• Title/Summary/Keyword: capillary absorption

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Development of Polymer-Concrete Composite(I) - Physical Properties of Polymer-Cement Concrete Composites - (폴리머-콘크리트 복합재료 개발(I) - 폴리머-시멘트 콘크리트의 물성 -)

  • Hwang, Eui-Hwan;Kil, Deog-Soo;Oh, In-Seok
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.979-984
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    • 1997
  • Test specimens of polymer-cement concrete composites were prepared using styrene-butadiene rubber(SBR) latex, ethylenevinyl acetate(EVA) and polyacrylic ester(PAE) emulsions as polymer dispersions in cement modified system at constant slump($10{\pm}0.5cm$), then compressive and flexural strengths water absorption, pore size distribution, and microstructures were investigated. Compressive and flexural strengths of these composites were remarkably improved with an increase of polymer-cement ratio. These composites had a desirable pore size distribution against frost damage due to a small capillary pore volume. Continuous polymer film was able to form in higher than 15% of polymer cement ratio.

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Detection of electromagnetic interference shielding effect of Hanji mixed with carbon nanotubes using nuclear magnetic resonance techniques

  • Byun, Young Seok;Chae, Shin Ae;Park, Geun Yeong;Lee, Haeseong;Han, Oc Hee
    • Carbon letters
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    • v.27
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    • pp.90-97
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    • 2018
  • Electromagnetic interference (EMI) shielding is an important issue in modern daily life due to the increasing prevalence of electronic devices and their compact design. This study estimated EMI-shielding effect (EMI-SE) of small ($8-14{\times}17mm$) Hanji (Korean traditional paper) doped with carbon nanotubes (CNTs) and compared to Hanji without CNT using $^2H$ (92.1 MHz) and $^{23}Na$ (158.7 MHz) nuclear magnetic resonance (NMR) peak area data obtained from 1 M NaCl in $D_2O$ samples in capillary tubes that were wrapped in the Hanji samples. The simpler method of using the variation of reflected power and tuning frequency by inserting the sample into an NMR coil was also tested at 242.9, 158.7, and 92.1 MHz. Overall, EMI shielding was relatively more effective at the higher frequencies. Our results validated that NMR methods to be useful to evaluate EMI-SE, particularly for small, flexible shielding materials, and demonstrated that EMI shielding by absorption is dominant in Hanji mixed with CNT.

Influence of Iranian low-reactivity GGBFS on the properties of mortars and concretes by Taguchi method

  • Ramezanianpour, A.A.;Kazemian, A.;Radaei, E.;AzariJafari, H.;Moghaddam, M.A.
    • Computers and Concrete
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    • v.13 no.4
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    • pp.423-436
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    • 2014
  • Ground Granulated Blast Furnace Slag (GGBFS) is widely used as an effective partial cement replacement material. GGBFS inclusion has already been proven to improve several performance characteristics of concrete. GGBFS provides enhanced durability, including high resistance to chloride penetration and protection against alkali silica reaction. In this paper results of an experimental research work on influence of low-reactivity GGBFS (which is largely available in Iran) on the properties of mortars and concretes are reported. In the first stage, influence of GGBFS replacement level and fineness on the compressive strength of mortars was investigated using Taguchi method. The analysis of mean (ANOM) statistical approach was also adopted to develop the optimal conditions. Next, based on the obtained results, concrete mixtures were designed and water penetration, capillary absorption, surface resistivity, and compressive strength tests were carried out on highstrength concrete specimens at different ages up to 90 days. The results indicated that 7-day compressive strength is adversely affected by GGBFS inclusion, while the negative effect is less evident at later ages. Also, it was inferred that use of low-reactivity GGBFS (at moderate levels such as 20% and 30%) can enhance the impermeability of high-strength concrete since 28 days age.

Industrialization possibilities of purified pig sperm hyaluronidase

  • Soojin Park;In-Soo Myeong;Gabbine Wee;Ekyune Kim
    • Journal of Animal Science and Technology
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    • v.65 no.6
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    • pp.1205-1213
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    • 2023
  • The goals of the present study were to develop a simple method for obtain highly purified pig sperm hyaluronidase (pHyase) and to assess its activity, function, and safety. In mammals, sperm-specific glycophosphatidylinositol (GPI)-anchored Hyase assists sperm penetration through the cumulus mass surrounding the egg and aids in the dispersal of the cumulus-oocyte complex. Recently, Purified bovine sperm hyaluronidase (bHyase) has been shown to enhance therapeutic drug transport by breaking down the hyaluronan barrier to the lymphatic and capillary vessels, thereby facilitating tissue absorption. Commercially available Hyase is typically isolated from bovine or ovine; which have several disadvantages, including the risk of bovine spongiform encephalopathy, low homology with human Hyase, and the requirement for relatively complex isolation procedures. This study successfully isolated highly purified pHyase in only two steps, using ammonium sulfate precipitation and fast protein liquid chromatography. The isolated Hyase had activity equal to that of commercial bHyase, facilitated in vitro fertilization, and effectively dissolved high molecule hyaluronic acid. This simple, effective isolation method could improve the availability of pHyase for research and clinical applications.

