• Title/Summary/Keyword: carbon dioxide($CO_2$)

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Effective Suppression of Methane Production by Chelating Nickel of Methanogenesis Cofactor in Flooded Soil Conditions (담수토양에서 메탄생성반응 보효소 니켈의 킬레이팅에 의한 메탄 생산량의 효과적 저감)

  • Kim, Tae Jin;Hwang, Hyun Young;Hong, Chang Oh;Lee, Jeung Joo;Kim, Gun Yeob;Kim, Pil Joo
    • Korean Journal of Environmental Agriculture
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    • v.33 no.4
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    • pp.282-289
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    • 2014
  • BACKGROUND: Methane($CH_4$) is considered as the secondmost potent greenhouse gas after carbon dioxide ($CO_2$). Methanogenesis is an enzyme-mediated multi-step process by methanogens. In the penultimate step, methylated Co-M is reduced by methyl Co-M reductase (MCR) to $CH_4$ involving a nickel-containing cofactor F430. The activity of MCR enzyme is dependent on the F430 and therefore, the bioavailability of Ni to methanogens is expected to influence MCR activity and $CH_4$ production in soil. In this study, different doses of EDTA(Ethylene Diamine Tetraacetic Acid) were applied in flooded soils to evaluate their suppression effect on methane production by chelating Ni of methanogenesis cofactor. METHODS AND RESULTS: EDTA was selected as chelating agents and added into wetland and rice paddy soil at the rates of 0, 25, 50, 75, and $100mmol\;kg^{-1}$ before 4-weeks incubation test. During the incubation, cumulative $CH_4$ production patterns were characterized. At the end of the experiment, soil samples were removed from their jars to analyze total soil Ni and water-soluble Ni content and methanogen abundance. Methane production from 100 mmol application decreased by 55 and 78% in both soils compared to that from 0 mmol. With increasing application rate of EDTA in both soils, water-soluble Ni concentration significantly increased, but total soil Ni and methanogen activities showed negative relationship during incubation test. CONCLUSION: The decrease in methane production with EDTA application was caused by chelating Ni of coenzyme F430 and inhibiting methanogenesis by methyl coenzyme M reductase. Consequently, EDTA application decreased uptake of Ni into methanogen, subsequently inhibited methanogen activities and reduced methane production in flooded soils.

Investigation of Early-Age Concrete Strength Development Using Hardening Accelerator (경화촉진제를 사용한 콘크리트의 초기강도 발현 특성 검토)

  • Kim, Gyu-Yong;Kim, Yong-Ro;Park, Jong-Ho
    • Journal of the Korea Concrete Institute
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    • v.28 no.3
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    • pp.309-316
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    • 2016
  • In this study, performance of hardening accelerator types which promote setting and hardening of cement has been reviewed in order to develop early age strength of concrete with compressive strength of 21~27 MPa after examination of strength development of the concrete at early age according to curing temperature and unit cement(binder) content. As results, soluble mineral salt showed better hardening acceleration effect than organic salt in the scope of this study. Also, hydration reaction accelerating effect of $C_3S$ by Soluble mineral salt is effective on development of early age compressive strength and it was shown that the Pt's hydration reaction accelerating effect was the best. Construction duration reduction can be expected by securing compressive strength for prevention of early aged freezing damage in 25hour-curing time under curing temperature at $15^{\circ}C$. Also, it was shown that compressive strength of specimen cured at $5^{\circ}C$ was similar with plain specimen cured at $10^{\circ}C$. Therefore, it is expected that fuel costs and carbon dioxide can be reduced when the same construction duration is considered.

The effect of using laser for ceramic bracket bonding of porcelain surfaces (세라믹 브라켓 부착 시 레이저를 이용한 포세린 표면처리 효과)

