• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.1
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• pp.431-438
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• 2012

The $CO_2$ capture technology using an aqueous amine solution is studied widely now. The entire process consists of an absorber to remove carbon dioxide selectively and a regenerator to regenerate absorbent and acquire pure carbon dioxide. Because there are the complicated design variables that affect performance of the process, it needs optimization and analysis through modeling to make a commercially reliable process. In this study, the decomposition method was proposed to consider convergence problem and sensitivity analysis was executed for the carbon dioxide capture process variables. Non-equilibrium model was used in the simulation to get more realistic results and we designed optimized process with more than 95% purity and 90% recovery.

• Applied Biological Chemistry
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• v.35 no.1
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• pp.55-63
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• 1992

The essential oil of Korean ginger(Zingiber officinale Roscoe) was isolated by liquid carbon dioxide extraction method and fractionated into one hydrocarbon fraction and two oxygenated hydrocarbon fractions by using silica gel column chromatography. The compositions of the resulting oils were investigated by GC and GC-MS spectrometry. Out of 102 identified compounds, 44 were identified by comparing GC retention time and mass spectral data with authentic samples and 58 were tentatively identified according to mass spectral data only. The major compounds of hydrocarhon fraction were $zingiberene,\;{\beta}-sesquiphellandrene,\;{\gamma}-bisabolene,\;{\gamma}-cardinene,\;ar-curcumene$, and those of oxygenated hydrocarbon fractions wee geranal, sesquisabinene hydrate, borneol and zingiberenol. The major compounds of ginger oil were zingiberene, $citronellol+{\beta}-sesquiphellandrene,\;geranial,\;{\gamma}-bisabolene\;and\;ar-curcumene+geranyl\;acetate$, and ginger oil contained higher amounts of sesquiterpene hydrocarbons. The yield of extract was 6.96%.

• Korean Chemical Engineering Research
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• v.53 no.2
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• pp.193-198
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• 2015

The high-pressure phase behavior of a polycaprolactone (Mw=56,145 g/mol, polydispersity 1.2), dichloromethane, and carbon dioxide ternary system was measured using a variable-volume view cell. The experimental temperatures and pressures ranged from 313.15 K to 353.15 K and up to 300 bar as functions of the $CO_2$/dichloromethane mass ratio and temperature, at poly(D-lactic acid) weight fractions of 1.0, 2.0, and 3.0%. The correlation results were obtained from the hybrid equation of state (Peng-Robinson equation of state + SAFT equation of state) for the $CO_2$-polymer system using the van der Waals one-fluid mixing rule. The three binary interaction parameters were optimized by the simplex method algorithm.

• Clean Technology
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• v.18 no.1
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• pp.38-42
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• 2012

Photonic crystals (PCs) are highly ordered porous materials which have been much attention because of its potential for controlling the light sauces. There are many methods for synthesizing this kind of materials among them we chose the supercritical deposition. With this method the reactants can easily infiltrate into the complex structure. In this paper, supercritical carbon dioxide ($scCO_2$) was used as a reaction medium, which is known as a sustainable solvent due to its nontoxic and noninflammable characteristics. We coated the colloidal template with metal alkoxide by using $scCO_2$ and then obtained macro-porous inverse opals. The reaction was carried out at $40^{\circ}C$ and 80 bar. We synthesized two different inverse opals which called silica and titania inverse opals by use of tetraethyl orthosilicate (TEOS) and titanium isopropoxide (TTIP) as a precursor, respectively.

• Proceedings of the KOR-BRONCHOESO Conference
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• 1983.05a
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• pp.7.2-8
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• 1983

Chronic laryngotracheal stenosis is becoming increasingly prevalent. Many acceptable procedures such as repeated dilation, laryngotracheoplasty and end-to-end anastomosis had been done according to it's indication, but it have given less than favorable results. Since 1972 the experimental and clinical experiences of Jako and Strong, the carbon dioxide laser has offered a valuable tool to the otolaryngologist. Mihashi (1976) and Lyons (1980) reported use of laser to the management of laryngotracheal stenosis with successful results. From April 82' to March 83', using the carbon dioxide laser, the various obstructing lesions were excised microendoscopically which include four patients considered failures from conventional surgical technique and one patient laryngeal stenosis occured after hemilaryngectomy and neoglottis formation. We concluded as follows, 1) Laser surgery is a useful method to the management of laryngotracheal stenosis in maintaining adequate airway. 2) Formation of granulation after laser surgery was less than other conventional methods.

