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Corrosion of Steel in Blended Concretes Containing OPC, PFA, GGBS and SF

  • Song, Ha-Won;Lee, Chang-Hong;Lee, Kewn Chu
    • Corrosion Science and Technology
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    • v.8 no.5
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    • pp.171-176
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    • 2009
  • The chloride threshold level (CTL) in mixed concrete containing, ordinary Portland cement (OPC), pulverized fuel ash (PFA) ground granulated blast furnace slag (GGBS), and silica fume (SF) is important for study on corrosion of reinforced concrete structures. The CTL is defined as a critical content of chloride at the steel depth of the steel which causes the breakdown of the passive film. The criterion of the CTL represented by total chloride content has been used due to convenience and practicality. In order to demonstrate a relationship between the CTL by total chloride content and the CTL by free chloride content, corrosion test and chloride binding capacity test were carried out. In corrosion test, Mortar specimens were cast using OPC, PFA, GGBS and SF, chlorides were admixed ranging 0.0, 0.2, 0.4, 0.8, 1.0, 1.5, 2.0, 2.5 and 3.0% by weight of binder. All specimens were cured 28 days, and then the corrosion rate was measured by the Tafel's extrapolation method. In chloride binding capacity, paste specimens were casting using OPC, PFA, GGBS and SF, chlorides were admixed ranging 0.1, 0.2, 0.3, 0.5, 1.0, 1.5, 2.0, 2.5 and 3.0% by weight of binders. At 28days, solution mixed with the powder of ground specimens was used to measure binding capacity. All specimens of both experiments were wrapped in polythene film to avoid leaching out of chloride and hydroxyl ions. As a result, the CTL by total chloride content ranged from 0.36-1.44% by weight of binders and the CTL by free chloride content ranged from 0.14-0.96%. Accordingly, the difference was ranging, from 0.22 to 0.48% by weight of binder. The order of difference for binder is OPC > 10% SF > 30% PFA > 60% GGBS.

Resistance of Cementitious Binders to Chloride Induced Corrosion of Embedded Steel by Electrochemical and Microstructural Studies

  • Song, Ha-Won;Ann, Ki-Yong;Kim, Tae-Sang
    • Corrosion Science and Technology
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    • v.8 no.2
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    • pp.74-80
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    • 2009
  • The high alkaline property in the concrete pore solution protects the embedded steel in concrete from corrosion due to aggressive ions attack. However, a continuous supply of those ions, in particular, chlorides altogether with a pH fall in electrochemical reaction on the steel surface eventually depassivate the steel to corrode. To mitigate chloride-induced corrosion in concrete structures, finely grained mineral admixtures, for example, pulverized fuel ash (PFA), ground granulated blast furnace slag (GGBS) and silica fume (SF) have been often advised to replace ordinary Portland cement (OPC) partially as binder. A consistent assessment of those partial replacements has been rarely performed with respect to the resistance of each binder to corrosion, although the studies for each binder were extensively looked into in a way of measuring the corrosion rate, influence of microstructure or chemistry of chlorides ions with cement hydrations. The paper studies the behavior of steel corrosion, chloride transport, pore structure and buffering capacity of those cementitious binders. The corrosion rate of steel in mortars of OPC, 30% PFA, 60% GGBS and 10% SF respectively, with chloride in cast ranging from 0.0 to 3.0% by weight of binder was measured at 7, 28 and 150 days to determine the chloride threshold level and the rate of corrosion propagation, using the anodic polarization technique. Mercury intrusion porosimetry was also applied to cement pastes of each binder at 7 and 28 days to ensure the development of pore structure. Finally, the release rate of bound chlorides (i.e. buffering capacity) was measured at 150 days. The chloride threshold level was determined assuming that the corrosion rate is beyond 1-2 mA/$m^3$ at corrosion and the order of the level was OPC > 10% SF > 60% GGBS > 30% PFA. Mercury intrusion porosimetry showed that 10% SF paste produced the most dense pore structure, followed by 60% GGBS, 30% PFA and OPC pastes, respectively. It was found that OPC itself is beneficial in resisting to corrosion initiation, but use of pozzolanic materials as binders shows more resistance to chloride transport into concrete, thus delay the onset of corrosion.

