• Title/Summary/Keyword: calcium carbonate content

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Paper Strength Improvement by Anionic PAM and Cationic Starch Adsorbed PCC (음이온성 PAM과 양이온성 전분으로 도포된 경질탄산칼슘에 의한 종이 강도 향상)

  • Choi, Do-Chim;Choi, Eun-Yeon;Won, Jong Myoung;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.1
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    • pp.59-66
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    • 2013
  • Fillers have been used for printing paper to improve printability, sheet formation and optical properties and to reduce production costs by replacing expensive wood pulps. However, an increased filler content will decrease paper strength because filler particles interfere with fiber-fiber bonding. In order to increase filler content without sacrificing too much paper strength in high filler content papers, the surface of precipitated calcium carbonate (PCC) has been modified by adsorbing anionic polyacrylamide and cationic starch in series. The adsorbed polymer layers would enhance interactions between the filler surface and the fiber surface, improving internal bonding. It was found that the modified PCC increased paper strength at a given filler content compared to the coventional method. Negligible differences in optical properties and formation of paper, filler and fines retention and drainage on the wire section were observed between the modified and the conventional PCC. However, the decreased bulk of paper was observed when the modified PCC was used.

A Study on the Technique to Manufacture Recycled Cement from Cementitious Powders for Complete Recycling of Concrete Structures (콘크리트 구조물의 완전순환이용을 위한 폐콘크리트계 미분말의 재생시멘트 활용 기술 연구)

  • Park, Cha-Won;An, Jae-Cheol;Gang, Byeong-Hui
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.3
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    • pp.143-151
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    • 2004
  • The purpose of this study is development of technique to use cementitious powder as recycle cement produced from deteriorated Concrete waste which has a large quantity of calcium carbonate. Therefore, after having theoretical consideration based on the properties of high-heated concrete and concerning about neutralization of Concrete, we analysis chemical properties of ingredients of cementitious powder. After making origin cement paste, then processing the accelarated carbonation, we consider the properties of hydration and chemical properties of cementitious powder under various temperature conditions. As a result of the thermal analysis, the $CaCO_3$ content of cementitious powder would affect decision of heat temperature to recover its hydrated ability because $CaCO_3$ content is increased when neutralization is progressed. And as a result of XRD analysis, in case of origin powder of non-neutralized paste, CaO peak is found at $700^{\circ}C$. but, heat temperature to generate CaO would increase when the content of neutralized ingredients is increased. Finally, recycle cement heated at $700^{\circ}C$ 120min. shows the best compressive strength when the content of neutralized ingredients in recycle cement is less then 50%.

The Properties of Recycle Cement to Reuse Cementitious Powder from Neutralized Concrete Waste (중성화가 진행된 폐콘크리트계 미분말을 재활용한 재생시멘트의 물성)

  • Kang, Tae-Hun;Kim, Sung-Su;Jung, Min-Soo;Kang, Byung-He
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.11a
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    • pp.77-82
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    • 2003
  • The purpose of this study is development of technique to use cementitious powder as recycle cement produced from deteriorated Concrete waste which has a large quantity of calcium carbonate. Therefore, after having theoretical consideration based on the properties of high-heated concrete and concerning about neutralization of Concrete, we analysis chemical properties of ingredients of cementitious powder. After making origin cement paste, then processing the accelarated carbonation, we consider the properties of hydration and chemical properties of cementitious powder under various temperature conditions. As a result of the thermal analysis, the CaCo3 content of cementitious powder would affect decision of heat temperature to recover its hydrated ability because CaCo3 content is increased when neutralization is progressed. And as a result of XRD analysis, in case of origin powder of non-neutralized paste, CaO peak is found at 700℃. but, heat temperature to generate CaO would increase when the content of neutralized ingredients is increased. Finally, recycle cement heated at 700℃ shows the best compressive strength when the content of neutralized ingredients in recycle cement is less then 50%. However, it would be quite difficult to manage quality of recycle cement according to recycling points of various concrete waste.

