• Korean Journal of Materials Research
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• v.23 no.12
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• pp.687-694
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• 2013

This study was performed with an aim to improve the early-age strength of concrete containing fly ash, which is known to increase the long-age strength of concrete, reduce drying shrinkage, and enhance water tightness. The composition was partially substituted with calcium sulfoaluminate (CSA), from which ettringite is actively produced, in the early stages of hydration to verify its effect on improving the early-age strength and to determine the optimal mixing ratio. For this purpose, up to 30 % of the cement weight was substituted with fly ash, and the amount of CSA substitution was 8% of the fly ash weight. The mixtures were then fabricated into concrete specimens for compressive strength measurement and analysis of the correlation between the hydration products and the compressive strength.

• Journal of the Korean Ceramic Society
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• v.37 no.4
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• pp.388-394
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• 2000

The C4A3S clinker was prepared by the solid-state reaction. The mixture of raw materials; calcite, kaoline and gypsum, was fired at 135$0^{\circ}C$ for 1hr and cooled rapidly in air. C4A3S type expansive was made with C4A3S clinker, CaO and CaSO4. The cement replaced by 10 wt.% C4A3S type expansive was investigated by the measurement of the strength(compressive, tensile, flexural) and length change at various curing conditions. Hydration products were mainly ettringite, monosulfate and Ca(OH)2. The densification and the expansion due to the formation of ettringite during the hydration increased strength and reduced the drying shrinkage of hardened cement.

• Journal of the Korean GEO-environmental Society
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• v.13 no.2
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• pp.59-65
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• 2012

Solidification/Stabilization(S/S) is one of the remediation technologies that have been applied for treating inorganic hazardous wastes. This study investigated the reduction of arsenic concentration of arsenic-contaminated soil using by S/S. The binder plays a role in controlling the mobility and solubility of the contaminants in S/S process, so it is important to determine the optimum binder content. Therefore, this study evaluated the effectiveness of S/S using four different binders(cement, zero valent iron, and monosulfate and ettringite(cement-based synthesized materials) at the binder content ranged between 5%(wt.) and 20%(wt.). The leachability of arsenic in 1 N HCl was different depending on the types of binders: cement(71.41%) > monosulfate(47.45%) > ettringite(46.36%) > ZVI(33.08%) at the binder content of 20%. Additionally, three kinds of a mixture binder were prepared using cement and additives(monosulfate, ettringite, calcium sulfoaluminate(CSA)) and tested for arsenic reduction. The highest arsenic removal capacity was found at the mass ratio of cement to the additive, 4:1 in all experiments using a mixture binder, regardless of the additives types. A mixture binder(cement and additives) resulted in higher arsenic removal relative to the arsenic removal when cement was used alone.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.5
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• pp.12-20
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• 2017

This report presents the results of an investigation on the fundamental properties of mortars high fluidity high volume slag cement(HVSC) activated with sodium silicate($Na_2SiO_3$). The ordinary Portland cement(OPC) was replaced by ground granulated blast furnace slag(GGBFS) from 40% to 80% and calcium sulfoaluminate(CSA) was 2.5% or 5.0% mass. The $Na_2SiO_3$ was added at 2% and 4% by total binder(OPC+GGBFS+CSA) weight. A constant water-to-binder ratio(w/b)=0.35 was used for all mixtures. The research carried out the mini slump, V-funnel, setting time, compressive strength and drying shrinkage. The experimental results showed that the contents of superplasticizer, V-funnel, setting time and drying shrinkage increased as the contents of CSA and $Na_2SiO_3$ increase. The compressive strength increases with and an increase in CSA and $Na_2SiO_3$. One of the major reason for these results is the accelerated reactivity of GGBFS with CSA and $Na_2SiO_3$. The maximum performance was CSA 5.0% + $Na_2SiO_3$ 4% specimens.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.6
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• pp.74-82
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• 2017

This research presents the results of the strength and drying shrinkage properties to study the effect of ground granulated blast furnace slag(GGBFS), fly ash(FA) and calcium sulfoaluminate(CSA) for activated ternary blended slag cement. The activated ternary blended cement(ATBC) mortar were prepared having a constant water-cementitious materials ratios of 0.4. The GGBFS contents ratios of 100%, 80%, 70% and 60%, FA replacement ratios of 10%, 20%, 30% and 40%, CSA ratios of 0%, 10%, 20% and 30% were designed. The superplasticizer of polycarboxylate type were used. The activator was used of 10% sodium hydroxide(NaOH) + 10% sodium silicate($Na_2SiO_3$) by weight of binder. Test were conducted for mini slump, setting time, V-funnel, water absorption, compressive strength and drying shrinkage. According to the experimental results, the contents of superplasticizer, V-funnel and compressive strength increases with an increase in CSA contents for all mixtures. Moreover, the setting time, water absorption ratios and drying shrinkage ratio decrease with and increase in CSA. One of the major reason for the increase of strength and decrease of drying shrinkage is the accelerated reactivity of GGBFS with alkali activator and CSA. The CSA contents is the main parameter to explain the strength development and decreased drying shrinkage in the ATBC.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.561-568
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• 2022

