• 제목/요약/키워드: carbon nanotube(CNT)

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전자빔을 자체 집속하는 탄소나노튜브 삼전극 전계방출소자의 시뮬레이션 (Simulations Of a Self-focusing Carbon Nanotube Triode Field Emission Device)

  • 이태동;류성룡;변창우;김영길;고남제;천현태;박종원;고성우
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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    • pp.538-541
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    • 2002
  • 탄소나노튜브 (CNT)가 도포된 평면형 에미터와 원형 개구의 게이트 전극을 가지는 삼전극 전계방출 소자의 전계방출 특성을 시뮬레이션하였다. 체계적인 시뮬레이션을 위해 소자 내 전위의 공간적 분포 특정을 결정하는 전계형상인자 $\gamma$를 정의하고 이 값에 따른 전위분포의 특성과 방출 전자의 궤적을 계산하였다. 계산 결과$\gamma$ > 1 인 전압조건에서는 에미터의 가운데를 중심으로 강한 전자방출이 발생하고 전자빔이 구조의 축 방향으로 자체 집속됨을 알 수 있었다. 이렇게 되면 에미터와 게이트의 정렬이 전혀 필요하지 않게 되며 또한 별도의 전자집속회로 없이도 에미터와 양극에 있는 형광체가 1:1 로 대응하는 획기적인 디스플레이 구조를 가능하게 해 준다 적정 전압조건에서 CNT의 전계강화인자 $\beta$의 변화에 따른 총 전류를 계산한 결과,$\beta$ >3000인 CNT를 사용할 경우 실제 소자로서 구현이 가능함을 확인하였다.

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이성분 나노유체 (NH3/H2O + 나노입자)의 열전달 및 흡수성능 촉진실험 (Experiment on Heat Transfer and Absorption Performance Enhancement for Binary Nanofluids (NH3/H2O + Nano-Particles))

  • 이진기;정청우;강용태
    • 대한기계학회논문집B
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    • 제32권9호
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    • pp.669-675
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    • 2008
  • The objectives of this paper are to examine the effect of nano-particles on the pool type absorption heat transfer enhancement and to find the optimal conditions to design a highly effective compact absorber for ammonia/water absorption system. The effect of $Al_2O_3$ nano-particles and carbon nanotube(CNT) on the absorption performance is studied experimentally. The experimental ranges of the key parameters are 20% of ammonia concentration, $0{\sim}0.08\;vol%$ (volume fraction) of CNT particles, and $0{\sim}0.06 \;vol%$ of $Al_2O_3$ nano-particles. For the ammonia/water nanofluids, the heat transfer rate and absorption rate with 0.02 vol% $Al_2O_3$ nano-particles were found to be 29% and 18% higher than those without nano-particles, respectively. It is recommended that the concentration of 0.02 vol% of $Al_2O_3$ nano-particles be the best candidate for ammonia/water absorption performance enhancement.

Comparison of Catalytic Activity for Methanol Electrooxidation Between Pt/PPy/CNT and Pt/C

  • Lee, C.G.;Baek, J.S.;Seo, D.J.;Park, J.H.;Chun, K.Y.
    • 전기화학회지
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    • 제13권4호
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    • pp.240-245
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    • 2010
  • This work explored the catalytic effect of Pt in multi-wall carbon nanotube and poly-pyrrole conductive polymer electrocatalysts (Pt/PPy/MWCNT). A home-made Pt/PPy/MWCNT catalyst was first evaluated by comparing its electrochemical active surface area (ESA) with E-Tek commercial catalysts by cyclic voltammetry in $H_2SO_4$ solution. Then, the methanol oxidation currents of Pt/PPy/MWCNT and the hydrogen peaks in $H_2SO_4$ solution were serially measured with microporous electrode. This provided the current density of methanol oxidation based on the ESA, allowing a quantitative comparison of catalytic activity. The current densities were also measured for Pt/C catalysts of E-Tek and Tanaka Precious Metal Co. The current densities for the different catalysts were similar, implying that catalytic activity depended directly on the ESA rather than charge transfer or electronic conductivity.

