• Title/Summary/Keyword: carbon dioxide method

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CO2 decomposition characteristics of Ni-ferrite powder (Ni-페라이트 분말을 이용한 CO2 분해 특성)

  • Nam, Sung-Chan;Yoon, Yeo-Il
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.11
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    • pp.5376-5383
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    • 2011
  • The objective of this study is the development of carbon-recycle technology, that converts carbon dioxide captured from flue gas to carbon monoxide or carbon for reuse in industrial fields. It is difficult to decompose $CO_2$ because $CO_2$ is very stable molecule. And then metal oxide was used as an activation agent or catalyst for the decomposition of $CO_2$ at low temperature. Metal oxides, which converts $CO_2$ to CO or C, were prepared using Ni-ferrite by solid state method and hydrothermal synthesis in this study. TPR/TPO and TGA were used as an analysis method to analyze the decomposition characteristics of $CO_2$. As the results, the reduction area of $H_2$ was high value at 15 wt% of NiO and the decomposition area of $CO_2$ was superior capacity at 5 wt% of NiO. However, TGA data showed contrary results that reduction area of $H_2$ was 28.47wt% and oxidation area by $CO_2$ was 26.95wt% at 2.5 wt% of NiO, one of the Ni-ferrite powders synthesized using solid state method. $CO_2$ decomposition efficiency was 94.66% and it is excellent results in comparison with previous studies.

Effects of $LiMn_{2}O_{4}$ Addition on $CO_{2}$ Decomposition Using Spinel Phase $Fe_{3}O_{4}$ (스피넬상 $Fe_{3}O_{4}$를 이용한 $CO_{2}$ 분해에서 $LiMn_{2}O_{4}$ 첨가효과)

  • Yang, Chun-Mo;Park, Young-Goo;Cho, Young-Koo;Rim, Byung-O
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.3
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    • pp.174-179
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    • 2001
  • The spinel $Fe_{3}O_{4}$ powders were synthesized using 0.2 $M-FeSO_4{\cdot}7H_{2}O$ and 0.5 M-NaOH by oxidation in air and the spinel $LiMn_{2}O_{4}$ powders were synthesized at 480 $^{\circ}C$ for 12 h in air by a sol-gel method using manganese acetate and lithium hydroxide as starting materials. The synthesized $LiMn_{2}O_{4}$ powders were mixed at portion of 5, 10, 15 and 20 wt% of $Fe_{3}O_{4}$ powders using a ball-mill. The mixed catalysts were dried at room temperature for 24 hrs. The mixed catalysts were reduced by hydrogen gas at 350 $^{\circ}C$ for 2 h. The carbon dioxide decomposition rates of the mixed catalysts were 90% in all the mixed catalysts but the decomposition rate of carbon dioxide was increased with adding $LiMn_{2}O_{4}$ powders to $Fe_{3}O_{4}$ powders.

Extraction of Ginger Oil from Korean-Grown Ginger-root using Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 국산 생강뿌리로부터 생강유의 추출)

  • 천재기
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.1
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    • pp.69-79
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    • 1998
  • The type photographic optical system is designed by using numerical method. Initially the paraxial quantites, numerical solutions are found for the system which is free from the Seidel seven aberrations. The final system has f/4 with the half field angle 20$^{\circ}$, and the image size is 36mm with the focal length of 50mm.

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A Study on the Method of the Feasibility Analysis for the Application of C0-Generation System in a New Apartment Complex (신규아파트 열병합발전 도입에 따른 경제성분석 방법)

  • Kee, Woo-Bong;Kim, Kwang-Ho
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.782-783
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    • 2007
  • Exhaustion of fossil fuel resources and high oil price, and furthermore environmental crisis due to emission of carbon dioxide from fossil fuel are serious problems in these days. In order to overcome these problems it is necessary to find and utilize the every energy saving measures and to make maximum utilization of renewable energy resources. The objective of this paper is to develop an instrument to verify the feasibility of Co-Generation System application in an Apartment Complex.

