• Bulletin of the Korean Chemical Society
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• 제19권4호
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• pp.492-495
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• 1998

• Bulletin of the Korean Chemical Society
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• 제25권3호
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• pp.361-364
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• 2004

The potentiometric response of electrode no. 4 based on 1,3-bisbridged cofacial-calix[6]crown-5-ether (IV) gave a sub-Nernstian (45.0 mV/decade) response and the best detection limit (-log $a_{ep}$ = 4.73) towards epinephrine. The responses are decreasing in the order of epinephrine > $K^+$, dopamine > $NH_4^+$ > norepinephrine > $Na^+$. It is remarkable that the proposed electrode shows the reasonable selectivity to epinephrine against other catecholamine neurotransmitters (dopamine and norepinephrine) as well as alkali metal ions.

• Bulletin of the Korean Chemical Society
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• 제24권5호
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• pp.674-676
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• 2003

• Bulletin of the Korean Chemical Society
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• 제28권5호
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• pp.816-820
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• 2007

Novel new red-light emitting perylene fluoroionophore N,N'-dipropyl-1,7-bis(calix[4]azacrown-5-crown-5)- 3,4,9,10-perylene tetracarboxy diimide (3) was prepared by reacting N,N'-dipropyl-1,7-dibromo-3,4,9,10- perylene tetracarboxy diimide (1) with calix[4]azacrown-5-crown-5. Also the alternating copolymer (4) with similar repeating unit was prepared reacting by calix[4]bisazacrown-5 with 1. Metal ion binding by 3 and 4 leads to a blue-shift of absorption band and emission spectra. When ionophoric characteristics were investigated by binding alkali, alkali earth metal and various metal ions, polymeric ionophores displayed large fluorescence decreasing effects with K+, Ag+ and Ba2+, which was rationalized by photo-induced charge transfer (PCT).

• 한국막학회:학술대회논문집
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• 한국막학회 1998년도 추계 총회 및 학술발표회
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• pp.31-36
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• 1998

1. 서론 : 산업이 고도로 발달함에 따라 야기되는 환경오염의 심각성이 날로 더해가고 있다. 특히 원자력 관련시설중 핵연료 재활용 공정에서 발생되는 방사성 폐기물의 처리기술에 대한 개발이 무엇보다도 시급한 실정이다. 핵연료 재활용 조작은 고준위 및 중준위 방사능 액체 폐기물을 발생시키며 이러한 방사능 액체 폐기물의 주요핵종은 긴 반감기를 갖는 것들이다. 이러한 방사능 액체 폐기물의 무해한 저장을 위해서 세계적으로 노력해 왔으며 고준위 폐기물은 유리화한후 심층매립을 하는 것이 가장 안전한 방법으로 고려되고 있다.(생략)

• 분석과학
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• 제13권4호
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• pp.428-432
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• 2000

새로운 캘릭스[4]크라운 화합물을 이온 선택성 물질로 사용하고 지지체로 PVC(polyvinyl chloride), 가소제로 DOS(dioctyl sebacate)를 사용하여 이온선택성 막전극을 제작 하였다. 제작한 막전극을 지시전극으로 사용하여 알칼리, 알칼리토금속 이온에 대하여 각각의 감응전위를 측정한 결과, pH7.20 Tris buffer에서 $10^{-5}-10^{-1}M$ 농도의 변화에 따른 $Cs^+$이온의 감응전위가 이론적인 Nernst식 기울기에 가까운 52.3 mV/decade로 직선성이 잘 성립하는 감응전위를 나타내었다. $Cs^+$이온 농도변화에 따른 막의 감응시간은 $t_{90%}$=10sec이었고, 막의 사용기간은 2개월 정도이다.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3445-3447
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• 2010

• Bulletin of the Korean Chemical Society
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• 제28권10호
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• pp.1792-1796
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• 2007

Insulating effects on Au electrode according to the thickness and density of coated materials are well-known. To do electrochemical immunoassay reproducibly the glod electrode would be coated with self-assembled monolayers and antobodies. To get reproducibility, the antobody monolayer should be packed at highest density so that the amount of immobilized antibody at defined area should be the same. The calix[4]crown-5 SAMs could provide the basis for the antibodies to be immobilized reproducibly and at highest density. But the insulating effect would be highest too. We proved that the compactly packed protein monolayers on SAMs inhibited the electron transfer by block the free shuttling of redox molecules. The inhibition was minimized by inserting redox molecules in between the proteins during immobilization process. In this paper, we demonstrated that the calix[4]crown-5 SAMs would provide the protein monolayers with highest density and new method to minimize the insulating effect by inserted redox molecules in between the compactly packed protein monolayers.

• Bulletin of the Korean Chemical Society
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• 제23권4호
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• pp.640-642
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• 2002

• 한국결정학회지
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• 제10권1호
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• pp.28-32
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• 1999

The title compound consisting of a calix[4]arene molecule with four phenyl rings arranged alternately in anti-orientation fashion, two propyloxy groups attached on the upper rim of calix[4]arene, and polyther chain with two phyenyl rings attached on the lower rim of calix[4]arene offers a big cavity inside a molecule with might a potential for forming host-guest complexes.