• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.723-730
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• 2017

The batch experiments by response surface methodology (RSM) have been applied to investigate the influences of operating parameters such as temperature, initial concentration, contact time and adsorbent dosage on 2,4-dichlorophenol (2,4-DCP) adsorption with an activated carbon prepared from waste citrus peel (WCAC). Regression equation formulated for the 2,4-DCP adsorption was represented as a function of response variables. Adequacy of the model was tested by the correlation between experimental and predicted values of the response. A fairly high value of $R^2$ (0.9921) indicated that most of the data variation was explained by the regression model. The significance of independent variables and their interactions were tested by the analysis of variance (ANOVA) and t-test statistics. These results showed that the model used to fit response variables was significant and adequate to represent the relationship between the response and the independent variables. The kinetics and isotherm experiment data can be well described with the pseudo-second order model and the Langmuir isotherm model, respectively. The maximum adsorption capacity of 2,4-DCP on WCAC calculated from the Langmuir isotherm model was 345.49 mg/g. The rate controlling mechanism study revealed that film diffusion and intraparticle diffusion were simultaneously occurring during the adsorption process. The thermodynamic parameters indicated that the adsorption reaction of 2,4-DCP on WCAC was an endothermic and spontaneous process.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.14 no.2
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• pp.91-100
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• 2016

The neutron activation inventories in reactor vessel and its internals, and bio-shield of a PWR nuclear power plant were calculated to evaluate the effect of impurity elements contained in the structural materials on the activation inventory. Carbon steel is, in this work, used as the reactor vessel material, stainless steel as the reactor vessel internals, and ordinary concrete as the bio-shield. For stainless steel and carbon steel, one kind of impurity concentration was employed, and for ordinary concrete five kinds were employed in this study using MCNP5 and FISPACT for the calculation of neutron flux and activation inventory, respectively. As the results, specific activities for the cases with impurity elements were calculated to be more than twice than those for the cases without impurity elements in stainless and carbon steel. Especially, the specific activity for the concrete material with impurity elements was calculated to be 30 times higher than that without impurity. Neutron induced reactions and activation inventories in each material were also investigated, and it is noted that major radioactive nuclide in steel material is Co-60 from cobalt impurity element, and, in concrete material, Co-60 and Eu-152 from cobalt and europium impurity elements, respectively. The results of this study can be used for nuclear decommissioning plan during activation inventory assessment and regulation, and it is expected to be used as a reference in the design phase of nuclear power plant, considering the decommissioning of nuclear power plants or nuclear facilities.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.15 no.3
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• pp.207-218
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• 2017

In this study, pitch-based activated carbon fibers (ACFs) were modified with pyrolysis fuel oil (PFO). Carbonized ACF samples were activated at $850^{\circ}C$, $880^{\circ}C$ and $900^{\circ}C$. A scanning electron microscope (SEM) and a BET surface area apparatus were employed to evaluate the indoor radon removal of each sample. Among three samples, the BET surface area and micropore area of ACF880 recorded the highest value with $1,420m^2{\cdot}g^{-1}$ and $1,270m^2{\cdot}g^{-1}$. Moreover, ACF880 had the lowest external surface area and BJH adsorption cumulative surface area of pores with $151m^2{\cdot}g^{-1}$ and $35.5m^2{\cdot}g^{-1}$. This indicates that satisfactory surface area depends on the appropriate temperature. With the above scope, ACF880 also achieved the highest radon absorption rate and speed in comparison to other samples. Therefore, we suggest that the optimum activation temperature for PFO containing ACFs is $880^{\circ}C$ for effective indoor radon adsorption.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.7
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• pp.565-572
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• 2009

Greenhouse gas(GHG) inventories and basic strategies for Jeonbuk regional government were established to reduce greenhouse gas emissions. The method to construct GHG inventories of Jeonbuk followed the 'Revised IPCC 1996 Guidelines'which was used for the 'Third National Communication of the Republic of Korea under UNFCCC'. Korean government could use primary energy consumption for the energy industries section in the national GHG inventories. However, regional governments should use secondary energy consumption (included electricity consumption) for the energy industries section for their GHG inventories because they could not control the emission of energy transformation section. In the result of Jeonbuk GHG inventories in 2006, carbon dioxide($CO_2$) emissions from fuel combustion covered 87.1% of total emissions. Methane($CH_4$), carbon dioxide($CO_2$) from other sections, nitrous oxide($N_2O$) and F-gas(HFCs, PFCs, $SF_6$) accounted for 8.1, 2.2, 1.6 and 1.0% of total emissions, respectively. The sectional emission decreased in the order of the energy(88.0%), agriculture(7.6%), waste(2.3%) and industrial processes(2.1%) section. The energy industries section that contained electricity consumption was the most dominant emission source in the energy section. F-gas consumption, rice cultivation and waste incineration were main emission sources in the industrial processes, agriculture and waste section, respectively. In this study, basic directions of each section were established by the results of Jeonbuk GHG inventories in 2006.

