• Title/Summary/Keyword: carbon dioxide method

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Experimental Study on Estimation of Oxidation Rate of PM inside of Diesel Particulate Filter (DPF내 포집된 입자상 물질의 산화율 산출을 위한 실험적 연구)

  • Shim, Beomjoo;Park, Kyoungsuk;Jo, Kyuhee;Lee, Hyeongjun;Min, Byeongdu
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.2
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    • pp.98-103
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    • 2013
  • Conventional method to estimate mass of particulate matter accumulated in diesel particulate filter is to use pressure difference between upstream and downstream of the filter. Then measured pressure difference should be compared that of clean condition which is no particulate matter accumulated in DPF. During regeneration soot oxidation is also estimated by same method. This methodology, however, has demerit on accuracy because of pressure difference deviation of clean DPFs and pressure difference caused by non-carbon based PM which is different from that of caused by carbon based PM. This study suggests new methodology to estimate accumulated soot oxidation rate through exhaust gas characteristics during regeneration. Results, more high accuracy of soot oxidation was obtained by analysis of relationship between fuel mass and concentration of carbon dioxide and oxygen.

The method for total organic carbon analysis employing TiO2 photocatalyst (이산화티타늄 광촉매를 이용한 총유기탄소 분석방법)

  • Park, Buem Keun;Kim, Sung Mi;Lee, Young-Jin;Paik, Jong-Hoo;Shin, Jeong Hee
    • Journal of Sensor Science and Technology
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    • v.30 no.5
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    • pp.320-325
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    • 2021
  • Biochemical oxygen demand (BOD) and chemical oxygen demand (COD) methods are conventional analytical methods to analyze water quality. Both of these methods are technically indirect measurement methods, require complicated preconditions, and are time-consuming. On the other hand, the total organic carbon (TOC) method is a direct and fast measurement method which is more intuitive and accurate than the BOD and COD methods. However, general TOC analysis methods involve complicated processes and high power consumption owing to the process of phase transition from liquid to gas by a high-temperature heater. Furthermore, periodic consumables are also required for the removal of inorganic carbon (IC). Titanium dioxide (TiO2) is one of the most suitable photocatalysts for simple processes. Its usage involves low power consumption because it only reacts with the organic carbon (OC) without the requirement of any other reagents and extra processes. We investigated a TiO2 photocatalyst-based TOC analysis for simple and affordable products. TiO2-coated fiber substrate maintained under carbon included water was exposed to ultraviolet (UV) radiation of wavelength 365 nm. This method is suitable for the real-time monitoring of water pollution because of its fast reaction time. Its linear property is also sufficient to match the real value.

Temporal Variation of Indoor Air Quality in Daycare Centers (어린이집에서 이산화탄소와 미세먼지의 장기간 시간적인 변이를 활용한 실내환경수준 평가)

  • Kim, Yoonjee;Lee, Sewon;Ban, Hyunkyung;Cha, Sangmin;Kim, Geunbae;Lee, Kiyoung
    • Journal of Environmental Health Sciences
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    • v.43 no.4
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    • pp.267-272
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    • 2017
  • Objectives: The purposes of the study were to analyze the temporal variation of carbon dioxide ($CO_2$) and particulate matter (PM) in daycare centers and evaluate the appropriateness of the official test method of one-time measurement. Methods: Indoor air quality in 46 daycare centers in the Seoul Metropolitan Area was measured as specified in the official test method of Indoor Air Quality Management law. In addition, indoor air quality in the 46 daycare centers was measured over 37 days using a real-time monitor (AirGuard K). Results: The daily means of $CO_2$ and PM in the 46 daycare centers were $1042.74{\pm}134.45ppm$ and $67.60{\pm}18.25{\mu}g/m^3$, respectively. Indoor air quality in the daycare centers showed significant temporal fluctuation. Measurements for single days were significantly different from the 37-day average exposure. Relative error of short term exposure decreased with an increase in the number of sampling days. The noncompliance rate for $CO_2$ using the official testing method was 2.17%, and none exceeded the $PM_{10}$ standard of $100{\mu}g/m^3$. With monitoring over 37 days, the daily noncompliance rate for $CO_2$ was 50.4% and the daily noncompliance rate for PM was 13.8%. Conclusions: When the official test method evaluates the indoor air at daycare centers one day per year, the results may not represent actual indoor air quality over a longer period of time. Real-time monitoring devices could be an alternative for managing indoor air quality.