In this study, the mechanical properties and self-healing performance of cement mortar containing clinker binder, calcium sulfoaluminate(CSA), and sodium sulfate(Na₂SO₄) were evaluated. The mechanical properties of cement mortar were investigated by measuring compressive strength and flexural strength, and the healing performance was evaluated through hydrostatic water permeability test and gas diffusion test. In addition, the healing products precipitated in the cracks were visually observed through an optical microscope and a scanning electron microscope(SEM). As a result, the incorporation of the clinker binder-based inorganic additives improved the initial and 28-day strength by about 20 %. Depending on the healing performance evaluation method, there was a difference in the healing rate, and the healing rate showed a tendency to be underestimated. Nevertheless, CaCO₃ was precipitated as the main healing product inside the 0.3 mm crack when the inorganic additives were mixed with cement mortar, improving the self-healing performance.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.552-559
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• 2023

The purpose of this study is to evaluate the crack reduction performance of blast furnace slag concrete mixed with expansive and swelling admixtures. As a basic performance test, various ingredients such as blast furnace slag fine powder (BFS), calcium sulfoaluminate (CSA), bentonite, and hydroxypropyl methyl cellulose (HPMC) were used, and the results showed that bentonite showed superior performance compared to HPMC. Afterwards, a MOCK-UP test was conducted to evaluate cracking and drying shrinkage according to the mixing ratio. As a result, when bentonite and a small amount of calcium phosphate were added, drying shrinkage was reduced and cracking was reduced. In particular, a cement mixture consisting of 30 % BFS, 1 % bentonite, and 1 % calcium phosphate showed optimal crack-free performance. It is believed that BFS concrete will contribute to compensating for shrinkage through continuous expansion activity and can be used for field applications.

• Advances in concrete construction
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• v.10 no.5
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• pp.393-402
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• 2020

The given research focuses on examining the effect of relatively humidity (RH) and curing temperature on the hydrates as well as the porosity of calcium sulfoaluminate (CSA) cement pastes. Numerous tests, which consist of mercury intrusion porosimetry (MIP), thermosgravi metric (TG) and X-ray diffraction (XRD) were conducted. Various characterization techniques which include, scanning electron microscopy, Fourier transform microscopy along with X-ray diffraction evaluations were conducted on the samples to examine phase formation and crystallinity, morphology and microstructure along with bond formations and functional groups, respectively. During long-term study, the performance of concrete which consisted of limestone and flash-calcined was close to those from standard Portland cement concrete. Traditional classifications and methods of corrosion were widely used for the assessment of steel in concrete which may get employed to concrete which contains LC3 to recalibrate the range of polarization resistance for passitivity condition. For example, there is up to 79.5% and 146% respective flexural and compressive strengths. Moreover, they developed more advance electrical and thermo-mechanical performance with a substantial reduction in absorption of water of close to 400%. These advantages allow this research crucial to evaluate how these methods can be applied. Additionally, the research evaluates developed and more advanced cement preservation and repair techniques. The conclusion suggests concerted efforts by various stakeholders such as policy makers to enable low-carbon rates.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.1
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• pp.75-83
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• 2014

In order to prevent brittle failure of concrete, steel fiber reinforcement is effective composite material. However ductility of steel fiber reinforced concrete may be limited due to shrinkage caused by large content of cement binder. Chemical prestressing for steel fiber reinforcement in cement matrix can be induced through expansive admixture and this can increase reinforcing effect of steel fiber. In this study, mechanical performances in concrete with CSA (Calcium sulfoaluminate) expansive admixture and steel fiber reinforcement are evaluated. For this work, steel fiber reinforcement of 1 and 2% of volume ratio and CSA expansive admixture of 10% weight ratio of cement are added in concrete. Mechanical and fracture properties are evaluated in concrete with steel fiber reinforcement and CSA expansive admixture. CSA concrete with steel fiber reinforcement shows increase in tensile strength, initial cracking load, and ductility performance like enlarged fracture energy after cracking. With appropriate using expansive admixture and optimum ratio of steel fiber reinforcement, their interactive action can effectively improve brittle behavior in concrete.

• Geomechanics and Engineering
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• v.18 no.4
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• pp.407-415
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• 2019

A controlled low strength material (CLSM) is a highly flowable cementitious material used for trench backfilling. However, when applying vertical loads to backfilled trenches, shear failure or differential settlement may occur at the interface between the CLSM and natural soil. Hence, this study aims to evaluate the characteristics of the interface friction between the CLSM and soils based on curing time, gradation, and normal stress. The CLSM is composed of fly ash, calcium sulfoaluminate cement, sand, silt, water, and an accelerator. To investigate the engineering properties of the CLSM, flow and unconfined compressive strength tests are carried out. Poorly graded and well-graded sands are selected as the in-situ soil adjacent to the CLSM. The direct shear tests of the CLSM and soils are carried out under three normal stresses for four different curing times. The test results show that the shear strengths obtained within 1 day are higher than those obtained after 1 day. As the curing time increases, the maximum dilation of the poorly graded sand-CLSM specimens under lower normal stresses also generally increases. The maximum contraction increases with increasing normal stress, but it decreases with increasing curing time. The shear strengths of the well-graded sand-CLSM interface are greater than those of the poorly graded sand-CLSM interface. Moreover, the friction angle for the CLSM-soil interface decreases with increasing curing time, and the friction angles of the well-graded sand-CLSM interface are greater than those of the poorly graded sand-CLSM interface. The results suggest that the CLSM may be effectively used for trench backfilling owing to a better understanding of the interface shear strength and behavior between the CLSM and soils.