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The Properties of Recycle Cement to Reuse Cementitious Powder from Neutralized Concrete Waste (중성화가 진행된 폐콘크리트계 미분말을 재활용한 재생시멘트의 물성)

  • 강태훈;김성수;정민수;강병희
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.05a
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    • pp.77-82
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    • 2003
  • The purpose of this study is development of technique to use cementitious powder as recycle cement produced from deteriorated Concrete waste which has a large quantity of calcium carbonate. Therefore, after having theoretical consideration based on the properties of hish-heated concrete and concerning about neutralization of Concrete, we analysis chemical properties of ingredients of cementitious powder After making origin cement paste, then processing the accelerated carbonation, we consider the properties of hydration and chemical properties of cementitious powder under various temperature conditions As a result of the thermal analysis, the CacO3 content of cementitious powder would affect decision of heat temperature to recover its hydrated ability because CacO3 content is increased when neutraliTation is preBlessed. And as a result of XRD analysis. in case of origin powder of non-neutralized paste, CaO peak is found at $700^{\circ}C$. but, heat temperature to generate CaO would increase when the content of neutralized ingredients is increased. Finally, recycle cement heated at $700^{\circ}C$ shows the best compressive strength when the content of neutralized ingredients in recycle cement is less then 50%. However, it would be quite difficult to manage quality of recycle cement according to recycling points of various concrete waste.

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Effects of Grain Size Distribution in Soil on the Strength Characteristics of Lime-Soil Mixtures (흙의 粒度分捕가 石灰混合土의 强度特性에 미치는 影響)

  • Cho, Seong-Jeong;Kang, Yea-Mook
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.27 no.2
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    • pp.57-71
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    • 1985
  • The characteristics of compaction and unconfined compressive strength were investigated by mixing with lime to all soils adjusted by given percentages of two kinds of clays to sand to obtain the most effective distribution of grain size and the optimum lime content for soil stabilization. In addition, unconfined compressive strength and durability tested by adding of sodium metasilicate, sodium sulfate, sodium carbonate, sodium gydroxide and magnesium oxide to lime-soil mixture mixed with 8 percent lime to adjusted soil having the mixing percentage of 60 percent of cohesive black clay and 40 percent of sand by weight to get the effect and the optimum content of chemicals. The results obtained were as follows; 1.With the addition of more lime, the optimum moisture content was increased, and the maximum dry density was decreased, whereas the more the amount of clay and the less was the maximum drt density. 2. In the soil having more fine grain size the unconfined compressive strength was larger in the earlier stage of curing period, in accordance with the longer period, the mixing percentages of sand to clay showing the maximum unconfined compressive strength, on the basis of 28-day strength, were 60% : 40% (black clay) and 40% : 60% (brown clay) respectively. 3. The reason why the soil adjusted with black clay was remarkably bigger in the unconfined compressive strength than ones adjusted with brown clay for all specimen of lime-soil mixture was the difference in the kind of clay, the amount of chemical compositions the value of pH. Black clay was mainly composed of halloysite that reacted with lime satisfactorily, whereas the main composition of brown clay was kaolinite that was less effect in the enhance of unconfined compressive strength. Also the difference of unconfined compressive strength was because black clay was larger in the amount of composition of calcium oxide and magnesium oxide in the value of pH affecting directly on the unconfined compressive strength of lime-soil mixture than brown clay. 4. In the lime-soil mixture mixed with 8 percent of lime to soil that mixing percentage of sand to black clay was 60% : 40%, on the standard of 7-day strength, the effect of chemical was arranged in the order of magnesium oxide, sodium carbonate, sodium sulfate, sodium hydroxide and sodium metasilicate. 5. The optimum amount of chemical being applicable to the maximum unconfined compressive strength of lime-chemical-soil mixture was 1 percent by weight for air dry soil in the case of adding sodium carbonated and 0.75 percent on sodium hydroxide, the unconfined compressive strength was increased continuously with increase of the amount of chemical up to 2 percent of chemical content is the lime-chemical-soil mixture added sodium metasilicate, sodium sulfate and magnesium oxide. 6. It was considered that the chemical played and accelerant role of early revelation of strength because the rate of increase of unconfined compressive strength of all of lime-chemical-soil mixtures was largest on the 7-day cured specimen. 7. The effect of test on freezing and thawing after adding suitable amount of chemical on the lime-soil mixture mixed with 8 percent of lime to soil that mixing percentage of sand to black clay was 60% : 40% was arranged in the order of magnesium oxide, sodium carbonate, sodium sulfate, sodium metasilicate and sodium hydroxide.

