emission could be reduced by about 4.5%. Drainage and diesel consumption were the main sources having the largest effect on the GHG reduction at the farming system without agricultural chemicals. Based on the above results, we suggest that no-tillage and midsummer drainage could be a method to decrease GHG emissions from rice production system.

• Journal of the Korean Wood Science and Technology
• /
• v.48 no.2
• /
• pp.253-266
• /
• 2020

This study selected three types of agglomerated wood charcoal (Agglomerated wood charcoal with charcoal powder, Carbonized wood briquette, Ignition-type of perforated charcoal) that are in circulation in Korea among fuel-type wood products and analyzed the fuel characteristics, harmful substance content, and emissions of air pollutants generated by combustion. The first results showed that charcoal-grilled carbon, which is the raw material of charcoal, produced higher CO than saw-billed carbon. The second result is that the emission standards of air pollutants generated by the combustion of molded wood coal are not up to the emission standards of nitrogen oxides and sulfur oxides in the entire product, compared with the emission criteria of the atmospheric environment preservation method (based on 2019, carbon monoxide: 200 ppm, nitrogen oxides, 150 ppm sulfur oxides: 100 ppm), but the carbon dioxide moulding and carbon dioxide levels were not up. Based on the analysis of combustion gas generated during combustion derived from this study, future research is needed for comparing with the emission standards of pellets, which are wood products for fuel, among the existing biomass burning standards and for reducing carbon monoxide generated during incomplete combustion of agglomerated wood charcoal.

• Korean Journal of Construction Engineering and Management
• /
• v.13 no.4
• /
• pp.78-88
• /
• 2012

As worldwide efforts to reduce global warming gases, the construction Industry is endeavoring to diminish carbon dioxides emissions. Especially, by introducing the LCA methodology to the industry, A variety of related studies to measure the emission of carbon dioxides have been conducted. However, when the conventional LCA methodology is applied to the construction projects, some limitations have been reported. To overcome the restrictions derived from the industry characteristics, this research suggested the Activity-based LCA model by applying the Activity-based Costing (ABC), which breaks down the whole life cycles into more detailed stages. By implementing the newly developed model, forecasting accuracy of $CO_2$ emission was elevated, and the critical control points on carbon dioxides were established. Through the case study of aluminium curtain-wall system, this research verified the usefulness of the Activity-based LCA.

• Journal of the Korea Institute of Building Construction
• /
• v.13 no.3
• /
• pp.218-226
• /
• 2013

Of construction materials, cement and steel are the representative material that carbon dioxide. to reduce carbon emissions in the use of these materials The purpose of this study is low heat type blended cement, which is manufactured using a amount of cement than ordinary low heat blended cement. Low heat blended cement, mixing ratio of 10%, was investigated hydration properties and adiabatic temperature of concrete. The study in order to activate the reaction mineral admixture, a separate source of CaO and $SO_3$ areneeded. gypsum and lime, it expected amount of cement, low-carbon low-heat blended cement could reduce the hydration heat concrete than currentlyused low heat blended cement.

• KEPCO Journal on Electric Power and Energy
• /
• v.2 no.4
• /
• pp.517-523
• /
• 2016

South Korea is the 8th biggest greenhouse gas emitter in the world due to its phenomenal economic growth based on manufacturing, and it is ranked first among OECD members for the rate of increase in emissions. Thus, the Korea government has voluntarily presented a reduction target and demonstrated global leadership. For the reduction of nation's GHG emission, importance of CCU(Carbon Capture and Utilization) along with CCS(Carbon Capture and Storage) technology development is increased. CCU technology is $CO_2$ utilization technology for the usage of $CO_2$ from flue gas and it can create a new economic value while reducing $CO_2$ emission. Therefore, with continued technology development, the number of application of CCU technology is increasing globally.

