• Title/Summary/Keyword: carbon waste

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Corrosion Behavior of Stainless Steel 316 for Carbon Anode Oxide Reduction Application

  • Jeon, Min Ku;Kim, Sung-Wook;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.2
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    • pp.169-177
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    • 2020
  • Here, the stability of stainless steel 316 (SS-316) was investigated to identify its applicability in the oxide reduction process, as a component in related equipment, to produce a complicated gas mixture composed of O2 and Cl2 under an argon (Ar) atmosphere. The effects of the mixed gas composition were investigated at flow rates of 30 mL/min O2, 20 mL/min O2 + 10 mL/min Cl2, 10 mL/min O2 + 20 mL/min Cl2, and 30 mL/min Cl2, each at 600℃, during a constant argon flow rate of 170 mL/min. It was found that the corrosion of SS-316 by the chlorine gas was suppressed by the presence of oxygen, while the reaction proceeded linearly with the reaction time regardless of gas composition. Surface observation results revealed an uneven surface with circular pits in the samples that were fed mixed gases. Thermodynamic calculations proposed the combination of Fe and Ni chlorination reactions as an explanation for this pit formation phenomenon. An exponential increase in the corrosion rate was observed with an increase in the reaction temperature in a range of 300 ~ 600℃ under a flow of 30 mL/min Cl2 + 170 mL/min Ar.

Effects of glass powder on the characteristics of concrete subjected to high temperatures

  • Belouadah, Messaouda;Rahmouni, Zine El Abidine;Tebbal, Nadia
    • Advances in concrete construction
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    • v.6 no.3
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    • pp.311-322
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    • 2018
  • This paper presents an experimental investigation on the performance of concrete with and without glass powder (GP) subjected to elevated temperatures. Mechanical and physicochemical properties of concretes were studied at both ambient and high temperatures. One of the major environmental concerns is disposal or recycling of the waste materials. However, a high volume of the industrial production has generated a considerable amount of waste materials which have a number of adverse impacts on the environment. Further, use of glass or by-products in concrete production has advantages for improving some or all of the concrete properties. The economic incentives and environmental benefits in terms of reduced carbon footprint are also the reason for using wastes in concrete. The occurrence of spalling, compressive strength, mass loss, chemical composition, crystalline phase, and thermal analysis of CPG before and after exposure to various temperatures (20, 200, 400, and $600^{\circ}C$) were comprehensively investigated. The results indicated that, the critical temperature range of CPG was between $400^{\circ}C$ and $600^{\circ}C$.

Numerical Study for the Design of Biogas-fired Low Emission Cyclone Incinerator (바이오 가스 소각용 저공해 사이클론 소각기 개발을 위한 수치 해석적 연구)

  • 전영남;김시욱;백원석
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.5
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    • pp.401-410
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    • 2002
  • Concerns for energy conservation, environmental pollution, and the fact that organic wastes account for a major portion of our waste materials, have created the interest of biogas, which usually contains about 60 to 70 percent methane, 30 to 40 percent carbon dioxide, and other gases, including ammonia, hydrogen sulfide, mercaptans and other noxious gases. Cyclone combustors are used for homing a wide range of fuels such as low calorific value gas, waste water, sludge. coal, etc. The 3-dimensional swirling flow, combustion and emission in a tangential inlet cyclone incinerator under different inlet conditions are simulated using a standard k-s turbulence model and ESCRS (Extended Simple Chemically-Reacting System) model. The commercial code Phoenics Ver.3.4 was used for the present work. The main parameters considered in this work are inlet velocity and air to fuel ratio. The results showed that the change of operating conditions had an influence on the shape and size of recirculation zones, mixture fraction and axial velocity which are important factors for combustion efficiency and emission behavior. The application of this kind of computer program seams to be promising as a potential tool for the optimum design of a cyclone combustor with low emission.

Effective Production of N-Acetyl-$\beta$-glucosamine by Serratia marcescens Using Chitinadceous Waste

  • Kim, Kwang;A. Louise Creagh;Charles A. Haynes
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.3 no.2
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    • pp.71-77
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    • 1998
  • The strain of Serratia marcescens QM B1466 produces selectively large amount of chitinolytic enzymes (about 1mg/L medium). Enzymatic hydrolysis of chitin to N-acetyl-${\beta}$-D-glucosamine (NAG) was performed with a system consisting of two hydrolases (chitinase and chitobiase) produced by optimization of a microbial host consuming chitin particles. For the development of Large-scale biological process for the production of NAG from chitinaceous waste, the selection and optimization of a microbial host, particle size of crab/shrimp chitin sources and initial induction time using chitin as a sole carbon source on chitinase/chitobiase production and NAG production were examined. Crab-shell chitin(1.5%) treated by dilute acid and , ball-milled with a normal diameter less than 250m gave the highest chitinase activity over a 7 days culture. Crude chitinase/ chitobiase solution obtained in a 10 L fed-batch fermentation showed a maximum activities of 23.6 U/mL and 5.1 U/mL, respectively with a feeding time of 3 hrs, near pH 8.5 at 30$^{\circ}C$.