Paper-based Electrochemical Sensor Using a Self-operated Paper Pump (자발 구동형 종이 펌프를 이용한 종이 전기화학 센서)

  • Si Hiep Hua;Chikwan Kim;Duc Cuong Nguyen;Yong Shin Kim
    • Journal of Sensor Science and Technology
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    • v.33 no.3
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    • pp.158-164
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    • 2024
  • We developed a self-operated paper pump that can maintain a nearly constant flow rate of an aqueous solution along a paper strip channel in paper-based analytical devices (PADs). The quasi-stationary flow rate was controlled by increasing the crosssectional channel area (capillary force) using a fan-shaped absorption pad coupled with a paper strip channel. The flow rate is regulated by varying the fan angle of the circular absorbing pad. Furthermore, the flow rate can be increased by furnishing a hollow cavity at the center of a conventional paper strip channel. The rate was regulated by varying the length of the hollow paper channel in the flow rate range of 5.1-26.4 mm/min. As a preliminary work, a paper-pump-coupled PAD was fabricated, and its CV detection capability was evaluated for the redox reaction of Fe(CN)6+4/+3. The combination of a paper pump with a PAD resulted in an ideal CV curve with a higher limiting current and faster response time. These results are interpreted well by the Levich equation, which suggests that the paper pump is a very useful component in paper-based sensors.

Radioanalytical and Spectroscopic Characterizations of Hydroxo- and Oxalato-Am(III) Complexes (방사분석과 분광학을 이용한 Am(III) 가수분해와 옥살레이트 착물 화학종 연구)

  • Kim, Hee-Kyung;Cho, Hye-Ryun;Jung, Euo Chang;Cha, Wansik
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.4
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    • pp.397-410
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    • 2018
  • When considering the long-term safety assessment of spent-nuclear fuel management, americium is one of the most radio-toxic actinides. Although spectroscopic methods are widely used for the study of actinide chemistry, application of those methods to americium chemistry has been limited. Herein, we purified $^{241}Am$ to obtain a highly pure stock solution required for spectroscopic studies. Quantitative and qualitative analyses of purified $^{241}Am$ were carried out using liquid scintillation counting, and gamma and alpha radiation spectrometry. Highly sensitive absorption spectrometry coupled with a liquid waveguide capillary cell and time-resolved laser fluorescence spectroscopy were employed for the study of Am(III) hydrolysis and oxalate (Ox) complexation. $Am^{3+}$ ions under acidic conditions exhibit maximum absorbance at 503 nm, with a molar absorption coefficient of $424{\pm}8cm^{-1}{\cdot}M^{-1}$. $Am(OH)_3(s)$ colloidal particles formed under near neutral pH conditions were identified by monitoring the absorbance at around 506-507 nm. The formation of ${Am(Ox)_3}^{3-}$ was detected by red-shifts of the absorption and luminescence spectra of 4 and 5 nm, respectively. In addition, considerable enhancements of the luminescence intensities were observed. The luminescence lifetime of ${Am(Ox)_3}^{3-}$ increased from 23 to 56 ns, which indicates that approximately six water molecules are replaced by carboxylate ligands in the inner-sphere of the Am(III). These results suggest that ${Am(Ox)_3}^{3-}$ is formed through the bidentate coordination of the oxalate ligands.