• Proceedings of the Korean Society of Crop Science Conference
• /
• 2017.06a
• /
• pp.319-319
• /
• 2017

Methane is the main greenhouse gas released from rice paddy field. Methane from paddy fields accounts for 11 % of the global total methane emission. The global warming potential (GWP) of methane is 25 times more than that of carbon dioxide on a mass basis. It is well known that most effective practice to mitigate methane in paddy is related to the water management during rice growing season and the use of organic matters. This study was conducted to investigate the effects of tillage and cultivation method on methane emission in paddy. Tillage (tillage and no-tillage) and cultivation methods (transplanting and direct seeding) were combined tillage-transplanting (T-T), tillage-wet hill seeding (T-W), tillage-dry seeding (T-D) and no-till dry seeding (NT-D) to evaluate methane mitigation efficiency. Daily methane emission was decreased on seeding treatments (T-W, T-D, NT-D) than transplanting treatment (T-T). Amount of methane emission during rice growing season is highest in T-T ($411.7CH_4\;kg\;ha^{-1}y^{-1}$) and lowest in NT-D treatment (89.7). In T-W and T-D treatments, methane emissions were significantly decreased by 36 and 51 % respectively compared with T-T. Methane emissions were highly correlated with the dry weight of whole rice plant ($R^2=0.62{\sim}0.93$). T-T treatment showed highest $R^2$ (0.93) among the four treatments. Rice grain yields did not significantly differ with the tillage and cultivation methods used. These results suggest that direct seeding practice in rice production could mitigate the methane emissions without loss in grain yield.

• Journal of Advanced Marine Engineering and Technology
• /
• v.33 no.6
• /
• pp.843-851
• /
• 2009

Much work has already been done to control and regulate the worldwide problems caused by climate change, particularly the issues on greenhouse gas (GHG) emissions. Carbon dioxide ($CO_2$), having the highest form of concentration among GHGs composed around 1.0 billion tons of emission, and comprises about 98% of the total emissions from the shipping industry. Korean trade mainly rely on the sea transportation. Korean ship tonnages that was brought about by shipbuilders all over the country, continues to grow annually due to the prevailing demands on goods or material supplies and depicting only a small part of the global maritime activity. Nowadays, new build ships coming from the Korean Shipbuilders are being optimized by hull, structure and appendages design, The operational capability of the propulsion and auxiliary machineries in its maximum capacity to achieve the highest possible efficiencies for energy and onboard power use to mitigate $CO_2$ emissions are continually being done through the help of research and development. In this paper, the energy efficiency design index and anboard power capacity of Korean new build ships have been analyzed with response to data collected by ship types, and its respective fuel consumption in relation to $CO_2$ emission results. In response to climate change convention outcome proposals, the best way for the new build ships to become energy efficient is by lowering its operational speed thru adopting the state of the art diesel propulsion engines, patronizing the best sailing practice to lower the transportation cost on the different sea trade routes also helps in $CO_2$ mitigation.

• Korean Journal of Agricultural Science
• /
• v.51 no.2
• /
• pp.227-238
• /
• 2024

Methane (CH₄) is an important greenhouse gas, with a short-term greenhouse effect 80-fold that of carbon dioxide. Blast furnace slag used as a base ingredient for silicate fertilizer, and contained Fe³⁺, which acts as reduction of CH₄ emissions in flooded rice paddy. This study was evaluated the effects of the silicate fertilizer with different rates of the iron slag on CH₄ emissions and rice growth. In this study, the SF 0.0% was applied with silicate fertilizer containing 0.0% of the iron slag, while the SF 2.5% and SF 5.0% were treated with silicate fertilizer containing 2.5 and 5.0%, respectively. The CH₄ emissions during rice cropping period were assessed using a closed-chamber method and then determined by Gas chromatography. The CH₄ fluxes were reduced by 17% (SF 0.0%), 17% (SF 2.5%), and 8% (SF 5.0%) compared to the treatment with only-inorganic fertilization (control). Conversely, rice grain yield increased by 15 - 30% compared to the control owing to the improvement of soil quality by silicate fertilization. In particular, soil pH, available phosphorus and available silicic acid content were increased with the increase in the iron slag rates from 0.0 to 5.0%. These contributed to a significant increase in rice growth such as 1,000-grains weight and percentage of filled grains. Consequently, these findings were indicated that the application of silicate fertilizer containing 2.5 - 5.0% of iron slag would be the most effective in both CH₄ reduction and rice growth.