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Performance Analysis of an Oxy-fuel Combustion Power Generation System Based on Waste Heat Recovery: Influence of CO2 Capture (배열회수형 순산소연소 발전시스템의 성능해석: CO2 포집의 영향)

  • Tak, Sang-Hyun;Park, Sung-Ku;Kim, Tong-Seop;Sohn, Jeong-Lak;Lee, Young-Duk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.12
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    • pp.968-976
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    • 2009
  • As the global warming becomes a serious environmental problem, studies of reducing $CO_2$ emission in power generation area are in progress all over the world. One of the carbon capture and storage(CCS) technologies is known as oxy-fuel combustion power generation system. In the oxy-fuel combustion system, the exhaust gas is mainly composed of $CO_2$ and $H_2O$. Thus, high-purity $CO_2$ can be obtained after a proper $H_2O$ removal process. In this paper, an oxy-fuel combustion cycle that recovers the waste heat of a high-temperature fuel cell is analyzed thermodynamically. Variations of characteristics of $CO_2$ and $H_2O$ mixture which is extracted from the condenser and power consumption required to obtain highly-pure $CO_2$ gas were examined according to the variation of the condensing pressure. The influence of the number of compression stages on the power consumption of the $CO_2$ capture process was analyzed, and the overall system performance was also investigated.

Respiratory Activity of Bacteria in Various Concentrations of Glucose (박테리아의 산소소비량에 관한 실험적 고찰)

  • Choi, Hyung-Ja
    • Journal of Preventive Medicine and Public Health
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    • v.10 no.1
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    • pp.134-137
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    • 1977
  • The most efficient method for reducing the organic content of dilute liquid waste is by aerobic-biological treatment. Basically, the organisms responsible for treatment possess the ability to decompose complex organic compounds and to use the energy so liberated for their bodily functions: reproduction, growth, locomotion and so on. That part of organic matter used to produce energy is converted to the essentially stable end products of carbon dioxide, water and ammonia, while the remainder is converted to new cells which can be settled and thus removed from the liquid before the waste is discharged to the receiving body water. Oxygen must be supplied continuously during the aerobic process. In the field of sewage treatment the Warburg respirometer is used mainly for the measurement of the oxygen uptake of samples. In this experiment the Warburg constant volume respirometer was used to determine the oxygen uptake by bacteria in the presence of various glucose concentrations. The rate of oxygen uptake by the bacteria was expressed as the respiratory quotient. The result indicated that the oxygen uptake was proportional to the glucose concentration. The expecting equation of the regression line was Y=7.7+0.12X where Y: respiratory quotient, ${\mu}l.\;O_2$ taken up/mg. dry wt. bacterium/hr. X: concentration of glucose, mg/l

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The Development of Functional $TiO_2$-Biodegradable Plastic Composite Material by Thermal Spraying (용사를 이용한 고기능 $TiO_2$-생분해성 플라스틱 복합재료의 개발)

  • ;;Akira Ohmori;Takahiro Nakatsuji
    • Proceedings of the KWS Conference
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    • 2004.05a
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    • pp.316-318
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    • 2004
  • In recent years, plastic waste has been recognized as a worldwide environmental issue. To solve the disposal problem of the plastic waste, alternative treatment such as the use of biodegradable plastic(polybutylene succinate: PBS) is indeed highly in demand due to its merit of PBS buried in soil decomposed into carbon dioxide and water. In the present study, for the production of further functional PBS with TiO$_2$ as photocatalyst, which shows the decomposition of detrimental organic compound and pollutant under ultraviolet irradiation, we attempted to prepare photocatalytic TiO$_2$ coatings on PBS substrate by HVOF and plasma spraying techniques under various conditions using three kinds of agglomerated powders (P200: 200nm, P30: 30nm, P7: 7nm). The microstructures of coatings were characterized with SEM and XRD analysis, and the photocatalytic efficiency of coatings was evaluated through the photo degradation of gaseous acetaldehyde. Therefore, such functional TiO$_2$-Plastic composite material is expected to considerably contribute to the reduction of aggravated environmental problem.

