• Bulletin of the Korean Chemical Society
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• 제35권6호
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• pp.1619-1624
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• 2014

A new series of carbazole based 2,4-disubstituted thiazole derivatives were synthesized. All the synthesized compounds were tested for their cytotoxicity against three different cancer cell lines A549, MCF-7, and HT29. Some of these compounds showed good cytotoxicity. These compounds were also evaluated for antioxidant activity. Compounds 3a, 3b, 3d-f and 3i showed higher antioxidant activity than standard BHT.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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• pp.952-954
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• 2003

We report the photo-(PL) and electroluminescence (EL) properties of new conjugated compounds based on carbazolyl vinylene moiety, 3,3'-(1,4-phenylene di-2,1-ethenediyl) bis[9-ethyl-(E,E)-9H-carbazole](PEEC) and 3,3'-([1,1'-biphenyl]-4,4'-diyldi-2,1-ethenediyl)bis[9-ethyl-9H-carbazole](BPEEC), as emitting materials. The ITO/m-MTDATA/NPB/BPEEC/Alq3/LiF/Al device shows bluish-green EL spectrum at 490nm and turn-on voltage at 8V. PEEC shows bluish-green EL around ${\lambda}$ max=496nm and turn-on voltage at 6V and 2.4 Cd/A efficiency in ITO/m-MTDATA/NPB/PEEC/Alq3/LiF/Al device.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2010년도 하계학술대회 논문집
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• pp.58-58
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• 2010

We designed and synthesized DFPCE blue emitting materials by Mc Murry coupling reaction in order to improve the device efficiency and stability. The structure was confirmed by $^1H$-NMR. The physical properties were characterized by differential scanning calorimetry, thermogravimetric analysis, UV-vis, photoluminescence spectrum and cyclic voltammetry. The decomposition temperature of the material, which correspond to a 5% weight loss upon heating, is $513.58^{\circ}C$. The photoluminescence (PL) spectrum of DFPCE exhibited blue emission at 425 nm in chloroform solution and 462 nm in film.

• Transactions on Electrical and Electronic Materials
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• 제13권6호
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• pp.317-321
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• 2012

Poly[4,4'(3,3')-biphenylenevinylene-alt-2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene-vinylene], 4,4'(3,3')-PBPMEH-PPV, and poly[4,4'(3,3')-biphenylenevinylene-alt-N-ethylhexyl-3,6-carbazolevinylene], 4,4'(3,3')-PBPCAR-PPV, of varying effective conjugation lengths, were synthesized by the well-known Wittig condensation polymerization between the appropriate biphenyl diphosphonium salts and dialdehyde monomers such as carbazole or dialkoxyphenyl dialdehyde. The conjugation lengths of the polymers were controlled by biphenyl linkages (4,4' or 3,3'). The resulting polymers were highly soluble in common organic solvents and exhibited good thermal stability up to $300^{\circ}C$. The synthesized polymers showed UV-visible absorbance and photoluminescence (PL) in the ranges of 314-400 nm and 430-507 nm, respectively. Carbazole and 3,3'-biphenyl containing 3,3'-PBPCAR-PPV showed a blue PL peak at 430 nm. A single-layer light-emitting diode was fabricated in a configuration of ITO/polymer/Al. Electroluminescence (EL) emission of 3,3'-PBPCAR-PPV was shown at 455 nm.

• Bulletin of the Korean Chemical Society
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• 제33권6호
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• pp.1900-1906
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• 2012

Three carbazole chromophores featuring dicyano, cyano, ethyl acetate and dimethyl acetate groups as an acceptor moiety with a ${\pi}$-conjugated spacer and $N$-methyl dibenzo[$b$]pyrole as donor were synthesized by Knovenagel condensation and characterized by IR, $^1HNMR$, $^{13}CNMR$, UV-vis, fluorescence spectroscopy, electrochemistry and theoretical B3LYP/6-$311G^*$ level whilst NLO properties and spectroscopic quantities were calculated. Calculations showed remarkable trend with HOMO located on the donor moiety and LUMO on the acceptors dicyano methylene, cyano, ethyl acetate methylene and dimethyl acetate methylene. In agreement with the calculations, solvatochromic, behavior intramolecular charge transfer band was observed in the visible region.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 학술대회 논문집 전문대학교육위원
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• pp.120-124
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• 2002

Considerable progress has been made in organic photorefractive materials, since the first observation of photorefractive phenomena from organic materials. Within recent years, a large number of organic photorefractive materials, especially amorphous materials. have been developed based on polymeric composites, fully functional polymers and the multifunctional chromophore approach. Among these organic photorefractive materials, some of them containing carbazole components as a charge transporting function have been demonstrated to exhibit high performance photorefractive effects. The carbazole building blocks with charge transporting functionality or multifunctions play a very important role in photorefraction and have been widely used in the molecular design approach to new organic photo- refractive materials.

