• 제목/요약/키워드: carbon waste

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A Novel Technology for Recycling Waste Dry-battery

  • Chen, Weiliang;Chai, Liyuan;Min, Xiaobo;Zhang, Chuanfu
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.249-251
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    • 2001
  • A novel technology for recycling valuable metals contained in waste dry-battery by vacuum metallurgy was devised by theoretical analysis. On the condition of the total chamber pressure of 1.013$\upsilon$10$^1$Pa, Hg, Cd and Zn are distilled in the temperature range of 773~973K, Pb is volatilized in the range of 1173~1273K while Mn, Cu, Fe and C are remained in residual. MnO$_2$and ZnO are reduced by carbon in waste dry-battery in 773~1273K. Pure metals including Zn, Cd, Hg and Pb can be recovered respectively from their mixed vapor by fractional condensation. Metal Cu and MnO$_2$can be obtained from the residual by hydrometallguical method. The technology can eliminate the pollution of Cd, Hg and Pb to environment.

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DEVELOPMENT OF ANODIC STRIPPING VOLTAMMETRY FOR THE DETERMINATION OF PALLADIUM IN HIGH LEVEL NUCLEAR WASTE

  • Bhardwaj, T.K.;Sharma, H.S.;Jain, P.C.;Aggarwal, S.K.
    • Nuclear Engineering and Technology
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    • v.44 no.8
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    • pp.939-944
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    • 2012
  • Deposition potential, deposition time, square wave frequency, rotation speed of the rotating disc electrode, and palladium concentration were studied on a Glassy Carbon Electrode (GCE) in 0.01M HCl for the determination of palladium in High Level Nuclear Waste (HLNW) by anodic stripping voltammetry. Experimental conditions were optimized for the determination of palladium at two different, $10^{-8}$ and $10^{-7}M$, levels. Error and standard deviation of this method were under 1% for all palladium standard solutions. The developed technique was successfully applied as a subsidiary method for the determination of palladium in simulated high level nuclear waste with very good precision and high accuracy (under 1 % error and standard deviation).

Energy recovery characteristics by combustion of pulverized fuel made from food waste (음식물쓰레기로부터 제조한 분체연료의 연소에 의한 에너지회수 특성)

  • Kim, Sang-Guk;Kwon, Hyo-Lee
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.329-330
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    • 2009
  • Food waste contains almost no heavy metals and high fuel ratio 0.14-0.17 that makes it a good candidate for solid fuel. Thermogravimetric analysis showed that volatile matter volatilizes at $200-400^{\circ}C$, and ignition temperature is $460^{\circ}C$. Combustion efficiency measured from energy balance before and after combustion was over 99%. Pulverized fuel made from food waste is a new and renewable energy which contribute to low carbon green economic growth.

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Feasibility Study on the Development of Alternative Methods for the Treatment of TRISO Fuels

  • Lee Jong-Hyeon;Shim Joon-Bo;Ahn Byung-Gil;Kwon Sang-Woon;Kim Eung-Ho
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.352-361
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    • 2005
  • In this study, conventional head-end processes of spent TRISO fuel have been reviewed to develope more effective treatment methods. The main concerns in the TRISO treatment are to effectively separate the carbon and SiC contained in the TRISO particles. The crush-burn scheme which was considered in the early stages of the development has been replaced by the crush-leach process because of $^{14}C$ problems as a second waste during the process. However there are still many obstacles to overcome in the reported processes. Hence, innovative thermomechanical concepts to breach the coating layers of the TRISO particle with a minimized amount of second waste are proposed in this paper and their principles are described in detail.

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A Study of Microwave Waste Tire Pyrolysis in a Batch Reactor (회분식 반응기에서의 마이크로파 폐타이어 열분해 연구)

  • KIM, SEONG-SOO
    • Journal of Hydrogen and New Energy
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    • v.28 no.5
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    • pp.577-583
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    • 2017
  • A series of microwave waste tire pyrolysis experiments were conducted using a lab-scale batch reactor to delineate the effects of microwave ouput power on the pyrolysis behavior of waste tire. As results of experiments, it was found that as the microwave output power was increased from 1.22 kW/kg to 2.26 kW/kg, the reaction temperature and oil yield increased significantly and the required time and microwave power consumption decreased remarkably, respectively. With increased power consumption, the content of the fixed carbon of pyrolysis residue increased.