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Thermal Stability of Trifunctional Epoxy Resins Modified with Nanosized Calcium Carbonate

  • Jin, Fan-Long;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.334-338
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    • 2009
  • Trifunctional epoxy resin triglycidyl paraaminophenol (TGPAP)/$CaCO_3$ nanocomposites were prepared using the melt blending method. The effects of nano-$CaCO_3$ content on the thermal behaviors, such as cure behavior, glass transition temperature ($T_g$), thermal stability, and the coefficient of thermal extension (CTE), were investigated by several techniques. Differential scanning calorimetry (DSC) results indicated that the cure reaction of the TGPAP epoxy resin was accelerated with the addition of nano-$CaCO_3$. When the nano-$CaCO_3$ content was increased, the $T_g$ of the TGPAP/$CaCO_3$ nanocomposites did not obviously change, whereas the crosslinking density was linearly increased. The nanocomposites showed a higher thermal stability than that of the neat epoxy resin. This result could be attributed to the increased surface contact area between the nano-$CaCO_3$ particles and the epoxy matrix, as well as the high crosslinking density in the TGPAP/$CaCO_3$ nanocomposites. The CTE of the nanocomposites in the rubbery region was significantly decreased as the nano-$CaCO_3$ content was increased.

Space Charge Formation in Epoxy/Filler Composites (Epoxy/Filler 복합재료의 공간전하축적 현상)

  • 남진호;이창용;이미경;서광석;강동필
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.171-174
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    • 1995
  • Space charge formation in epoxy loaded with silica and calcium carbonate has been studied. The epoxy itself showed almost no charge at up to 40 kV/mm. The addition of fillers such as SiO$_2$and CaCO$_3$resulted in homocharge formation, which was attributed to the interfacial trapping of injected charge at epoxy/filler interfaces. The amount of charge showed a maximum at 20-40 parts per hundred resin above which the charge decreased gradually. This was tentatively attributed to the enhanced interconection of charge transport path by an increased filler content

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Acetylation of Papermaking Pulp Fiber and its Application (제지용(製紙用) 펄프 섬유(纖維)의 아세틸화(化)와 응용(應用))

  • Won, Jong-Myoung
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.1
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    • pp.51-59
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    • 1992
  • The acetylation of papermaking pulp fiber(SwBKP, SwUKP, HwBKP and HwBCTMF) is carried out to modify the characteristics of pulp and paper. The effects of the addition of acetylated pulp on the filler retention and paper properties were investigated. The acetylation depended upon pulp type and the content of short fiber and fines. The addition of acetylated SwBKP did not deteriorate the retention of clay, talc and calcium carbonate, while the retention of titanium dioxide was increased with the addition of 20% and above. The brightness opacity, air permeability and tear strength were improved, but water resistance, burst strength and folding endurance were decreased by the addition of acetylated SwBKP and SwUKP. The tensile strength of SwBKP was increased until 20% of acetylated pulp is added, and then decreased. The tensile strength of SwUKP, however, was not changed until the acetylated pulp of 25% is added. The dimensional stability was improved by the addition of acetylated pulp and showed the different response to SwBKP and SwUKP.

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Optimization of some major factors in cigarette paper manufacturing using response surface analysis (반응표면 분석방법에 의한 궐련지 제조 주요인자의 최적화 연구)

  • 김영호;이근회
    • Journal of the Korean Society of Tobacco Science
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    • v.11 no.2
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    • pp.211-224
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    • 1989
  • 10. Three major factors, freeness, filler and blend ratio that exercised considerable influence on physical properties of cigarette papers were chosen for the sake of their optimization at this experiment. An optimization of those above factors in paper manufacturing was investigated using response surface analysis. Optimum beating degree for Kenaf, Flax and NBKP showed around 72。SR, 68。SR and 85 SR, respectively, in considering of five quality index such as porosity, tensile strength, stretch, whiteness and opacity. The best blending ration of reciprocal pulps treated under optimum beating degree were diversified and combination scope of the bast fiber (Kenaf, Flax) to the NBKP was range from 30% to 65% in case of the Kenaf, from 25 to 40% in Flax at the same receipe. The optimum range of calcium carbonate content revealed 25%~30% in Kenaf mixed NBKP and 24%~31% in Flax mixed NBKP.

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Analysis on Long-Term Behavior of Reinforced Clayey Soil by Model Test (모형실험에 의한 보강 점성토체의 장기적 거동 분석(지반공학))

  • 이상호;김철영;장병욱
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2000.10a
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    • pp.471-476
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    • 2000
  • Long-term behavior of reinforced clayey soil by model tests were performed to investigate the effect of reinforcement during loads and under static loads. In order to determine proper contents by weight of monofilament polypropylene fiber and calcium carbonate, the drying shrinkage and compressive strength tests had been conducted before model tests. Model tests were run on a clayey soil mixed with or without reinforcement and test specimen in test apparatus was placed in air dry for 7days before load application. In the case of fiber reinforced soil, the horizontal strain was lower than others during loads because the presence of fibers increased the soil's resistance to deformation. All of reinforced clayey soil, horizontal strain decreased as the water content decrease under static loads.

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