• Bulletin of the Korean Chemical Society
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• 제21권7호
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• pp.701-704
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• 2000

Fluorene and carbazole-containing distyrylarylene model and polymeric fluorophores were prepared by reacting 2,7-dibromo-9-butylfluorene and 3,6-dibromo-9-butylcarbazole with styrene and divinylbenzene using the Heck reaction for the chemiluminesc ence. The UV-vis absorbance, photoluminescence (PL) as well as the chemiluminescence (CL) characteristics of the model and polymeric fluorophores were measured. Sodium salicylate-catalyzed reaction of bis(2,4,6-trichlorophenyl)oxalate (TCPO) with hydrogen peroxide produced a strong chemiluminescent blue light emission with 439-489 nm in the presence of the fluorophore. The wave-length of CL light was similar to that of photoluminescence. The chemiluminescent intensity was decayed according to the exponential equation.The glow of CL maintained more than 12 hr and was visible with naked eye.

• Bulletin of the Korean Chemical Society
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• 제20권4호
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• pp.451-455
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• 1999

The polymerization of 2-ethynylpyridine by alkyl bromide carrying carbazole moiety, 6-(N-carbazolyl)hexyl bromide, relatively proceed well to give the corresponding poly[6'-(N-carbazolyl)hexyl-2-ethynylpyridinium bromide) in high yields under DMF reflux conditions without any initiator or catalyst. This polymerization was influenced upon the initial monomer concentration. The polymer yields and inherent viscosities of the resulting polymers were in the range of 34-85% and 0.11-0.21 dL/g, respectively. Instrumental analyses using NMR, IR, and UV-visible spectroscopies and elemental analysis indicated that the resulting polymer has a conjugated polymer backbone system carrying pyridine and n-hexyl carbazole moiety. The polymers were mostly brown powders and completely soluble in DMF, DMSO, nitrobenzene, and formic acid. The photoluminescence spectrum of the dilute polymer solution with the excitation at 383 nm exhibited two sharp peaks at 495 and 540 nm.

• 공업화학
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• 제32권2호
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• pp.180-189
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• 2021

Cu(I) 촉매를 사용하여 열반응을 이용한 N-heteroaryl carbazole을 합성하였고 이를 새로운 heteroleptic Ir(III) 착물 합성을 위한 주리간드로 사용하였다. 새로운 Ir(III) 착물은 일반적인 Ir(III) 착물이 가지는 5각 고리가 아닌 6각 고리를 주리간드와 Ir 금속 결합 사이에서 형성하는 것으로 X-ray 단결정구조를 통해 확인할 수 있었다. 합성한 Ir(III) 착물들은 좋은 인광 특성을 나타내므로 OLED 발광층 재료물질로의 가능성을 보여주었다. 주리간드와 보조리간드 변화에 따른 분광학적 특성을 고찰하였는데 PL 최대 발광 파장(λmax) 변화는 보조리간드가 Ir 금속과 더 강한 결합을 만들수록 단파장 쪽으로 이동하는 것을 발견하였다. 또한, 주리간드에 대해서는 Ir-N 결합을 만드는 헤테로아릴 그룹의 아로마틱고리 전자밀도가 커질수록 단파장 쪽으로 이동하는 경향이 있는 것을 알 수 있었다.

• 공업화학
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• 제24권4호
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• pp.396-401
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• 2013

Benzo[1,2,5]thiadiazole, carbazole 및 phenanthrene을 기본 골격으로 한 교대공중합체인 poly[9-(2-octyl-dodecyl)-9H-carbazole-alt-4,7-di-thiophen-2-yl-benzo[1,2,5]thiadiazole] (PCD20TBT)와 poly[9,10-bis-(2-octyl-dodecyloxy)-phenanthrene-alt-4,7-di-thiophen-2-yl-benzo[1,2,5]thiadiazole] (PN40TBT)을 Suzuki coupling reaction을 이용하여 중합하였다. 합성한 고분자들은 chloroform, chlorobenzene, 1,2-dichlorobenzene, tetrahydrofuran, toluene과 같은 유기용매에 대한 용해도가 우수하였다. PCD20TBT의 최대흡수 파장과 밴드갭은 각각 535 nm와 1.75 eV이고, PN40TBT의 최대흡수 파장과 밴드갭은 각각 560 nm과 1.97 eV이었다. PCD20TBT의 HOMO 및 LUMO 에너지준위는 각각 - 5.11 eV와 - 3.36 eV이고, PN40TBT의 HOMO 및 LUMO 에너지준위는 각각 -5.31 eV와 -3.34 eV이었다. 합성한 고분자와 (6)-1-(3-(methoxycarbonyl)-{5}-1-phenyl[5,6]-fullerene(PCBM)을 1:2의 중량비로 블랜딩하여 제작한 이종접합형태(bulk heterojunction) 태양전지를 제작하였다. PCD20TBT의 광전변환효율은 0.52%, PN40TBT의 광전변환효율은 0.60%이었다. 그리고 소자의 단락 전류밀도, 충진 인자와 개방전압은 PCD20TBT가 각각 $-1.97mA/cm^2$, 38.2%, 0.69 V이며, PN40TBT의 경우 각각 $-1.77mA/cm^2$, 42.9%, 0.79 V이었다.