Development on Integrated Pyrolysis Cogeneration System for Waste Tire Recycling Treatment (폐타이어 재활용 처리를 위한 열분해 열병합 복합공정기술개발)

  • Kim, Seong-Yeon;Ha, Man-Yeong
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.1990-1995
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    • 2008
  • The thermochemical recycling of waste tires by pyrolysis is studied to recover the value added three by-products; a pyrolytic carbon black, a pyrolytic oil, and a non-condensable gas. The exhausted energy from pyrolysis of waste tires is converted for electricity power and process steam in cogeneration system. The characteristics of the pyrolysis recovered by-products as alternative energy resource are investigated with the design of a demonstration and a commercialization plant including cogeneration system, as called integrated pyrolysis cogeneration system.

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Thermal characteristics of spent activated carbon generated from air cleaning units in korean nuclear power plants

  • So, Ji-Yang;Cho, Hang-Rae
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.873-880
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    • 2017
  • To identify the feasibility of disposing of spent activated carbon as a clearance level waste, we performed characterization of radioactive pollution for spent activated carbon through radioisotope analysis; results showed that the C-14 concentrations of about half of the spent activated carbon samples taken from Korean NPPs exceeded the clearance level limit. In this situation, we selected thermal treatment technology to remove C-14 and analyzed the moisture content and thermal characteristics. The results of the moisture content analysis showed that the moisture content of the spent activated carbon is in the range of 1.2-23.9 wt% depending on the operation and storage conditions. The results of TGA indicated that most of the spent activated carbon lost weight in 3 temperature ranges. Through py-GC/MS analysis based on the result of TGA, we found that activated carbon loses weight rapidly with moisture desorption reaching to $100^{\circ}C$ and desorbs various organic and inorganic carbon compounds reaching to $200^{\circ}C$. The result of pyrolysis analysis showed that the experiment of C-14 desorption using thermal treatment technology requires at least 3 steps of heat treatment, including a heat treatment at high temperature over $850^{\circ}C$, in order to reduce the C-14 concentration below the clearance level.

Selective Adsorption of Uranium Ionsin High Concentration of Chemical Salts

  • Jung, Chong-Hun;Won, Hui-Jun;Kim, Gye-Nam;Park, Wangkyu;Wonzin Oh
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.119-120
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    • 2004
  • A study on the selective adsorption of uranium(VI) from a high concentration of chemical salts has tern peformed to investigate the uranium removal mechanisms and the application conditions of the electrosorption technique using the activated carbon fiber(ACF) as a good conductive electrosorption adsorbent. Electrosorption test were carried out using an electrochemical cell.(omitted)

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Production of Gardenia Blue Color from Gardenia Waste by the Bacillus subtilis (Bacillus substilits에 의한 치자황색소 부산물로부터 치자청색소의 생산)

  • 김희구;이상준
    • The Korean Journal of Food And Nutrition
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    • v.11 no.6
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    • pp.606-611
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    • 1998
  • For waste recyle, we were investigated on Gardenia blue color production using Gardenia by-product by Bacillus subtilits. Optimum conditions for producing blue pigment were found to be 30$^{\circ}C$, initial pH 6.5, glucose as a carbon source 3% and yeast extract as a nitrogen source 0.5%, respectively. Optimum conditions for fermentor culture were agitation speed 400rpm, aeration 2 vvm and inoculum 5%. The optimum perculture time for inoculum was 20 hrs for blue pigment production.

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Treatability Tests for the Bioremediation of Unsanitary Landfill Waste Soils

  • Park, Sung-Chan;Lee, Young-Hee;Oh, Young-Sook
    • Journal of Microbiology
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    • v.41 no.2
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    • pp.169-173
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    • 2003
  • A treatability investigation was conducted to determine if landfarming would be effective for the remediation of unsanitary landfill waste soils. Calculations based on biodegradable organic carbon contents and initial CO$_2$ evolution rates revealed that landfarming has a high potential for landfill site remediation and that the optimum strategy for bioremediation is site-specific.