• 멤브레인
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• 제32권5호
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• pp.348-356
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• 2022

바이오산업의 발전으로 의약품, 식품 등의 생산 과정의 분리/정제 공정에 사용되어 왔던 기존의 컬럼 크로마토그래피를 대체하여 더 높은 처리효율을 갖는 막 크로마토그래피가 부상하고 있다. 본 연구에서는 서로 다른 기공 크기의 두 가지 상용 셀룰로오스 아세테이트(Cellulose acetate, CA) 분리막을 탈아세틸화 과정을 통해, 리간드의 개질이 용이한 다공성 재생 셀룰로오스 지지체를(Regenerated cellulose, RC) 제조하였다. 음이온 교환능을 부여하고자 grafting을 수행하였으며, 구체적으로는 UV 중합법을 통해 4차 암모늄을 포함하는 음이온 교환 리간드(MAPTAC)를 부착하여 음이온 교환용 흡착막을 제조하였다. 단백질 흡착 용량은 정적 흡착 용량(Static binding capacity, SBC)시험을 통해 총 단백질 흡착 용량을 측정했고, 동적 흡착 용량(Dynamic binding capacity, DBC)을 측정하여 상용막과 비교 평가하였다. 성능 평가 결과 단백질 흡착량은 넓은 표면적에 의해 리간드 밀도가 높은, 기공 크기가 작은 순서로 높게 측정되었고, 상용 CA분리막을 탈아세틸화하고 리간드를 부착시킨 분리막(RC 0.8 + MAPTAC 43.69 mg/ml, RC 3.0 + MAPTAC 36.33 mg/ml)이 상용 막 크로마토그래피 제품(28.38 mg/ml) 대비 높은 흡착 용량을 보였다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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• pp.105-108
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• 2002

Materials, matrices mixed with various kinds of conductive or magnetic powder, such as ferrite, have been used as the electromagnetic wave absorbing ones, so called RAM(radar absorbing material). The structure that does not only have electromagnetic waves absorbing property like RAM but also supports loads is called RAS(radar absorbing structure). One of the existing manufacturing process of RAS is to compound with conductive powders the glass fiber-reinforced composite with good permeability and the ability to support loads. The process, however, causes a number of problems, such as the degradation in the mechanical properties of the composite, especially, interlamina shear strength. In this study, mechanical properties of glass fabric/epoxy composite containing 7wt% carbon black powders were measured and compared with pure glass fabric/epoxy composites.

• 한국관개배수논문집
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• 제21권1호
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• pp.17-31
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• 2014

Excessive emission of greenhouse gases from fossil fuels usage has become a major cause of climate change. As an alternative to reduce the greenhouse gas emission, renewable energy has been highlighted around the world and UK government also established the Climate Change Act 2008 and policies for response the climate change. Those of them has been supporting many practical actions for reducing greenhouse gas emission and community energy projects is representative program to supporting security of energy supply and helping the country to reduce its carbon footprint. Rural Community Energy Fund (RCEF) which is one of community energy projects supports rural communities to develop renewable energy projects which provide economic and social benefits to the community. The review of UK's renewable energy policies and action plan can be useful to promote in Korea policies for becoming low-carbon society.

• Structural Engineering and Mechanics
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• 제13권1호
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• pp.75-90
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• 2002

Many existing concrete structures suffer from low quality of concrete and inadequate confinement reinforcement. These deficiencies cause low strength and ductility. Wrapping concrete by carbon fiber reinforced polymer (CFRP) composite sheets enhances compressive strength and deformability. In this study, the effects of the thickness of the CFRP composite wraps on the behavior of concrete are investigated experimentally. Both monotonic and repeated compressive loads are considered during the tests, which are carried out on strengthened undamaged specimens, as well as the specimens, which were tested and damaged priorly and strengthened after repairing. The experimental data shows that, external confinement of concrete by CFRP composite sheets improves both compressive strength and deformability of concrete significantly as a function of the thickness of the CFRP composite wraps around concrete. Empirical equations are also proposed for compressive strength and ultimate axial deformation of FRP composite wrapped concrete. Test results available in the literature, as well as the experimental results presented in this paper, are compared with the analytical results predicted by the proposed equations.

• International Journal of Concrete Structures and Materials
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• 제11권1호
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• pp.1-16
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• 2017

The compression or tension-controlled failure mode of concrete beams prestressed with unbonded FRP tendons is governed by the relative amount of prestressing tendon to the balanced one. Explicit assessment to determine the balanced reinforcement ratio of a beam with unbonded tendons (${\rho}^U_{pfb}$) is difficult because it requires a priori knowledge of the deformed beam geometry in order to evaluate the unbonded tendon strain. In this study, a theoretical evaluation of ${\rho}^U_{pfb}$ is presented based on a concept of three equivalent rectangular curvature blocks for simply supported concrete beams internally prestressed with unbonded carbon-fiber-reinforced polymer (CFRP) tendons. The equivalent curvature blocks were iteratively refined to closely simulate beam rotations at the supports, mid-span beam deflection, and member-dependent strain of the unbonded tendon at the ultimate state. The model was verified by comparing its predictions with the test results. Parametric studies were performed to examine the effects of various parameters on ${\rho}^U_{pfb}$.