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A study of SO2 Removal Efficiency from Traditional Herbal Medicine Using Traditional & Electronic Medicine Boilers (전통약탕기와 전자약탕기를 이용한 이산화황 제거효율 연구)

  • Yang, Seung-Hee;Ryu, Seok-Gyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.5
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    • pp.1133-1140
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    • 2009
  • The purpose of this study is to determine the most efficient method of removing sulfur dioxide from traditional herbal medicine (hanyak) by slow boiling using a traditional pipkin and an electronic slow boiler. By boiling a hanyak batch containing] 56.4ppm of sulfur dioxide for one hour using a traditional pipkin, 96.7 percent of the sulfur dioxide was removed, while two hours of slow boiling removed ]00 percent. Among different cover materials placed over the pipkin during the slow boiling process including the traditional Korean paper (hanji), regular hanji, filter paper and regular paper, the traditional hanji produced the best performance of sulfur dioxide removal. The initial pH level of the traditional hanji was] 0.03. After one hour of slow boiling hanyak batches in a traditional pipkin covered with traditional hanji, where each batch contained sulfur dioxide of 48ppm, 193ppm, 753ppm and 1,506ppm respectively, the pH level of the hanji cover material was reduced to 9.37, 9.14, 8.9 and 8.03 in respective cases. Our experiment using an electronic medicine slow boiler showed 82.8 percent removal of sulfur dioxide after one hour of slow boiling a hanyak batch containing 753ppm of sulfur dioxide. When hanyak batches were boiled by placing traditional hanji, filter paper, active carbon and hardwood charcoal separately in the middle area within the electronic slow boiler, the sulfur dioxide removal rate was 73.6 percent, 72.8 percent, 73.9 percent and 69.5 percent, respectively. When charcoal was added so as to remove toxic materials from the hanyak, its presence impeded the sulfur dioxide flow and thus reduced the removal efficiency contrary to our anticipation.

Autonomous Micro-grid Design for Supplying Electricity in Carbon-Free Island

  • Hwang, Woo-Hyun;Kim, Sang-Kyu;Lee, Jung-Ho;Chae, Woo-Kyu;Lee, Je-Ho;Lee, Hyun-Jun;Kim, Jae-Eon
    • Journal of Electrical Engineering and Technology
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    • v.9 no.3
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    • pp.1112-1118
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    • 2014
  • In island and backcountry areas, electrical power is usually supplied by diesel generators. It is difficult for small scale diesel generators to have an economy of scale owing to the usage of fossil fuels to produce electricity. Also, there is a problem of carbon dioxide emissions that brings some environmental pollution to the entire region of the area. For solving those, this paper proposes a design method of autonomous micro-grid to minimize the fossil fuels of diesel generator, which is composed of diesel generator, wind turbine, battery energy storage system and photovoltaic generation system. The proposed method was verified through computer simulation and micro-grid operation system.

Seasonal Variation of Carbon Dioxide and Energy Fluxes During the Rice Cropping Season at Rice-barley Double Cropping Paddy Field of Gimje (김제 벼-보리 이모작 논에서 벼 재배기간동안의 CO2 및 에너지 플럭스의 계절적 변화)

  • Min, Sung-Hyun;Shim, Kyo-Moon;Kim, Yong-Seok;Jung, Myung-Pyo;Kim, Seok-Cheal;So, Kyu-Ho
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.15 no.4
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    • pp.273-281
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    • 2013
  • Based on the results of continuous flux measurements at the Gimje paddy flux site in the southwestern coast of Korea, carbon dioxide and energy exchanges between customarily cultivated rice-barley double cropping paddy field and the atmosphere during the 2012 rice growing season (from $9^{th}$ Jun. 2012 through $20^{th}$ Oct. 2012) were analyzed. Carbon dioxide and energy (H, LE) fluxes were estimated by the eddy covariance method. Environmental parameters (net radiation, precipitation, etc.) and plant biomass (LAI, plant height, etc.) were measured along with fluxes. After the quality control and gap-filling, the observed fluxes were analyzed. The results have been showed that net ecosystem exchange (NEE), gross primary production (GPP), and ecosystem respiration (Re) during the rice cropping period were -277.1, 710.3, and 433.2 g C $m^{-2}$, respectively.