Biologically-Inspired Selective and Sensitive Trinitrotoluene Sensors Using Conjugated Lipid-like Polymer Nanocoatings for CNT-FET Sensors

  • Jaworski, Justyn;Kim, Tae-Hyun;Yokoyama, Keisuke;Chung, Woo-Jae;Wang, Eddie;Lee, Byung-Yang;Hong, Seung-Hun;Majumdar, Arun;Lee, Seung-Wuk;Kwon, Ki-Young
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.495-495
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    • 2011
  • Miniaturized sensors capable of both sensitive and selective real-time monitoring of target analytes are tremendously valuable for various applications ranging from hazard detection to medical diagnostics. The wide-spread use of such sensors is currently limited due to insufficient selectivity for target molecules. We developed selective nanocoatings by combining trinitrotoluene (TNT) receptors bound to conjugated polydiacetylene (PDA) with single-walled carbon nanotube-field effect transistors (SWNT-FET). Selective binding events between TNT molecules and phage display derived TNT receptors were effectively transduced to sensitive SWNT-FET conductance sensors through the PDA coating. The resulting sensors exhibited unprecedented 1 fM sensitivity toward TNT in real time, with excellent selectivity over various similar aromatic compounds. Our biomimetic receptor coating approach may be useful for the development of sensitive and selective micro and nanoelectronic sensor devices for various other target analytes.

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전도성을 가지는 탄소나노튜브강화 알루미나복합소재의 마이크로방전가공에서 초음파진동 부가에 의한 가공특성 (Machining characteristics on ultrasonic vibration assisted micro-electrical discharge machining of carbon-nanotube reinforced conductive Al2O3 composite)

  • 강명창;탁현석;이창훈;김남경
    • 한국기계가공학회지
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    • 제13권6호
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    • pp.119-126
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    • 2014
  • Micro-holes of conductive ceramic are required in micro structures. Micro-electrical discharge machining (Micro-EDM) is an effective machining method since EDM is as process for shaping hard metals and complex-shaped holes by spark erosion in all kinds of electro-conductive materials. However, as the depth of micro hole increases, the machining condition becomes more unstable due to inefficient removal of debris between the electrode and the workpiece. In this paper, micro-EDM was performed to evaluate machining characteristic such as electrode wear, machining time, taper angle, radial clearance with varying voltage and ultrasonic vibration on 10 vol.% Carbon-nanotube reinforced conductive $Al_2O_3$ composite fabricated by spark plasma sintering in previous research.

On vibrations of functionally graded carbon nanotube (FGCNT) nanoplates under moving load

  • Alaa A. Abdelrahman;Ismail Esen;Mohammed Y. Tharwan;Amr Assie;Mohamed A Eltaher
    • Advances in nano research
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    • 제16권4호
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    • pp.395-412
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    • 2024
  • This article develops a nonclassical size dependent nanoplate model to study the dynamic response of functionally graded carbon nanotube (FGCNT) nanoplates under a moving load. Both nonlocal and microstructure effects are incorporated through the nonlocal strain gradient elasticity theory. To investigate the effect of reinforcement orientation of CNT, four different configurations are studied and analysed. The FGM gradation thorough the thickness direction is simulated using the power law. In the context of the first order shear deformation theory, the dynamic equations of motion and the associated boundary conditions are derived by Hamilton's principle. An analytical solution of the dynamic equations of motion is derived based on the Navier methodology. The proposed model is verified and compared with the available results in the literature and good agreement is found. The numerical results show that the dynamic performance of FGCNT nanoplates could be governed by the reinforcement pattern and volume fraction in addition to the non-classical parameters and the moving load dimensionless parameter. Obtained results are reassuring in design and analysis of nanoplates reinforced with CNTs.

자기력 최적화에 따른 전해-자기 복합가공의 특성 평가에 관한 연구 (Study on Characteristics of EP-MAP Hybrid Machining by Optimization of Magnetic Flux Density)

  • 박창근;곽재섭
    • 대한기계학회논문집A
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    • 제37권3호
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    • pp.319-324
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    • 2013
  • 본 연구에서는 CNT-Co 복합체를 이용한 전해-자기(EP-MAP) 복합가공 공정을 개발하였다. CNT-Co 복합체는 높은 강도와 뛰어난 전기적 성질을 가지는 소재이기 때문에 전해-자기 복합가공의 연마재 및 전극으로 적합하다. 전해-자기 복합가공의 시너지 효과를 평가하기 위해서 각 실험조건하에서 특성평가 실험이 수행되었으며, 각 실험인자는 자기력, 전해액, 공구의 회전속도, 전해전압, 간극 등이 있다. 그 결과 CNT-Co 복합체와 화학적 반응이 없는 $NaNO_3$ 가 본 공정의 가장 적절한 전해액으로 선정되었다. 그리고 높은 자기력은 가공중의 CNT-Co 복합체내에 전해액 유동을 방해하는 인자이다. 이로 인해 공작물의 표면상의 가공부위에 열에너지가 상승하게 되고 공작물 표면손상과 피팅현상이 발생하여 가공효율성이 떨어지게 된다.