Feasibility Evaluation of Lane Grouping Methods for Signalized Intersection Performance Index Analysis in KHCM (도로용량편람 신호교차로 성능지표 분석을 위한 차로군 분류의 적정성 평가)

  • Kim, Sang-Gu;Yun, Ilsoo;Oh, Young-Tae;Ahn, Hyun-Kyung;Kwon, Ken-An;Hong, Doo-Pyo
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.13 no.1
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    • pp.109-126
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    • 2014
  • The level of service (LOS) of the Highway Capacity Manual (KHCM) has been used as a basic criterion at decision making processes for signalized intersections in Korea. The KHCM provides five steps for the signalized intersection analysis. Among them, lane grouping, which is the third step, significantly influence the final LOS. The current method presented in the KHCM, however, classifies a shared lane as a de facto turning lane group, even though the turning traffic of the shared lane is few. Thus, this research was initiated to provide an alternative. To this end, three alternatives were suggested, including the method based on the lane grouping presented in the U.S. Highway Capacity Manual, the method using turning ratio of shared turning lane, and the method using a threshold traffic volume in lane grouping. The feasibilities of the three methods were evaluated using a calibrated CORSIM model. Conclusively, the method using a threshold traffic volume in lane grouping outperformed.

Construction of Optimal Concatenated Zigzag Codes Using Density Evolution with a Gaussian Approximation

  • Hong Song-Nam;Shin Dong-Joon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.31 no.9C
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    • pp.825-830
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    • 2006
  • Capacity-approaching codes using iterative decoding have been the main subject of research activities during past decade. Especially, LDPC codes show the best asymptotic performance and density evolution has been used as a powerful technique to analyze and design good LDPC codes. In this paper, we apply density evolution with a Gaussian approximation to the concatenated zigzag (CZZ) codes by considering both flooding and two-way schedulings. Based on this density evolution analysis, the threshold values are computed for various CZZ codes and the optimal structure of CZZ codes for various code rates are obtained. Also, simulation results are provided to conform the analytical results.

Characteristics and Useful Life Prediction of Rubber Spring for Railway Vehicle (전동차용 방진고무스프링 특성 및 사용수명 예측)

  • Woo, Chang-Su;Park, Hyun-Sung;Park, Dong-Chul
    • Journal of the Korean Society for Railway
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    • v.10 no.2 s.39
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    • pp.211-216
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    • 2007
  • Rubber components are widely used in many application such as vibration isolators, damping, ride quality. Rubber spring is used in primary suspension system for railway vehicle. Characteristics and useful life prediction of rubber spring was very important in design procedure to assure the safety and reliability. Non-linear properties of rubber material which are described as strain energy function are important parameter to design and evaluate of rubber spring. These are determined by physical tests which are uniaxial tension, equi-biaxial tension and pure shear test. The computer simulation was executed to predict and evaluate the load capacity and stiffness for rubber spring. In order to investigate the useful life, the acceleration test were carried out. Acceleration test results changes as the threshold are used for assessment of the useful life and time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. By using the acceleration test, several useful life prediction for rubber spring were proposed.

Evaluation of Characteristics and Useful Life of Rubber Spring for Railway Vehicle

  • Woo, Chang-Su;Park, Hyun-Sung;Park, Dong-Chul
    • International Journal of Railway
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    • v.1 no.3
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    • pp.122-127
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    • 2008
  • Rubber components are widely used in many application such as vibration isolators, damping, ride quality. Rubber spring is used in primary suspension system for railway vehicle. Characteristics and useful life prediction of rubber spring was very important in design procedure to assure the safety and reliability. Non-linear properties of rubber material which are described as strain energy function are important parameter to design and evaluate of rubber spring. These are determined by physical tests which are uniaxial tension, equi-biaxial tension and pure shear test. The computer simulation was executed to predict and evaluate the load capacity and stiffness for rubber spring. In order to investigate the useful life, the acceleration test were carried out. Acceleration test results changes as the threshold are used for assessment of the useful life and time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. By using the acceleration test, several useful life prediction for rubber spring were proposed.