Performance of Magnesia Cement Using MgCO3 and Serpentine

  • Lee, Jong-Kyu;Soh, Jung-Sub
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.116-121
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    • 2016
  • The amount of carbon dioxide ($CO_2$) released while producing building materials is substantial and has been targeted as a leading contributor to global climate change. One of the most typical methods of reducing $CO_2$ in building materials is the addition of slag and fly ash, like pozzolan material another method is to reduce $CO_2$ production by developing carbon negative cement. MgO-based cement from the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. It is also believed that adding reactive MgO to Portland-pozzolan cements can improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, basic research on magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as the main starting materials, as well as blast furnace slag for the mineral admixture, was carried out for industrial waste material recycling. In order to increase the overall hydration activity, $MgCl_2$ was also added. In the case of the addition of $MgCl_2$as accelerating admixture, there was a promoting effect on the compressive strength. This was found to be due to the production of needle-like dense Mg-Cl hydrates. Mgnesia cement has a high viscosity due to its high specific surface area therefore, when the PC-based dispersing agent was added at a level of more than 1.0%, it had the effect of improving fluidity. In particular, the addition of $MgCl_2$ in magnesia cement using $MgCO_3$and magnesium silicate ore (serpentine) as main starting materials led to a lower expansion ratio and an increase in the freeze-thaw resistance finally, the addition of $MgCl_2$ as accelerating admixture led to good overall durability.

A Study of Upgrading Real Biogas via CO2 Precipitation Route Under Indian Scenario

  • Gehlaut, Avneesh Kumar;Gaur, Ankur;Hasan, Shabih Ul;Park, Jin-Won
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.381-387
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    • 2018
  • Our study focuses on upgrading real biogas obtained under Indian scenario using carbon capture and utilization (CCU) technology to remove carbon dioxide ($CO_2$) and utilize it by forming metal carbonate. Amines such as monoethanolamine (MEA), diethanolamine (DEA), and sodium hydroxide (NaOH) were used to rapidly convert gaseous $CO_2$ to aqueous $CO_2$, and $BaCl_2$ was used as an additive to react with the aqueous $CO_2$ and rapidly precipitating the aqueous $CO_2$. All experiments were conducted at $25^{\circ}C$ and 1 atm. We analyzed the characteristics of the $BaCO_3$ precipitates using X-ray diffractometry (XRD), scanning electron microscopy - Energy dispersive spectroscopy (SEM-EDS) and Fourier-transform infrared spectroscopy (FT-IR) analyses. The precipitates exhibited witherite morphology confirmed by the XRD results, and FT-IR confirmed that the metal salt formed was $BaCO_3$, and EDS showed that there were no traces of impurities present in it. The quantity of the $BaCO_3$ was larger when formed with DEA. Also, a comparison was done with a previous study of ours conducted in Korean conditions. Finally, we observed that the carbonate obtained using real biogas showed similar properties to carbonates available in the market. An economic analysis was done to show the cost effectiveness of the method employed by us.

Effect of the additive gas on the bonding structure and mechanical properties of the DLC films deposited by RF-PECVD (RF-PECVD법에 의해 증착된 DLC 박막의 결합구조와 기계적 특성에 관한 보조가스의 영향)

  • Choi, Bong-Geun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.4
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    • pp.145-152
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    • 2015
  • In this work, we were investigated the effect of the additive gases on the relationship between bonding structure and mechanical properties of the deposited films when the DLC films were deposited on Si-wafer by the rf-PECVD method with the addition of small amounts of carbon dioxide and nitrogen to the mixture gas of methane and hydrogen. The deposition rate of the films increased as the rf-power increased, while it decreased with increasing the amount of additive gases. Also, as the carbon dioxide gas increased, the hydrogen content in the films decreased but the $sp^3/sp^2$ ratio of the films increased. In case of nitrogen gas, the hydrogen content decreased, however the $sp^3/sp^2$ ratio and nitrogen gas flow rate did not show a specific tendency.