• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.11a
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• pp.310-313
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• 2000

Polyaniline Emeraldine Base (PANI EB) polymerized by chemical oxidative polymerization was doped with Camphorsulfonic Acid(CSA). Polyaniline-Camphorsulfonic Acid Emeraldine Salt(PANI-CSA ES) solutions were solved in organic solvents and sonificated at the room temperature for different solvents in PANI-CSA ES solution and sonification time. PANI-CSA ES solutions was coated on PET films using bar coater. 1-Step oxidatively-polymerized Polyaniline-Camphorsulfonic Acid Emeraldine Salt(PANI-CSA ES) was solved in m-cresol:chloroform 1:1 co-solvents and their solution was bar-coated on PET film. The surface resistivities of these coated films were measured, The surface resistivity of PANI-CSA ES solution in m-cresol:chloroform 1:1 co-solvent system was 5${\times}$10$^2$$\Omega$/$\square$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.11a
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• pp.215-218
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• 1998

The thermal stability of polyaniline-camphorsulfonic acid(PANI-CSA) film was studied as a function of temperature and time. A decrease in electrical conductivity of PANI-CSA film occurred when PANI-CSA film is subjected to temperature above 60$^{\circ}C$. From the result of thermogravimetry (TG), it was thought that the deterioration in electrical conductivity of PANI-CSA film was due to evaporation of water and residual solvent.

• Proceedings of the Korean Fiber Society Conference
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• 1996.04a
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• pp.234-236
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• 1996

• Journal of the Korean Chemical Society
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• v.58 no.5
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• pp.456-462
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• 2014

Binary-doped conducting chiral polyaniline (PAni) was synthesized by electrochemical polymerization of aniline at low-temperature ($0^{\circ}C$) and room-temperature (RT) conditions. (+)-Camphorsulfonic acid (CSA) and hydrochloric acid (HCl) were used as a binary dopant. Formation of the binary-doped PAni rather than a mixture of the corresponding single-doped PAni was confirmed by cyclic voltammogram, FT-IR and circular dichroism spectra. The temperature influenced the electrochemical behavior and doping level, thus determining the crystallinity and morphology of the PAni. However, among other results, morphology of the PAni is found to be most strongly depends on the polymerization temperature. With increased temperature from the initial state to RT, morphology of the PAni changed from fibrous to short-fibrous structure. The sheet resistance of the PAni films on an ITO was measured by using four-point probe dc method.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.3
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• pp.215-222
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• 2001

Polyaniline-Camphorsulfonic Acid Emeraldine Salt(PANI-CSA ES) was prepared by doping Polyaniline Ermeralidine Base(PANI EB) with DL-10-Camphorsulfonic Acid(CSA). PANI-CSA ES was solved in an organic solvent by ultrasonification for different periods of time and its surface resistivity was measured. Several PANI-CSA ES solutions solved in different organic solvents were prepared and their surface resistivities were measured. Thermal stability of film casted with PANI-CAS ES solution in m-cresol was estimated by measuring its surface conductivity and the content of this moisture and organic solvents. PANI-CSA ES was blended with different polymeric binders to improve its physical properties and the surface resistivities of several kinds of PANI-CSA ES blends were measured as a function of the content of PANI-CSA ES. PANI-CSA ES polymerized by 1-step oxidative polymerization was prepared and its surface resistivity was measured.

• Applied Chemistry for Engineering
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• v.9 no.7
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• pp.979-984
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• 1998

The conducting composites were prepared by blending of polyaniline(PANI) as conducting polymer and nylon6,6 as matrix in m-cresol. The PANI was protonated with alkylbenzenesulfonic acid such as camphorsulfonic acid(CSA) or dodecylbenzenesulfonic acid(DBSA). The miscibility of the composites was improved and the electrical conductivity was increased by adding dioctylphthalate(DOP). The electrical conductivity of the composites depending on the amount of protonating agent and PANI complex and the morphology were investigated. When it was protonated with DBSA having long alkyl chain and the content of PANI complex was 25 wt%, the electrical conductivity of the compsosite was increased up to 1.02 S/cm.