Uncertainty Analysis of the Eddy-Covariance Turbulent Fluxes Measured over a Heterogeneous Urban Area: A Coordinate Tilt Impact (비균질 도시 지표에서 측정된 에디 공분산 난류 플럭스의 불확실성 분석: 좌표계 편향 영향)

  • Lee, Doo-Il;Lee, Jae-Hyeong;Lee, Sang-Hyun
    • Atmosphere
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    • v.26 no.3
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    • pp.473-482
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    • 2016
  • An accurate determination of turbulent fluxes over an urban area is a challenging task due to its morphological diversity and associated flow complexity. In this study, an eddy covariance (EC) method is applied over a highly heterogeneous urban area in a small city (Gongju), South Korea to investigate the quantitative influence of 'coordinate tilt' in determining the turbulent fluxes of sensible heat, latent heat, momentum, and carbon dioxide mass. Two widely-used coordinate transform methods are adopted and applied to eight directional sections centered on the site to analyze a 1-year period EC measurement obtained from the urban site: double rotation (DR) and planar fit (PF) transform. The results show that mean streamline planes determined by the PF method are distinguished from the sections, representing morphological heterogeneity of the site. The sectional pitch angles determined by the DR method also compare well with those in the PF method. Both the PF and DR methods show large variabilities in the determined streamline planes at each directional section, implying that flow patterns may form in a complicate way due to the surface heterogeneity. Resulting relative differences of the turbulent fluxes, defined by $(F_{DR}-F_{PF})/F_{DR}$, are found on average +13% in sensible heat flux, +21% in latent heat flux, +37% in momentum flux, and +26% in carbon dioxide mass flux, which are larger values than those reported previously for fairly homogeneous natural sites. The fractional differences depend significantly on wind direction, showing larger differences in northerly winds at the measurement site. It is also found that the relative fractional differences are negatively correlated with the mean wind speed at both stable/unstable atmospheric conditions. These results imply that EC turbulent fluxes determined over heterogeneous urban areas should be carefully interpreted with considering the uncertainty due to 'coordinate tilt' effect in their applications.

Enhancement of carbon dioxide absorption rate with metal nano particles (금속 나노입자를 이용한 이산화탄소 흡수 속도 촉진)

  • Choi, Young Ju;Youn, Min Hye;Park, Ki Tae;Kim, In Ho;Jeong, Soon Kwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.10
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    • pp.6439-6444
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    • 2015
  • With increasing concern about global warming, CCS (Carbon dioxide capture and storage) has attracted much attention as a promising technology for reducing $CO_2$ emission. It is necessary to develop the cost-effective absorbents materials in order to rapid commercialize CCS technologies. In this work, he study for the promotion of absorption rate in $CO_2$ capture system using metal nanoparticle were investigated. Three kinds of metal nanoparticle, cobalt, zinc, and nickel, were prepared by wet and dry method and effect of preparation method on the absorption rate of $CO_2$ were compared. Among the tested using pH method, nickel nanoparticle prepared by wet method showed the most significant improvement of $CO_2$ absorption rate. In case that metal nanoparticle is applied to CCS process, it is expected to be more efficient in $CO_2$ capture process due to reduce the size of absorption tower.

Development of Adsorption Process with UiO-66 Particles for Hydrogen Purification Using Statistical Design of Experiment (통계학적 실험계획법을 이용한 수소정제용 UiO-66 흡착제 개발)

  • Lee, Hyun Sik;Kim, Da Som;Park, Ji Won;Yoo, Kye Sang
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.784-791
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    • 2018
  • UiO-66 particles were synthesized under various synthesis conditions to study the adsorption of carbon dioxide for hydrogen purification. For the purpose, the design and analysis of experiments was performed using statistical design of experiment method. As the synthesis time, temperature and acetic acid amount increased, the crystallinity of UiO-66 particles increased. Especially, the amount of acetic acid was confirmed as an important factor in determining the crystallinity of the particles. The specific surface area of the particles measured by the nitrogen adsorption method also showed a similar tendency. Using the general factor analysis in the experimental design method, the main effects and interactions of major factors were analyzed. In addition, the carbon dioxide adsorption capacity was predicted using a nonlinear regression method. Then, the adsorption performance was shown through surface and contour maps for all ranges.