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A Study on Preparation of Adsorbent from Coffee Grounds and Removal of Trichloroethylene in Water Treatment (커피찌꺼기를 이용한 흡착제 제조 및 수중 Trichloroethylene(TCE) 흡착제거에 관한 연구)

  • 이향숙;강주원;양원호;정문식
    • Journal of Environmental Health Sciences
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    • v.24 no.2
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    • pp.20-31
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    • 1998
  • There is a need for waste recycling. This study was carried out to investigate removal efficiency of TCE in water treatment with adsorbent made from coffee grounds which obtained after extraction of coffee through hot water. The removal of TCE in synthetic Waste water using adsorbents was examined varying dose, concentration and temperature on a laboratory scale. The results were as followed 1. As much as 95% TCE remogal was possible with adsorbent made from coffee grounds at an adsorbent dose over 2.5 g/l under the test conditions. 2. The removal rate of TCE was propotional to weight of adsorbent made from coffee grounds (0.025, 0.1, 0.3, 0.5 g). 3. In the effect of temperature, as temperature of wastewater was high, the rate of removal was increased. 4. Iodine number (865 mg/g) of adsorbent made from coffee grounds was not higher than that (1123 mg/g) of adsorbent made from coconut. But, in considering adsorption capacity, Iodine number was inapplicable to adsorbent made from coffee grounds. 5. Generally, Freundlich's equation applies to adsorption in wastewater. In case of TCE, slope (1/n) was 0.83, 1.06 and intercept (k) was 456.18, 405.19 at 150, 300 ppb respectively (average r=0.904, 0.933).

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Strength enhancement of concrete incorporating alccofine and SNF based admixture

  • Reddy, Panga Narasimha;Jindal, Bharat Bhushan;Kavyateja, Bode Venkata;Reddy, A. Narender
    • Advances in concrete construction
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    • v.9 no.4
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    • pp.345-354
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    • 2020
  • Cement is the most significant component in concrete. Large scale manufacturing of cement consumes more energy and release harmful products (Carbon dioxide) into the atmosphere that adversely affect the environment and depletes the natural resources. A lot of research is going on in globally concentrating on the recycling and reuse of waste materials from many industries. A major share of research is focused on finding cementitious materials alternatives to ordinary Portland cement. Many industrial waste by-products such as quartz powder, metakaolin, ground granulated blast furnace slag, silica fume, and fly ash etc. are under investigations for replacement of cement in concrete to minimize greenhouse gases and improve the sustainable construction. In current research, the effects of a new generation, ultra-fine material i.e., alccofine which is obtained from ground granulated blast furnace slag are studied as partial replacement by 25% and with varying amounts of sulfonated naphthalene formaldehyde (i.e., 0.3%, 0.35% and 0.40%) on mechanical, water absorption, thermal and microstructural properties of concrete. The results showed moderate improvement in all concrete properties. Addition of SNF with combination of alccofine showed a significant enhancement in fresh, hardened properties and water absorption test as well as thermal and microstructural properties of concrete.

Biological Treatment of Two-Phase Olive Mill Wastewater (TPOMW, alpeorujo): Polyhydroxyalkanoates (PHAs) Production by Azotobacter Strains

  • Cerrone, Federico;Sanchez-Peinado, Maria Del Mar;Juarez-Jimenez, Belen;Gonzalez-Lopez, Jesus;Pozo, Clementina
    • Journal of Microbiology and Biotechnology
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    • v.20 no.3
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    • pp.594-601
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    • 2010
  • Azotobacter chroococcum H23 (CECT 4435), Azotobacter vinelandii UWD, and Azotobacter vinelandii (ATCC 12837), members of the family Pseudomonadaceae, were used to evaluate their capacity to grow and accumulate polyhydroxyalkanoates (PHAs) using two-phase olive mill wastewater (TPOMW, alpeorujo) diluted at different concentrations as the sole carbon source. The PHAs amounts (g/l) increased clearly when the TPOMW samples were previously digested under anaerobic conditions. The MNR analysis demonstrated that the bacterial strains formed only homopolymers containing $\beta$-hydroxybutyrate, either when grown in diluted TPOMW medium or diluted anaerobically digested TPOMW medium. COD values of the diluted anaerobically digested waste were measured before and after the aerobic PHA-storing phase, and a clear reduction (72%) was recorded after 72 h of incubation. The results obtained in this study suggest the perspectives for using these bacterial strains to produce PHAs from TPOMW, and in parallel, contribute efficiently to the bioremediation of this waste. This fact seems essential if bioplastics are to become competitive products.