• Applied Chemistry for Engineering
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• v.10 no.2
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• pp.281-286
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• 1999

The conducting composites were prepared by blending polypyrrole (PPy) as a conducting polymer and nylon6,6 as a matrix. In chemical polymerization of PPy, the oxidizing agent was $FeCl_3$ and dopant was alkylbenzenesulfonic acid, such as camphorsulfonic acid (CSA) or dodecylbenzene sulfonic acid (DBSA). The electrical conductivity and mechanical properties were measured for the amount of dopant and PPy complex, and these morphology observed. When it was doped with DBSA having long alkyl chain and added the PPy complex of 25 wt %, the electrical conductivity was increased up to 0.64 S/cm.

• Macromolecular Research
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• v.13 no.3
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• pp.187-193
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• 2005

The TEMPO-mediated living free-radical bulk and dispersion polymerization of styrene in the presence of camphorsulfonic acid (CSA) are investigated. In the absence of TEMPO and CSA in the bulk polymerization, a conversion of $93\%$ is achieved within 6 hr of polymerization. When only TEMPO is involved in this polymerization, the pseudo-living free-radical polymerization is well achieved, however, the polymerization rate becomes quite slow. This retardation of the polymerization rate is solved by the addition of a low concentration of CSA. In the TEMPO-mediated dispersion polymerization in the presence of CSA, similar trends in the conversion, kinetics, and PDI are observed as those observed in the case of bulk polymerization. When only TEMPO is used in the dispersion polymerization, the resulting particle size becomes quite broad, due to the prolonged polymerization time. However, when a 1.0 molar ratio of CSA to TEMPO is added to the TEMPO-mediated dispersion polymerization, fairly mono-disperse PS microspheres having an average size of 5.83 $\mu$m and a CV of 3.4$\%$ are successfully obtained, due to the narrow molecular weight distribution of the intermediate oligomers and shortening of the polymerization time. This result indicates that the addition of CSA to the TEMPO-mediated bulk and the use of dispersion polymerization not only shortens the polymerization time, but also greatly improves the uniformity of the microspheres.

• Applied Chemistry for Engineering
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• v.10 no.2
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• pp.287-292
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• 1999

The conducting composites were prepared by solution blending of polyaniline (PANI) as a conducting polymer and polycarbonate (PC) as a matrix in chloroform. Also the composites film was prepared by solution casting method. The PANI was protonated with alkylbenzenesulfonic acids, such as camphorsulfonic acid (CSA) or dodecylbenzenesulfonic acid (DBSA). The electrical conductivity of composites prepared by solution casting was enhanced compared with that of compression molding. The electrical conductivity, tensile strength and morphology were observed as a function of the amount of protonating agent as well as PANI complex content. In general, as the PANI complex content was increased, the electrical conductivity increased. In the case of the composite film containing 25 wt % of PANI complex doped with DBSA, the electrical conductivity exhibited 3.18 S/cm.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.12 no.2
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• pp.293-298
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• 2001

EB-NMP free standing film is manufactured from NMP solution of polyaniline(emeraldine base EB). Also ES(emeraldine salt EB . HCl) film is manufactured by doping of EB-NMP film with 1 mole HCI aqueous solution. And EB-mixture films containing conductor(carbon black, graphite, Ag etc.) are prepared, In this study, electromagnetic interference shielding efficiency(EMI SE) of ES free standing film ($\sigma$=5 S/cm, t=0.14mm) is 23~25 dB in the frequency range of 10 MHz~1 GHz. ES-mixture(carbon black, graphite, Ag etc.) films, polyaniline film doped camphorsulfonic acid(CSA) show higher EMI SE(30~34 dB, 36~42 dB, 44~52 dB, 34~43 dB) property than that of ES free standing film, respectively.