• Journal of the Korea Organic Resources Recycling Association
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• v.10 no.4
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• pp.103-111
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• 2002

The purpose of this study is to investigate influence of NaCl precisely in recycling process of food waste and in places where food waste compost is used, because NaCl with food waste has caused concerns of adverse effects in the process of food waste recycling and in plates where final products is used. The influence of NaCl in composting was measured through temperature, concentration of carbon dioxide ($CO_2$) and pH. NaCl didn't cause bad effects until 1%(wet base) of NaCl concentration for composting, showed adverse effects gradually at 2% and 3% and affected composting deeply at 6%. The influence of NaCl in composting was insignificant until 3% of NaCl concentration but decomposing efficiency of organic compounds was interfered with more than 3%. NaCl concentration has to be maintained less than 1%(wet base) to minimize adverse effects of NaCl in composting however NaCl concentration with food waste used in real composting facilities is so lower than 1 %(wet base) that the bad influence in food waste composting is slight. Compost(final product) was collected from real food waste recycling facilities in A city, S city, K-Gu and S-Gu and controlled NaCl concentration artificially such as 0.5%, 0.8%, 1.2%, 1.6%, 2.0%, 2.5% and 3.0% to investigate influence of NaCl on growth of plants. In results of plant test and pot experiment, according to quality of compost sampled, the influence of NaCl is insufficient until 3% and bad effects appeared clearly more than 3%. The bad effects showed less than 3% because compost sampled was not stabilized fully.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.205.2-205.2
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• 2010

Optimum operation conditions of low-NOx MILD combustion for gaseous and solid fuels have been investigated by experimental and computer simulation. Loop reactor type MILD combustor without air pre-heater has been used in the present work. The results show that the balance of injection velocities of fuel and surrounding air is major factor for maintaining MILD combustion mode. Temperature difference between lower and upper part can be reduced less than 20 degree of Celsius. It was found that NOx emission in MILD combustion also can be remarkably reduced to more than 85% in comparison with conventional premixed combustion, and reduced to more than 50% in case of nitrogen and carbon dioxide carrying dried waste water sludge and pulverized coal in comparison with the same of air carrying. It was also found that carbon monoxide emission increase was not appeared at the time of changeover to MILD combustion mode from premixed or air carrying combustion at optimum operation condition.

• Journal of the Korean Ceramic Society
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• v.53 no.4
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• pp.429-434
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• 2016

Here, we introduce a means of utilizing waste oyster shells which were obtained from temporary storage near coastal workplaces as $CO_2$ adsorbents. The calcined CaO can be easily dissociated to $Ca^{2+}$ cation and $CO_3{^{2-}}$ anion by hydrolysis and gas-liquid carbonation reaction and converted to precipitated calcium carbonate (PCC) in algae-containing water. The calcium hydroxide and carbonation combination in algae-containing water significantly contributed to improving water quality which is very dependent on the addition amount of calcined powders.

• Journal of Environmental Science International
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• v.22 no.4
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• pp.425-433
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• 2013

A mass balance of process was calculated by using the analysis of basic unit and environmental assessment of all the processes of Busan fashion color industry cooperative that operates a combined heat and power plant and a bio treatment plant. The mass balance for the combined heat and power plant was done, based on boiler and water treatment processes while each unit reactor was used for the bio treatment plant. From the results above, a resource recycle network, a treatment flowchart for food waste water/wastewater treatment and a carbon reduction program were established.

• Journal of environmental and Sanitary engineering
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• v.19 no.3 s.53
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• pp.31-39
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• 2004

In order to reduce the pollution load from the livestock farms and to improve the water quality of the effluent in livestock wastewater, the electrolysis system is introduced. For the selection of optimal electrode, various combination of electrodes such as carbon, Al and Fe were examined. In this study, electrode material, electrolyte concentration, electrode distance, current density, and pH value were found to have significant effect on both pollutant removal efficiency and current efficiency in electrochemical oxidation process. After electrolysis for 90 min with carbon/Al, it was observed that COD, T-N, T-P and $NH_4^+-N$ of livestock waste-water were removed with $80\%,\;61\%,\;81\%\;and\;87\%$, respectively.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.821-824
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• 2009

LFG-MGT CHP system development project with $CO_2$ enrichment in greenhouses was introduced. LFG is produced from the anaerobic digestion of landfilled waste and it has been utilized for power/heat generation since it contains around 50% of $CH_4$. Utilization of LFG from small scale landfill is also needed as well as large scale landfill. However, due to economy of scale, it is very difficult to develop business model. In this context, combining CHP system with greenhouses is considered as feasible option for LFG utilization. LFG-MGT CHP system with $CO_2$ fixation in greenhouses has been derived as an active greenhouse gas reduction strategy, The focus of the system is beyond carbon neutral LFG utilization to neutral carbon absorption. The system is feasible in terms of direct and indirect $CO_2$ emission reduction with more economical way.