Characterization and behaviors of single walled carbon nanotube by equivalent-continuum mechanics approach

  • Eltaher, Mohamed A.;Almalki, Talaal A.;Ahmed, Khaled I.E.;Almitani, Khalid H.
    • Advances in nano research
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    • 제7권1호
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    • pp.39-49
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    • 2019
  • This paper focuses on two main objectives. The first one is to exploit an energy equivalent model and finite element method to evaluate the equivalent Young's modulus of single walled carbon nanotubes (SWCNTs) at any orientation angle by using tensile test. The calculated Young's modulus is validated with published experimental results. The second target is to exploit the finite element simulation to investigate mechanical buckling and natural frequencies of SWCNTs. Energy equivalent model is presented to describe the atomic bonding interactions and their chemical energy with mechanical structural energies. A Program of Nanotube modeler is used to generate a geometry of SWCNTs structure by defining its chirality angle, overall length of nanotube and bond length between two adjacent nodes. SWCNTs are simulated as a frame like structure; the bonds between each two neighboring atoms are treated as isotropic beam members with a uniform circular cross section. Carbon bonds is simulated as a beam and the atoms as nodes. A finite element model using 3D beam elements is built under the environment of ANSYS MAPDL environment to simulate a tensile test and characterize equivalent Young's modulus of whole CNT structure. Numerical results are presented to show critical buckling loads, axial and transverse natural frequencies of SWCNTs with different orientation angles and lengths. The understanding of mechanical behaviors of CNTs are essential in developing such structures due to their great potential in wide range of engineering applications.

반응가스 비율에 따른 탄소나노월의 성장특성 (Growth Properties of Carbon nanowall according to the Reaction Gas Ratio)

  • 김성윤;강현일;최원석;정연호;임윤식;유영식;황현석;송우창
    • 전기학회논문지P
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    • 제63권4호
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    • pp.351-355
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    • 2014
  • Graphite electrodes are used for secondary batteries, fuel cells, and super capacitors. Research is underway to increased the reaction area of graphite electrodes used carbon nanotube (CNT) and porous carbon. CNT is limited to device utilization in order to used a metal catalyst by lack of surface area to improve. In contrast carbon nanowall (CNW) is chemically very stable. So this paper, microwave plasma enhanced chemical vapor deposition (PECVD) system was used to grow carbon nanowall (CNW) on Si substrate with methane ($CH_4$) and hydrogen ($H_2$) gases. To find the growth properties of CNW according to the reaction gas ratio, we have changed the methane to hydrogen gas ratios (4:1, 2:1, 1:2, and 1:4). The vertical and surficial conditions of the grown CNW according to the gas ratios were characterized by a field emission scanning electron microscopy (FE-SEM) and Raman spectroscopy measurements showed structure variations.

실크 스크린 프린팅 기법을 적용한 용액 기반의 탄소나노튜브와 은 나노 와이어 코팅 기술 개발 (Development of Solution-based Carbon Nanotube and Silver Nanowire Coating Technology using Silk Printing Technique)

  • 김무진
    • 산업융합연구
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    • 제21권9호
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    • pp.33-39
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    • 2023
  • 나노 크기의 물질은 여러 기판에 코팅이 가능하며, 이 소재는 투명하며, 전도성이 있기 때문에 전자소자의 투명전극이나 전원 공급용 전극으로 활용이 가능하다. 본 연구에서는 CNT와 Ag 나노와이어를 실크스크린 기법을 이용하여 반복적으로 코팅하였으며, 5번까지 형성한 샘플을 제작하여, 광학 및 전기 특성을 측정하고, 분석하였다. 실크스크린 코팅된 샘플 표면은 코팅 방향에 의한 자국이 형성되었음을 확인하였으며, 코팅한 횟수에 따른 투과도 및 표면 저항의 경향성을 조사하였다. 코팅 횟수가 늘어남에 따라 투과도 및 표면 저항은 감소하는 경향을 나타내었다. 특히 투과도의 경우 2번과 5번에서 변화폭이 컸으며, 이러한 변화는 Ag 나노와이어 코팅에 의한 것으로 확인되었다. 또한, 700nm를 기점으로 이전 파장 영역에서는 파장에 따라 증가하는 반면 이상에서는 감소하는 경향을 보였다. 표면 저항은 1번 코팅했을 때 9Ω/cm2 에서 5번 코팅을 진행하였을 때 0.856Ω/cm2 으로 낮아졌다. 투과도와 유사하게 Ag에 의하여 저항값이 영향을 받는다는 것을 알 수 있었다. 향후 Ag 나노와이어의 Ag 농도 및 다른 방법으로 코팅하여 투명도가 높은 CNT와의 융합을 통하여 원하는 투명 전극을 구현하여 전자소자에 적용할 필요가 있다.