Development of Membrane Strip Assay System for Lipoprotein Cholesterol Based on Liquid-Phase Enzyme Reactions (액상 효소반응을 이용한 Membrane Strip 형 Cholesterol 측정시스템의 개발)

  • 신인수;목락선;장미라;백세환
    • KSBB Journal
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    • v.13 no.5
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    • pp.577-584
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    • 1998
  • A sensitive membrane strip assay for plasma lipoprotein cholesterol that can be performed without handling reagents has been investigated. We previously developed an assay system with immobilized enzymes (cholesterol esterase and cholesterol oxidase) on the surfaces of nitrocellulose membrane(1). In such a case, the amount of enzymes present on the membrane was limited by its surface area and, thus, the detection capability was relatively poor (> 50 mg/dL cholesterol). To overcome this problem, we devised a new system with non-immobilized enzymes by placing them within interstitial spaces of a celullose membrane pad in a dry state. Upon contact with sample medium, the enzymes were immediately dissolved and participated in the reactions with cholesterol in a liquid phase. We constructed a user-friendly system consisting of four membrane pads fro sample application, cholesterol decomposition, color development as signal, and medium absorption to invoke a continuous flow (sequential location from the bottom). A sample containing lipoproteins was added into the application pad by capillary action and transferred to the next pad for decomposition. The decomposition pad (namely, enzyme pad) contained a detergent (sodium cholate) for the destruction of lipoprotein particles, the two enzymes for cholesterol decomposition, and a chromogen (3,3'-diaminobenzidine). As a consequence of the enzyme reactions, hydrogen peroxide was produced, and then reacted in the presence of the chromogen with horseradish peroxidase immobilized on the signal generation pad. Finally, a colorimetric signal directly proportional to the cholesterol concentration was produced. The detection limit determined from this system under optimal conditions was at least 2 times lower than of the enzyme-immobilized system.

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An Experimental Study on the Basic Properties of Penetrating repair material using Silicate-based Inorganic Materials (규산염계 무기 재료를 활용한 침투성 보수재의 기초 특성에 관한 실험적 연구)

  • Ha, Sang-Woo;Oh, Sung-Rok;Choi, Yung-Wang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.7
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    • pp.39-45
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    • 2017
  • In this study, permeable repair materials mainly composed of silicate - based inorganic materials(SIM), which are easily available domestically, were prepared as a basic study for the development of permeable repair materials using SIM. SIM were compared and examined for their performance as repair materials by selecting a product group which has many cases of use in foreign countries. The SIM used were mainly composed of sodium, potassium and lithium silicate. Performance evaluation of SIM was performed by absorption and penetration, compression and adhesion, rapid chloride ion penetration, rapid freezing and thawing, and chemical resistance test. According to the test results, SIM showed effective performance in all areas, mainly because SIM permeates into the interior of the capillary and has a dense internal microstructure. Therefore, it can be used variously to improve the durability of concrete based on the results of this experiment.

A Study on the Application of SILRES BS OH 100 Consolidants for Shale (셰일에 대한 SILRES BS OH 100 강화제 적용연구)

  • Lee, Sang-Jin;Kim, Jin-Hyung;Do, Jin-Young
    • Journal of Conservation Science
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    • v.21
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    • pp.33-40
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    • 2007
  • The consolidation application of SILRES BS OH 100 was investigated, which has been used for consolidation of the weathered shale. The liquid SILRES BS OH 100 was polymerized by the sol-gel reaction with air moisture, and the XRD patterns showed that the gel was an amorphous solid. The drastic weight reduction of the sample was found by differential thermal analysis, which was followed to the formation of $Si(OH)_4$ particles. After consolidation, the polymerized gel was filled into the voids within the shale. The capillary water absorption of the consolidated shale was reduced to 48.7%, and the abrasive strength was improved.

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Development of a Method for Rapid Analysis of DNA Hybridization (측방유동방식 신속 DNA 교잡 분석법의 개발)

  • 정동석;최의열
    • Korean Journal of Microbiology
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    • v.39 no.2
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    • pp.114-117
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    • 2003
  • In molecular biology, it is necessary to develop an easy and rapid method to identify a specific DNA sequence. Though Southern and Northern blot techniques have been used widely for the analysis of gene structure and function, those methods are inconvenient in the points that we need to control incubation temperature, time, and other parameters to get the final result. In this study, we report a new method for the rapid analysis of specific DNA sequence with the modification of an immunochromatographic method. The lateral flow DNA analysis strip is composed of a sample pad, a nitrocellulose membrane for the separation and propagation of analytes, and an absorption pad for the generation of capillary action. Capture DNA was immobilized on the membrane by UV cross-linking and target DNA was labeled with Cy-5 for signaling. The samples containing target DNA were applied onto the sample pad, incubated for 15 min for separation, and scanned with a GSI fluorescence scanner. Though the hybridization reaction occurs in a short time without any washing steps, there appears to be little cross hybridization between the different sequences. The result showed a possibility that the new method can be used for the rapid identification of specific DNA sequence among the samples.