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Characteristics Evaluation and Useful Life Prediction of Rubber Spring for Railway Vehicle (전동차용 방진고무스프링 특성평가 및 사용수명 예측)

  • Woo, Chang-Su;Park, Dong-Chul
    • Proceedings of the KSR Conference
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    • 2006.11b
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    • pp.104-111
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    • 2006
  • The non-linear properties of rubber material which are described as strain energy function are important parameter to design and evaluate of rubber spring. These are determined by material tests which are uni-axial tension and bi-axial tension. The computer simulation using the nonlinear element analysis program executed to predict and evaluate the load capacity and stiffness for chevron spring. In order to investigate the heat-aging effects on the rubber material properties, the acceleration test were carried out. Compression set results changes as the threshold are used for assessment of the useful life and time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. By using the compression set test, several useful life prediction for rubber material were proposed.

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Study of Transient Control of Nonlinear Dynamically Induced Instabilities in Brillouin-Active Fiber (브릴루앙 산란에서 유발되는 비선형적인 불안정 현상에 대한 제어연구)

  • Kim, Yong-K.;Kim, Jin-Su;Park, Jae-Wan
    • Proceedings of the KIEE Conference
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    • 2004.11a
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    • pp.141-143
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    • 2004
  • In this present the transient control of SBS chaos induced instability in Brillouin-active fiber systems is described. The inherent optical feedback by the backscattered Stokes wave in optical fiber systems leads to instabilities in the form of optical chaos. At weak power, the nature of the Brillouin instability can occur at before threshold. At strong power, the temporal evolution above threshold is periodic and at higher intensity can become chaotic. Multistable periodic states, makes transition to logic 'on' or 'off'. It can make theoretically potential large memory capacity.

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Systematic Study of Fluorescein-Functionalized Macrophotoinitiators for Colorimetric Bioassays

  • Lee, Jeong-Gyu;Han, Gyeong-Yeop;Go, Sang-Won;Sikes, Hadley D.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.263.2-263.2
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    • 2013
  • We report a systematic investigation of a set of macrophotoinitiators for use in polymerization-based signal amplification. To test the dependence of photopolymerization responses on the number of photoinitiators localized per molecular recognition event, we gradually increased the number of photoinitiator molecules coupled to a scaffold macromolecule. Macrophotoinitiators constructed with an average of 7 to 168 photoinitiators per polymer with the goals of quantifying the relationship between the number of initiators per binding event and the degree of amplified colorimetric readout. To evaluate the capacity of the macrophotoinitiators to detect molecular recognition, neutravidin was coupled to these molecules to recognize biotin-labeled DNA immobilized on biochip test surfaces. Fluorescein macroinitiators are found to be useful in detecting molecular recognition above a threshold of initiators per polymer. Above this threshold, increasing the number of initiators per macroinitiator resulted in increased signal strength.

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Effects of Cardiac Rehabilitation in Elderly Patients After Myocardial Infarction (노인 심근경색 환자에서의 심장재활의 효과)

  • KIM, JI HEE
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.464-471
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    • 2016
  • To investigate the effects of cardiac rehabilitation (CR) on cardiopulmonary exercise capacity in both elderly and younger patients with myocardial infarction (MI). Of the MI patients who received hospital-based CR between February 2012 and December 2015, we retrospectively reviewed the medical records of patients who continued a follow-up through the outpatient clinic. A total of 46 patients (18 elderly patients (${\geq}60years$) and 28 younger patient (< 60)) were included in this study. The subjects visited the clinic to perform aerobic exercises with ECG monitoring based on their initial exercise tolerance test outcome. The exercise capacity was measured by symptom-limited exercise tests before and after hospital-based CR. Before CR, the elderly group had a significantly lower exercise capacity in peak VO2, METs, anaerobic threshold, exercise time, respiratory exchange ratio (RER) than the younger group. After CR, elderly groups showed a significantly improved exercise capacity in exercise time, HRmax, HRrest, peak VO2, METs, anaerobic threshold, and RER. Both elderly and younger groups showed similar improvement of cardiopulmonary exercise capacity after hospital-based CR. There is a very low cardiac rehabilitation participation and referral rates with MI patients in Korea. It is considered necessary to further expand the participation of cardiac rehabilitation in elderly MI patients.