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.2
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• pp.89-96
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• 2010

This study presented the analytical evaluation model effective in the concrete structure repaired with a patching material. The model considered the effect of the repair material on carbon dioxide penetration into the repaired concrete as evaluating the remaining service life of the CO2-deteriorated concrete structure after repair. The diffusion profiles of carbon dioxide as well as the carbonated concrete were effectively able to be modelled with analytical method based on Fick's 1st diffusion law. The evaluation of the model equation showed the good result and rational process quantitatively and numerically to evaluate the remaining service life of the repaired concrete structure after repair.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.65 no.3
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• pp.165-170
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• 2016

Due to environmental issues such as global warming, the reduction of greenhouse gas emissions has become an inevitable measure to be taken. Among others, the building sector accounts for 50% of total carbon dioxide emissions, which is significantly high. Therefore, in order to reduce carbon dioxide emissions of the buildings, improving the energy efficiency by utilizing wind power among renewable energy sources is recommended. In case of buildings in the planning stage, it is possible to take the load of wind power generation systems into consideration when determining installed capacity. Already completed buildings, however, should be connected to small wind electric systems according to the live loads of the buildings based on the architectural design criteria. In order to connect to a building that has already been completed, it is necessary to consider the load of the small wind electric system as well as the live load of building. In addition, we need to generate the maximum electricity possible by determining the maximum installed capacity in a small area. In this paper, we propose the method for determining maximum capacity for building integrated small wind electric systems, which takes into account the considerations associated with connecting small wind electric systems to completed buildings. This can be developed into a system linked to solar power, which makes it possible to improve the energy independence of the building. In addition, carbon dioxide reduction by improving energy efficiency is expected.

• Membrane Journal
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• v.25 no.6
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• pp.547-557
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• 2015

In this study, we synthesized polyimide with high carbon dioxide gas transport property using 2,2-bis(3,4-carboxylphenyl) hexafluoropropane, 2,3,5,6-tetramethyl-1,4-phenylenediamine and poly(ethylene glycol) bis(3-aminopropyl) terminated and then we calculated solubility parameter of synthesized polymer and non-solvent phase separation coefficient to determine proper solvent for preparation of asymmetric membrane, also we measured the viscosity of the polymer solution to check polymer contents in membrane solution and prepare asymmetric membrane with $LiNO_3$ additives. The morphology and gas separation property of membrane prepared by phase separation method was confirmed using Field Emission Scanning Electron Microsope and the single gas permeation measurement apparatus. We confirmed that the carbon dioxide permeance of the membrane increased and the selectivity showed little change with decreasing of the volatile solvent contents.

• Journal of ILASS-Korea
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• v.23 no.4
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• pp.227-233
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• 2018

An automobile is composed of a combination of a lot of parts, and it is difficult to maintain the same performance from a new car until it's scrapped. Greenhouse gases included in automobile emissions are typically carbon dioxide and methane. It is expected that this greenhouse gas will change depending on the aging (cumulative mileage) of the automobile However, the greenhouse gas characteristics by cumulative mileage lack of actual data due to time and economic difficulties. Therefore, in this paper, we selected automobile with high sales by displacement in korea and carbon dioxide and methane were measured by using method of the related law. The cumulative mileage is as follows; within 160 km (Statutory mileage by 2010), 6500 km (current statutory mileage), 15000 km (approximately 1-year average mileage of Non-business passenger vehicle). As a result of the test, the emission of carbon dioxide and methane was the smallest at 6,500 km, and increased in order of 15000 km, within 160 km. Also, it was confirmed that the $CO_2$ emission change of a large displacement automobile is more smaller at each mileage. Although the greenhouse gas tends to increase as the mileage of the vehicle, it is thought that additional confirmation is required of since 15,000 km as well, because it can occur deviations due to taming process or mechanical friction of the automobile.

• Korean Chemical Engineering Research
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• v.43 no.3
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• pp.432-437
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• 2005

An electric swing adsorption (ESA) process for recovering highly pure $CO_2$ from the mixed gases was tested. In this study, activated carbon fibers were used as an adsorbent. The activated carbon fibers showed fast adsorption rate and the high adsorption capacity for $CO_2$ adsorption under the condition of the ambient pressure. Activated carbon fiber with higher specific surface area was suitable to repeated adsorption-desorption cycle process, showing consistent breakthrough curve. Especially, the regeneration method by vacuum combined with ESA improved the performance of desorption process by an additional 17％ regeneration efficiency compared to a vacuum only method, and showed the high regeneration efficiency at comparatively low 7-8 Wh energy.