  • An, Kyung-Mi;Sohn, Dong-Seok
    • The korean journal of orthodontics
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    • v.38 no.4
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    • pp.275-282
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    • 2008
  • Objective: The purpose of this study was to investigate the effect of using laser for ceramic bracket bonding of porcelain surfaces and to compare it with conventional treatment of porcelain surfaces. Methods: Ninety feldspathic porcelain specimens were divided into 9 groups of 10, with each group having different surface treatments performed. Surface treatment groups were orthophosphoric acid, orthophosphoric acid with silane, hydrofluoric acid, hydrofluoric acid with silane, sandblasted, sandblasted with silane, laser etched, laser etched with silane, and glazed surface served as a control group. In the laser etched groups, the specimens were irradiated with 2-watt superpulse carbon dioxide ($CO_2$) laser for 20 seconds. Ceramic brackets were bonded with light-cure composite resin and all specimens were stored in water at $37^{\circ}C$ for 24 hours. Shear bond strength was determined in megapascals (MPa) by shear test at 1 mm/minute crosshead speed and the failure pattern was assessed. For statistical analysis, one-way ANOVA and tukey test were used. Results: Statistical analysis showed significant differences between the groups. The HFA + S group showed the highest mean shear bond strength ($13.92{\pm}1.94\;MPa$). This was followed by SB + S ($10.16\;{\pm}\;1.27\;MPa$), HFA ($10.09\;{\pm}\;1.07\;MPa$), L + S ($8.25\;{\pm}\;1.24\;MPa$), L ($7.86\;{\pm}\;0.96\;MPa$), OFA + S ($7.22\;{\pm}\;1.09\;MPa$), SB ($3.41\;{\pm}\;0.37\;MPa$), OFA ($2.81\;{\pm}\;0.37\;MPa$), G ($2.46\;{\pm}\;1.36\;MPa$), Bond failure patterns of HFA and silane groups, except L + S, were cohesive modes in porcelain while adhesive failure was observed in the control group and the rest of the groups. Conclusions : A 2-watt superpulse $CO_2$ laser etching of porcelain surfaces can provide a satisfactory result for porcelain surface treatment for ceramic bracket bonding. Laser irradiation may be an alternative conditioning method for the treatment of porcelain surfaces.

Short-term Variability of Carbon Dioxide within and across the Korean Peninsula: Case Study during 1995-1997 (이산화탄소의 단주기적 농도변화 특성)

  • Song, Ki-Bum;Youn, Yong-Hoon;Kim, Ki-Hyun
    • Journal of the Korean earth science society
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    • v.21 no.5
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    • pp.623-634
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    • 2000
  • This study was conducted to analyze the patterns associated with the short-term variability of CO$_2$ concentrations over 24-h scale within and across the Korean Peninsula. In the course of our study, we compared the data sets obtained from Moo-Ahn (MAN) station located in the far western coastal area of Korea with those determined from major background observatory stations around the world from the periods of Aug. 1995 to Dec. 1997. The mean CO$_2$ concentration of the MAN area for the whole study periods, when computed using the daily mean values, was found out to be 374.5${\pm}$6.6 ppm (N=884); seasonal mean values were found out to be 378${\pm}$5.2 (spring: N=181), 372${\pm}$10.2 (summer: N =210), 372${\pm}$7.2 (fall: N=243), and 376${\pm}$5.4 ppm (winter: N=206). When the data from MAN was compared with those of major background stations, the effects of both daily and seasonal components appear to vary distinctively across different stations. Those effects are expected to reflect the mixed effects of various factors which include: seasonal pollution patterns, weather conditions, vegetation, and so forth. Based upon this comparative analysis, we suspect that the MAN area is under the strong influence of anthropogenic source processes relative to all the other stations under consideration. If that is not the case, the existence of enhanced CO$_2$ level may be rather ubiquitous phenomena in Korea. More detailed inspection of CO$_2$ behavior from various respects is strongly desired in the future.

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Assessment of Conscious Coginition Degree and Survey on the Indoor Air Quality at a public School in Seoul (서울시 일부 학교의 실내 공기질 조사 및 인식도 평가)

  • Sohn, Jong-Ryeul;Byeon, Sang-Hoon;Kim, Young-Whan;Kim, Jong-Hyeok;Cho, Yun-Su;Lee, Jae-Young;Park, Youn-Ju
    • Journal of environmental and Sanitary engineering
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    • v.18 no.3 s.49
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    • pp.100-109
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    • 2003
  • Recently, Indoor air quality(IAQ) in workplace, residential environments and schools has been concern of people, scientists and related the public. And so in Seoul has recognized the healthy effect related to IAQ in schools. Therefore, the objective of this study reported in this article were to measure and compare the perception of IAQ of selected air pollutants at three different schools in Seoul. We performed a questionnaire survey of 400 students about their awareness for the importance of IAQ in our school. And we measured the IAQ of 3 schools considering as site region, construction year and studying level. The indoor air pollutants and parameters such as temperature, relative humidity, respirable particulate matter(PM10), formaldehyde(HCHO), total bacteria counts(TBC), carbon dioxide(CO$_2$), and noise were monitored in indoors. In results, all most response of occupant has recognized the awareness of IAQ at schools. The PMIO, TBC and Noise level of all schools were higher than the standard of the public 150 ${mu}$g/m$^3$ and 500CFU/m$^3$, the level formaldehyde(HCHO) was below 0.1 ppm of the healthy guideline of Korea And the concentration of CO$_2$ were investigated below 1,000 ppm of the standard implying ventilation in 2 schools except for 1 school(c school). Finally, the control of most important pollutants of IAQ in school were PM10, TBC and Noise. Therefore, it can be concluded that the indoor air quality of selected 3 schools studied was perceived as acceptable, it is recommended that the government related IAQ was suggested the guideline and control of IAQ problems in schools, and all member relating school need to be effort to reduce the exposure of sources to undesirable indoor pollutants such as Particlate and Noise.