A Study on Hazard of Renewable Energy based Alkaline Water Exectrolysis Equipment (재생에너지 기반 알칼라인 수전해 장치(2 Nm3/hr) 위험요인 고찰)

  • KIM, HYEONKI;SEO, DOOHYOUN;KIM, TAEHUN;RHIE, KWANGWON;LEE, DONGMIN;SHIN, DANBEE
    • Journal of Hydrogen and New Energy
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    • v.33 no.1
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    • pp.55-60
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    • 2022
  • As interest in sustainable and eco-friendly energy sources is increasing due to various problems in the carbon society, a hydrogen economy using hydrogen as a main energy source is emerging. While the natural gas reforming method generates carbon dioxide, the water electrolysis method based on renewable energy is eco-friendly. The water electrolysis device currently being developed uses a 2 Nm3/hr class alkaline aqueous solution as an electrolyte and produces hydrogen based on renewable energy. In this study, risk assessment was conducted for these water electrolysis devices

LCCO2 analysis of wood-containing printing paper by mixed ratio of de-inked pulp and BTMP (DIP 및 BTMP 혼합비율에 따른 인쇄용지의 LCCO2 분석)

  • Seo, Jin Ho;Kim, Hyoung Jin;Chung, Sung Hyun;Park, Kwang Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.2
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    • pp.46-55
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    • 2013
  • Recently, there are growing interests on carbon emissions related in climate change which is worldwide emerging important issue. Some research works are now carrying out in order to reduce the carbon emission in pulp and paper industries by the synthesis of precipitated calcium carbonate using the exhaust carbon dioxide from combustion furnace or incinerator. However, for solving the original problems on carbon emission, we need to consider the analysis of basic methodology on $CO_2$ through the process efficiencies. There are two general tools for carbon emissions; one is the greenhouse gas inventory and the other is $LCCO_2$ method which is applied to particular items of raw materials and utilities in unit process. In this study, the carbon emissions in wood-containing printing paper production line were calculated by using $LCCO_2$ method. The general materials and utilities for paper production, such as fibrous materials, chemical additives, electric power, steam, and industrial water were analyzed. As the results, $Na_2SiO_3$ showed the highest loads in carbon emissions, and the total amount of carbon emissions was the highest in electricity. In the production line of printing paper using de-inked pulp and BTMP, as the mixing ratio of DIP was higher, the carbon emissions were decreased because of high use of electric power in TMP process.

The Influence of Green Finance on Carbon Emissions in China - Green technology innovation as a parameter - (중국 녹색금융이 탄소 배출에 미치는 영향 - 녹색혁신을 매개변수로 -)

  • Qinghao Zhu;Jaeyeon Sim
    • Industry Promotion Research
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    • v.9 no.4
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    • pp.505-514
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    • 2024
  • The entropy method is employed to measure the four indicators of green credit, green securities, green investment, and green insurance of 18 prefecture-level cities in Henan Province, China from 2012 to 2022. Firstly, based on the standardized indicators and the measured indicator weights, the green finance development indicators we require are obtained. Secondly, a dynamic panel model concerning the development of green finance and the level of carbon emissions is constructed, and the influence path of green finance on carbon emissions is empirically analyzed. The conclusion puts forward that: Firstly, green finance not only directly affects carbon emissions. Secondly, it also indirectly acts on carbon dioxide emissions through green innovation. The level of low-carbon economic transformation in Henan Province, China shows a continuous improvement trend. During the analysis process, an overall correlation analysis of green finance and carbon emissions is carried out, and the specific mechanism of green finance on carbon emissions is explored.

Estimating carbon dioxide uptake in wetland ecosystems of Tumen River Basin using eddy covariance flux data (에디 공분산 기반의 플럭스 타워 관측자료를 이용한 두만강 유역 습지 생태계 CO2 흡수량 분석)

  • Chen, Pengshen;Zhao, Shuqing;Cui, Guishan;Lee, Dongkun
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.27 no.3
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    • pp.67-74
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    • 2024
  • In the context of rapid temperature rise in mid-to-high latitude regions, cold region wetlands have become a hotspot for current wetland carbon cycle research due to their high sensitivity to climate change. Strengthening the monitoring of CO2 fluxes in wetland ecosystems is of great practical significance for clarifying the carbon balance of wetlands and maintaining the ecological balance of wetland ecosystems in China's high latitude regions. In this study, the carbon flux (NEE, Net ecosystem exchange; GPP, Gross Primary Production; RECO, Ecosystem response) of Jingxin Wetland was monitored by eddy correlation method from August 2021 to March 2024.2022-2023 shows CO2 sinks, absorbing 349.4 g C·m-2·yr-1 annually. The correlation analysis showed that Ta, VPD and PPFD were the main environmental factors affecting CO2 flux in Jingxin wetland.