• Bulletin of the Korean Chemical Society
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• 제20권1호
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• pp.89-94
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• 1999

Carbon dioxide reforming of methane on Ni/γ-Al2O3 catalyst was studied. A new 10 wt% Ni/γ-Al2O3 catalyst prepared by the liquid phase oxidation method (L10O) exhibited much higher activity as well as resistances to both sintering and coke formation during the reaction than the catalyst prepared by the conventional impregnation method (D10). The electrically strong attractive interaction between nickel and support during the liquid phase oxidation process and the resultant high nickel dispersion made the L10 have superior activity and stability to the D10. To elucidate the results, the experiments with nickel catalysts on the other supports as well as 7-AI203 were performed. The effect of sodium as a promoter was also studied.

• Advances in concrete construction
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• 제13권6호
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• pp.451-459
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• 2022

In present study, the nonlocal Flügge shell model based is utilized to investigate the vibration characteristics of armchair and chiral single-walled carbon nanotubes with impact of small-scale effect subjected to two boundary supports. The wave propagation approach is employed to determine eigen frequencies for armchair and chiral tubes. The fundamental frequencies scrutinized with assorted aspect ratios by varying the bending rigidity. The raised in value of nonlocal parameter reduces the corresponding fundamental frequency. It is investigated with higher aspect ratio, the boundary conditions have a momentous influence on vibration of CNT. It is concluded that frequencies would increase by increasing of the bending rigidity. Solutions of the frequency equation have determined by writing in MATLAB coding.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 춘계학술대회
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• pp.200-203
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• 2007

Parametric investigation of the polyol process for the preparation of carbon supported Pt nano particles as catalysts for fuel cells was carried out. It was found that the concentration of glycolate anion, which is a function of pH, plays an important role in controlling Pt particle size and loading on carbon. It was observed that Pt loading decreased with increasing alkalinity of the solution. As evidenced by zeta potential measurement, this was mainly due to poor adsorption or repulsive forces between the metal colloids and the supports. In order to modify the conventional polyol process, the effect of the gas purging conditions on the characteristics of Pt/C was examined. By the optimization of the gas environment during the reaction, it was possible to obtain high loading of 39.5wt% with a 2.8 nm size of Pt particle. From the single cell test, it was found that operating in ambient $O_{2}$ at 70oC can deliver high performance of more than 0.6 V at 1.44 A $cm^{-2}$.

• 한국분말재료학회지
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• 제22권2호
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• pp.116-121
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• 2015

$WS_2$-W-WC embedded carbon nanofiber composites were fabricated by using electrospinning method for use in high-performance supercapacitors. In order to obtain optimum electrochemical properties for supercapacitors, $WS_2$ nanoparticles were used as precursors and the amounts of $WS_2$ precursors were controlled to 4 wt% (sample A) and 8 wt% (sample B). The morphological, structural, and chemical properties of all samples were investigated by means of field emission photoelectron spectroscopy, transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. These results demonstrated that the embedded phases of samples A and B were changed from $WS_2$ to $WS_2$-W-WC through carbothermal reaction during carbonization process. In particular, sample B presented high specific capacitance (~119.7 F/g at 5 mV/s), good high-rate capacitance (~60.5%), and superb cycleability. The enhanced electrochemical properties of sample B were explained by the synergistic effect of the using 1-D structure supports, increase of specific surface area, and improved conductivity from formation of W and WC phases.

• Advances in nano research
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• 제9권4호
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• pp.251-261
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• 2020

In this article, vibration attributes of single walled carbon nanotubes based on Galerkin's method have been investigated. The influence of power law index subjected to different end supports has been overtly examined. Application of the Hamilton's variational principal leads to the formation of partial differential equations. The effects of different physical and material parameters on the fundamental frequencies are investigated for armchair and zigzag carbon nanotubes with clamped-clamped, simply supported and clamped-free boundary conditions. By using volume fraction for power law index, the fundamental natural frequency spectra for two forms of Single-Walled Carbon Nanotubes (SWCNTs) are calculated. The influence of frequencies against length-to-diameter ratios with varying power law index are investigated in detail for these tubes. MATLAB software package has been utilized for extracting tube frequency spectra. The obtained results are confirmed by comparing with available literature.