Utilization of Egg-shell for Bread-making (제빵시 난각의 이용에 관한 연구)

  • Kim, Joong-Man;Kim, Yong-Seob;Yang, Hee-Chon;Choi, Yong-Bae
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.18 no.2
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    • pp.160-166
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    • 1989
  • This study was conducted to investigate whether egg-shell may be used as a mineral sourceor leavening agent in breadmaking. In Korea the waste volume of egg shell has been estimated at about 28,694 tons per year. Carbon dioxide generation maxima were established for barking powder$(153{\pm}3ml/g)$, egg-shell(205in reaction with lactic acid) and yeast$(115{\pm}3ml/sugar\;g)$. Gas release time required for each substance to reach $CO_2$ maximum was, for baking powder 7 minutes, for egg-shell 45 mins and for yeast 240 mins. Particle size of egg-shell in breadmaking was suitable more than 20 mesh (-). When egg-shell only was added to the basic formular without including lactic acid, no leavening effect was observed. However, when lactic acid and egg-shell were used together, the leavening effect was more or less equivalent to that of yeast(control). Addition of egg-shell was found to increase calcium content of bread products without noticeable altering flavor, as compared with control. Joint use of egg-shell was organic acids in breadmaking was shown to have potential in time saving, volume increase and yeast saving.

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Effect of Dietary Supplementation of Garlic and May Flower Powder on CO2 and CH4 Emission by Hanwoo Cow (산사 및 마늘 분말이 한우암소의 이산화탄소 및 메탄 발생량에 미치는 영향)

  • Kim, Du Ri;Ha, Jae Jung;Song, Young Han
    • Journal of Animal Science and Technology
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    • v.54 no.5
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    • pp.363-368
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    • 2012
  • This study was conducted to investigate the effects of dietary garlic and may flower powder on $CO_2$ and $CH_4$ emission by Hanwoo cows fed TMR (Total Mixed Ration) based diet. Animals were housed in a hood-type respiration chamber and the environmental temperature was maintained at $20^{\circ}C$. Gases were measured for 24 hours using the multi-detector instrument gas monitoring system (Mamos-300, Australia). The treatments composed of groups with no intake of garlic and may flower powder (Control), with intake of garlic at 0.5% of DM (T1), with intake of garlic at 1% of DM (T2), with intake of may flower at 0.5% of DM (T3), with intake of may flower at 1% of DM (T4), with intake of garlic and may flower at 0.5% of DM (T5) and with intake of garlic and may flower at 1% of DM (T6). The results indicated that $CO_2$ emission in T3 was 53% lower than that of control (p<0.05), and $CH_4$ emissions was 57% lower than control (p<0.05). Also, the hourly pattern of $CO_2$ and $CH_4$ emissions in T3 showed the least difference with all treatments. Gas emissions pattern peaked after 1 hour of feeding and this gap was wider in the afternoon than in the morning hours.

Blood Gas Management of a Membrane Oxygenator During Cardiac Surgery with Deep Hypothermic Circulatory Arrest (막형산화기에 의한 저체온 순환정지 심장수술시 혈액가스 조절)

  • Kim, W. G.;Lim, C.;Baek, Y. H.
    • Journal of Biomedical Engineering Research
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    • v.19 no.3
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    • pp.279-284
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    • 1998
  • Deep hypothermic circulatory arrest(DHCA), in which systemic temperatures of 2$0^{\circ}C$ or less are used to allow temporary cessation of the circulation, is an useful adjunct in cardiac surgery. Because man in natural circumstances is never exposed to the extreme hypothermic condition, however, one of the controversial aspects is appropriate blood gas management($\alpha$STAT versus PH-STAT) during DHCA. This study aims to compare $\alpha$STAT with PH-STAT management for control of blood gases in experimental cardiopulmonary bypass(CPB) circuits with a membrane oxygenator. Fourteen young pigs were assigned to one of two strategies of gas manipulation. After a median sternotomy, CPB was established. Core cooling was initiated and continued until nasopharyngeal temperature fell below 2$0^{\circ}C$. The flow rate was set at 2,500 ml/min. Once their temperatures were below 2$0^{\circ}C$, the animals were subjected to circulatory arrest for 40mins. During cooling, blood gas was maintained according to either $\alpha$$\alpha$STAT or pH-STAT strategies. After DHCA, the body was rewarmed to normal body temperature. Arterial blood gases were measured before the onset of CPB, before cooling, before DHCA, at the point of 27$^{\circ}C$ during re-warming, on completion of re-warming. Cooling time was significantly shorter in $\alpha$-STAT than PH-STAT strategy, while there was no significant differences in rewarming time between two groups. Carbon dioxide was added between 5.5 and 3.0% in PH-STAT, while no carbon dioxide was added in $\alpha$STAT management. Amounts of oxygen administration were gradually lowered as temperature decreased. In this way, criteria of PH, PaCO, and PaO adjustments were satisfied in both $\alpha$STAT and PH-STAT management groups.

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Applicability of CATIS as a Postharvest Phytosanitation Technology against the Peach Fruit Moth, Carposina sasakii Matsumura (복숭아심식나방(Carposina sasakil)의 수확 후 소독 처리로서 CATTS 기술의 적용 가능성)

  • Son, Ye-Rim;Choi, Kyung-Hee;Kim, Yong;Kim, Yong-Gyun
    • Korean journal of applied entomology
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    • v.49 no.1
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    • pp.37-42
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    • 2010
  • As an environment-friendly phytosanitary measure, CATTS (controlled atmosphere temperature treatment system) has been developed to kill several quarantine insect pests infesting subtropical agricultural commodities. This study tested any possibility to apply CATTS to apples to effectively eliminate the peach fruit moth, Carposina sasakii, which has been regarded as a quarantine insect from the imported countries. When the larvae of C. sasakii were directly exposed to $46^{\circ}C$ (an installed lethal temperature of CATTS), they showed a median lethal time at 14.66 min. Addition of high carbon dioxide to the temperature treatment enhanced the thermal limit susceptibility of C. sasakii to $46^{\circ}C$. CATTS device was constructed to automatically control $CO_2$ concentration and temperature with real-time monitoring both in the chamber and in the fruit. The larvae internally infesting apples were tested using the CATTS device and showed 100% lethality after 60 min exposure to a treatment of $46^{\circ}C$ under 15% $CO_2$ in the chamber. Relatively long exposure may be due to the deviation between the ramping temperature ($0.35^{\circ}C$/min) of the chamber and the ramping temperature (0.12-$0.23^{\circ}C$/min) inside apple fruit, where the tested larvae were located. This study suggests a possibility that CATTS can be applied as a quarantine measure to kill the larvae of C. sasakii locating inside the apples.

Normal Operation Characteristics of 30kW Scale CVCF Inverter-Based Micro-grid System (30kW급 CVCF 인버터 기반의 Micro-grid의 정상상태 운용특성에 관한 연구)

  • Ferreira, Marito;Lee, Hu-Dong;Tae, Dong-Hyun;Rho, Dae-Seok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.6
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    • pp.662-671
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    • 2020
  • Recently, for the purposes of reducing carbon dioxide(CO2) emissions in the island area, countermeasures to decrease the operation rate of diesel generator(DG) and to increase one of renewable energy sources(RES) is being studied. In particular, the demonstration and installation of stand-alone micro-grid(MG) system which is composed of DG, RES and energy storage system(ESS) has been implemented in some island areas such as Gapa-do, Gasa-do and Ulleung-do island. However, many power quality(PQ) problems may be occurred due to an intermittent output of RES including photovoltaic(PV) system and wind power(WP) system in a normal operating of constant voltage & constant frequency(CVCF) inverter-based MG system. Therefore, this paper presents a modeling of the 30kW scale MG system using PSCAD/EMTDC, and also implements a 30kW scale CVCF inverter-based MG system as test devices to analyze normal operating characteristics of MG system. From the simulation and test results, it is confirmed that the proposed methods are useful and practical tools to improve PQ problems such as under-voltage, over-voltage and unbalanced load in CVCF inverter-based MG system.